scholarly journals Identification of recombination losses and charge collection efficiency in a perovskite solar cell by comparing impedance response to a drift-diffusion model

Nanoscale ◽  
2020 ◽  
Vol 12 (33) ◽  
pp. 17385-17398
Author(s):  
Antonio Riquelme ◽  
Laurence J. Bennett ◽  
Nicola E. Courtier ◽  
Matthew J. Wolf ◽  
Lidia Contreras-Bernal ◽  
...  

Interpreting the impedance response of perovskite solar cells is significantly more challenging than for most other photovoltaics. Here we provide a way to obtain useful information from the spectrum using insights from drift-diffusion simulation.

2015 ◽  
Vol 17 (7) ◽  
pp. 4937-4944 ◽  
Author(s):  
Huiyun Wei ◽  
Jiangjian Shi ◽  
Xin Xu ◽  
Junyan Xiao ◽  
Jianheng Luo ◽  
...  

A MIS back contact was constructed by introducing an ultrathin AlOxlayer to improve the performance of HTM-free perovskite solar cells.


Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1751
Author(s):  
Inga Ermanova ◽  
Narges Yaghoobi Nia ◽  
Enrico Lamanna ◽  
Elisabetta Di Bartolomeo ◽  
Evgeny Kolesnikov ◽  
...  

In this paper, we demonstrate the high potentialities of pristine single-cation and mixed cation/anion perovskite solar cells (PSC) fabricated by sequential method deposition in p-i-n planar architecture (ITO/NiOX/Perovskite/PCBM/BCP/Ag) in ambient conditions. We applied the crystal engineering approach for perovskite deposition to control the quality and crystallinity of the light-harvesting film. The formation of a full converted and uniform perovskite absorber layer from poriferous pre-film on a planar hole transporting layer (HTL) is one of the crucial factors for the fabrication of high-performance PSCs. We show that the in-air sequential deposited MAPbI3-based PSCs on planar nickel oxide (NiOX) permitted to obtain a Power Conversion Efficiency (PCE) exceeding 14% while the (FA,MA,Cs)Pb(I,Br)3-based PSC achieved 15.6%. In this paper we also compared the influence of transporting layers on the cell performance by testing material depositions quantity and thickness (for hole transporting layer), and conditions of deposition processes (for electron transporting layer). Moreover, we optimized second step of perovskite deposition by varying the dipping time of substrates into the MA(I,Br) solution. We have shown that the layer by layer deposition of the NiOx is the key point to improve the efficiency for inverted perovskite solar cell out of glove-box using sequential deposition method, increasing the relative efficiency of +26% with respect to reference cells.


2021 ◽  
Author(s):  
Song Fang ◽  
Bo Chen ◽  
Bangkai Gu ◽  
Linxing Meng ◽  
Hao Lu ◽  
...  

UV induced decomposition of perovskite material is one of main factors to severely destroy perovskite solar cells for instability. Here we report a UV stable perovskite solar cell with a...


2013 ◽  
Vol 8 (03) ◽  
pp. C03023-C03023 ◽  
Author(s):  
M Jakubek ◽  
J Jakubek ◽  
J Zemlicka ◽  
M Platkevic ◽  
V Havranek ◽  
...  

2021 ◽  
Vol 16 (6) ◽  
pp. 855-860
Author(s):  
Ji Yong Hwang ◽  
II Tae Kim ◽  
Hyung Wook Choi

To reduce the manufacturing cost of perovskite solar cells, soda-lime glass and transparent conducting oxides such as indium tin oxide and fluorine-doped tin oxide are the most widely used substrates and lighttransmitting electrodes. However, the transmittance spectra of soda-lime glass, indium tin oxide, and fluorinedoped tin oxide show that all light near and below 330 nm is absorbed; thus, with the use of these substrates, light energy near and below 330 nm cannot reach the perovskite light-absorbing layer. It is expected that the overall solar cell can be improved if the wavelength can be adjusted to reach the perovskite solar cell absorbing layer through down-conversion of energy in the optical wavelength band. In this study, a polyvinylidene fluoride transparent film mixed with a ZnGa2O4:Mn phosphor was applied to the incident side of the perovskite solar cell with the intent to increase the light conversion efficiency without changing the internal bandgap energy and structure. By adding a phosphor layer to the external surface of PSC exposed to incident light, the efficiency of the cell was increased by the down-conversion of ultraviolet light (290 nm) to the visible region (509 nm) while maintaining the transmittance. To manufacture the perovskite solar cell, a TiO2-based mesoporous electron transport layer was spin-coated onto the substrate. The perovskite layer used in this experiment was CH3NH3PbI3 and was fabricated on a TiO2 layer. Spiro-OMeTAD solution was spin-coated as a hole-transport layer.


RSC Advances ◽  
2020 ◽  
Vol 10 (59) ◽  
pp. 35831-35839 ◽  
Author(s):  
Mustafa K. A. Mohammed

Carbon-based perovskite solar cells (C-PSCs) are the most promising photovoltaic (PV) due to their low material and manufacturing cost and superior long-term stability.


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