The AlAl triple bond in Al2X5+ and Al2X62+ (X = Li, Na) clusters with multiple alkali metal coordination

2020 ◽  
Vol 44 (48) ◽  
pp. 21119-21124
Author(s):  
Yingying Liu ◽  
Changyan Zhu ◽  
Chaoxia Wen ◽  
Min Zhang ◽  
Yun Geng ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Triple Bond ◽  
Metal Coordination ◽  
The Core ◽  
Alkali Metal Coordination

The AlAl triple bond does not change obviously with the increase in the number of Li+ or Na+ and [AlAl]4− is the core to stabilize these clusters and its stability is hard to be affected by the numbers and positions of the Li+ or Na+.

Novel Alkali-Metal Coordination in Phenoxides:  Powder Diffraction Results on C6H5OM (M = Li, Na, K, Rb, Cs)

1997 ◽  
Vol 36 (16) ◽  
pp. 3398-3401 ◽  
Author(s):  
R. E. Dinnebier ◽  
Maren Pink ◽  
J. Sieler ◽  
P. W. Stephens
Keyword(s):  
Alkali Metal ◽  
Powder Diffraction ◽  
Metal Coordination ◽  
Alkali Metal Coordination

Thiacalix[4]arene–rubidiumassembly: supramolecular architecture based on alkali metal coordination and cation–π interactions

CrystEngComm ◽  
2010 ◽  
Vol 12 (4) ◽  
pp. 1311-1315 ◽  
Author(s):  
Manabu Yamada ◽  
Yoshifumi Shimakawa ◽  
Yoshihiko Kondo ◽  
Fumio Hamada
Keyword(s):  
Alkali Metal ◽  
Metal Coordination ◽  
Supramolecular Architecture ◽  
Π Interactions ◽  
Alkali Metal Coordination

Structural diversity of alkali metal coordination polymers driven by flexible biphenyl-4,4′-dioxydiacetic acid

2018 ◽  
Vol 265 ◽  
pp. 92-99 ◽  
Author(s):  
Renata Łyszczek ◽  
Halina Głuchowska ◽  
Liliana Mazur ◽  
Bogdan Tarasiuk ◽  
Vasyl Kinzhybalo ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Coordination Polymers ◽  
Structural Diversity ◽  
Metal Coordination ◽  
Metal Coordination Polymers ◽  
Alkali Metal Coordination

Structural Versatility of Alkali Metal Coordination Polymers Driven by Arylhydrazones of β-Diketones

2013 ◽  
Vol 13 (11) ◽  
pp. 5076-5084 ◽  
Author(s):  
Kamran T. Mahmudov ◽  
M. Fátima C. Guedes da Silva ◽  
Alexander M. Kirillov ◽  
Maximilian N. Kopylovich ◽  
Archana Mizar ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Coordination Polymers ◽  
Metal Coordination ◽  
Metal Coordination Polymers ◽  
Alkali Metal Coordination ◽  
Structural Versatility

Effect of Alkali Metal Coordination on Gas-Phase Chemistry of the Diphosphate Ion: The MH2P2O7− Ions

2006 ◽  
Vol 12 (10) ◽  
pp. 2787-2797 ◽  
Author(s):  
Federico Pepi ◽  
Andreina Ricci ◽  
Marzio Rosi ◽  
Marco Di Stefano
Keyword(s):  
Alkali Metal ◽  
Gas Phase ◽  
Metal Coordination ◽  
Gas Phase Chemistry ◽  
Phase Chemistry ◽  
Alkali Metal Coordination

Lanthanum and Alkali Metal Coordination Chemistry of the Bis(dimethylphenylsilyl)amide Ligand

2006 ◽  
Vol 45 (8) ◽  
pp. 3437-3443 ◽  
Author(s):  
William J. Evans ◽  
Daniel B. Rego ◽  
Joseph W. Ziller
Keyword(s):  
Coordination Chemistry ◽  
Alkali Metal ◽  
Metal Coordination ◽  
Alkali Metal Coordination

Some alkali metal alkyl amides as alkyne isomerization reagents: selective isomerization of one triple bond of a diynol

1983 ◽  
Vol 61 (6) ◽  
pp. 1073-1076 ◽  
Author(s):  
Suzanne R. Abrams ◽  
Donato D. Nucciarone ◽  
Warren F. Steck
Keyword(s):  
Sex Pheromone ◽  
Alkali Metal ◽  
Sodium Salt ◽  
Triple Bond ◽  
Lithium Salt ◽  
Terminal Position ◽  
Sodium Salts ◽  
Triple Bonds ◽  
High Yields ◽  
Insect Sex

The lithium and sodium salts of 1,2-diaminoethane, 1,3-diaminopropane, n-butylamine, and the lithium salt of isobutylamine were studied as potential reagents for isomerization of triple bonds in alkyn-1-ols. The sodium salts of the diamines afforded high yields of the ω-alkyn-1-ol. Somewhat surprisingly, the sodium salt of n-butylamine also effects isomerization to the terminal position. The lithium salt of 1,3-diaminopropane gave the highest conversion of 2- to 3-alkyn-1-ol. A novel, selective rearrangement of one triple bond of a diynol, a 2, ω- to 3, ω-diyn-1-ol isomerization, was incorporated into a synthesis of the insect sex pheromone 3,13-octadecadienol acetate.

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