N-Substituted tetrahydropentaazadibenzocycloheptafluorenes – a new type of condensed polyazapolycyclic system

2021 ◽  
Author(s):  
Elena B. Rakhimova ◽  
Victor Yu. Kirsanov ◽  
Ekaterina S. Mescheryakova ◽  
Leonard M. Khalilov ◽  
Askhat G. Ibragimov
Keyword(s):  
System P ◽  

Ni-Catalyzed heterocyclization of octahydro-2,2′-biquinazoline with 1,3,5-triazinanes is an efficient synthetic route to mono-N-substituted tetrahydro-4b,5a,10b,12,13a-pentaazadibenzo[a,h]-cyclohepta[1,2,3,4-def]fluorenes.

2021 ◽  
Author(s):  
Bo Zhang ◽  
Yu'ai Duan ◽  
Xin Zhang ◽  
Shuai Guo

The study of non-innocent behavior of NHCs (NHCs = N-heterocyclic carbenes) has great implications for NHC-involved catalysis. Herein, we report a new type of NHC-to-azole rearrangement, during which process the...


2014 ◽  
Vol 50 (82) ◽  
pp. 12308-12310 ◽  
Author(s):  
Liuqun Gu ◽  
Ting Lu ◽  
Xiukai Li ◽  
Yugen Zhang

An efficient formation of acetoin from acetaldehyde was achieved under thiazolylidene catalysis and a new type of solid supported system.


Tetrahedron ◽  
1986 ◽  
Vol 42 (15) ◽  
pp. 4187-4195 ◽  
Author(s):  
Hiromichi Tanaka ◽  
Hiroyuki Hayakawa ◽  
Kikoh Obi ◽  
Miyasaka Tadashi
Keyword(s):  

2015 ◽  
Vol 51 (60) ◽  
pp. 12072-12075 ◽  
Author(s):  
Hongjun Chen ◽  
Qiong Wang ◽  
Miaoqiang Lyu ◽  
Zhi Zhang ◽  
Lianzhou Wang

A new type of hybrid TiO2–Ag nanocluster (NC) photoelectrode exhibits wavelength-switchable photocurrent by tuning the light wavelength from ultraviolet (UV) to visible light. The combination of UV-active TiO2 and visible-light-active Ag NCs with photoelectrochemical behaviour leads to the unique switchable photocurrent in the system.


1990 ◽  
Vol 180 ◽  
Author(s):  
R.W. Pekala ◽  
C.T. Alviso

ABSTRACTThe aqueous, sol-gel polymerization of melamine with formaldehyde, followed by supercritical extraction, leads to the formation of a new type of organic aerogel. Synthetic conditions (e.g. reaction time, pH) affect the density, transparency, and microstructure of the resultant aerogels. Unlike previous organic aerogels based upon resorcinol-formaldehyde, the melamine-formaldehyde aerogels are both colorless and transparent. Low densities (0.1–0.8 g/cc), high surface areas (∼1000 m2/g), and optical clarity are only a few of the promising characteristics of this new material.


2017 ◽  
Vol 8 (37) ◽  
pp. 5655-5659 ◽  
Author(s):  
Min-Sung Kim ◽  
Cheol Soo Phang ◽  
Young Kyu Jeong ◽  
Jin Kuen Park

A new type of organic nanosheet was synthesized via two different routes. We found that the morphologies of resulting products can be controlled based on the synthetic route and solvent used for film formation.


2021 ◽  
Author(s):  
Fengping Peng ◽  
Wanxin Xu ◽  
Yunya Hu ◽  
Weijie Fu ◽  
Haozhen Li ◽  
...  

Inspired by the microorganisms in nature, a new type of waste-energy-driven catalytic film is explored firstly by using magnetically actuated artificial cilia. Due to its singular characteristic of ciliary movement,...


RSC Advances ◽  
2017 ◽  
Vol 7 (8) ◽  
pp. 4402-4408 ◽  
Author(s):  
Jonathan B. Vander Wiel ◽  
Jonathan D. Mikulicz ◽  
Michael R. Boysen ◽  
Niloofar Hashemi ◽  
Patrick Kalgren ◽  
...  

A new type of multi-pixel photon counter was employed to miniaturize the device, lower its power consumption, and make it insensitive to magnetic fields.


RSC Advances ◽  
2017 ◽  
Vol 7 (78) ◽  
pp. 49777-49786 ◽  
Author(s):  
Zanru Guo ◽  
Hongjian Gu ◽  
Wei Ma ◽  
Qiang Chen ◽  
Zhanfeng He ◽  
...  

A new type CO2-switchable AgNPs hybrids show switchable and monotonous tunable catalytic activity for the reduction of 4-nitrophenol by varying the flow rate of CO2purged into the reaction system.


The Analyst ◽  
2020 ◽  
Vol 145 (10) ◽  
pp. 3569-3574
Author(s):  
Rui Guo ◽  
Shanwen Hu ◽  
Zonghua Wang

A new type of closed BPE-ECL system based on an Au electric circuit at a portable substrate is designed for the visualized sensing of Cas9 Activity in the CRISPR/Cas9 system.


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