scholarly journals Mixed valence trimers in cation radical salts of TMTTF with the planar bis(6-sulfo-8-quinolato) platinum complex [Pt(qS)2]2−

2020 ◽  
Vol 44 (36) ◽  
pp. 15538-15548
Author(s):  
Arkadiusz Frąckowiak ◽  
Bolesław Barszcz ◽  
Iwona Olejniczak ◽  
Mikołaj Tomasik ◽  
Natalia Jarzyniak ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Mixed Valence ◽  
Platinum Complex ◽  
Cation Radical

Hydrogen bonds between conducting stacks of (TMTTF)32+ trimers and the planar bis-sulfonate platinum complex [Pt(qS)2]2−.

C–H···O Hydrogen bonds in the mixed-valence salt [(η6-C6H6)2Cr]+[CrO3(OCH3)]- and the breakdown of the length/strength analogy

1998 ◽  
Vol 22 (8) ◽  
pp. 755-757 ◽  
Author(s):  
Dario Braga ◽  
Fabrizia Grepioni ◽  
Emilio Tagliavini ◽  
Juan J. Novoa ◽  
Fernando Mota
Keyword(s):  
Hydrogen Bonds ◽  
Mixed Valence

scholarly journals Face-to-Face Dimeric Tetrathiafulvalenes and Their Cation Radical and Dication Species as Models of Mixed Valence and π-Dimer States

2012 ◽  
Vol 85 (1) ◽  
pp. 51-60 ◽  
Author(s):  
Masashi Hasegawa ◽  
Kota Daigoku ◽  
Kenro Hashimoto ◽  
Hiroyuki Nishikawa ◽  
Masahiko Iyoda
Keyword(s):  
Mixed Valence ◽  
Cation Radical ◽  
Face To Face

Structural and spectroscopic characterisation of the mixed valence platinum complex PtdabI3 (dab=o-diaminobenzene)

1999 ◽  
Vol 287 (2) ◽  
pp. 218-222 ◽  
Author(s):  
Oliver Fritz Danzeisen ◽  
Mirela Goanta ◽  
Heinz Wilhelm Rotter ◽  
Gerhard Thiele
Keyword(s):  
Mixed Valence ◽  
Platinum Complex ◽  
Spectroscopic Characterisation

Cation radical salts of the tetrathiafulvalene series : fast mixed valence detection by thin layer cyclic voltammetry

1993 ◽  
Vol 56 (1) ◽  
pp. 2359-2363 ◽  
Author(s):  
R. Carlier ◽  
A. Tallec ◽  
P. Frere ◽  
M. Salle ◽  
M. Jubault ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Thin Layer ◽  
Mixed Valence ◽  
Cation Radical

scholarly journals Crystal structure of a mixed-valence μ-oxide Sn12cluster

2014 ◽  
Vol 70 (11) ◽  
pp. m378-m379 ◽  
Author(s):  
Marina M. Kireenko ◽  
Kirill V. Zaitsev ◽  
Sergey S. Karlov ◽  
Mikhail P. Egorov ◽  
Andrei V. Churakov
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Complex Molecule ◽  
Mixed Valence ◽  
Asymmetric Unit ◽  
Coordination Numbers ◽  
Trigonal Bipyramidal ◽  
Distorted Trigonal Bipyramidal Coordination ◽  
Solvent Molecules ◽  
Distorted Trigonal Bipyramidal

The mixed-valence μ-oxide Sn12cluster, decacarbonyltetra-μ4-oxido-hexa-μ3-oxido-tetrakis[μ-2,2′-(pyridine-2,6-diyl)bis(1,1-diphenylethanolato)]decatin(II)ditin(IV)dimolybdenum(O)(2Mo—Sn) toluene heptasolvate, [Mo2Sn12(C33H27NO2)4O10(CO)10]·7C7H8, has a crystallographically imposed inversion centre. The asymmetric unit also contains three and a half toluene solvent molecules, one of which is disordered about a centre of symmetry. The complex molecule comprises six distinct Sn atom species with four different coordination numbers, namely 3, 4, 5, and 6. The SnIIatoms forming the central Sn10O10core adopt distorted trigonal–pyramidal, square-pyramidal and octahedral coordination geometries provided by the μ-oxide atoms and by the O- and N-donor atoms of two pyridinediethanolate ligands. The terminal SnIVatoms have distorted trigonal–bipyramidal coordination geometries, with a μ4-oxide atom and the N atom of a pyridinediethanolate ligand occupying the axial positions, and the Mo atom of a Mo(CO)5group and the alkoxy O atoms of a ligand forming the equatorial plane. In the crystal, weak intra- and intermolecular C—H...O hydrogen bonds are observed.

A parametric two-mode vibronic model of a dimeric mixed-valence cell for molecular quantum cellular automata and computational ab initio verification

2020 ◽  
Vol 22 (44) ◽  
pp. 25982-25999
Author(s):  
Andrew Palii ◽  
Sergey Aldoshin ◽  
Shmuel Zilberg ◽  
Boris Tsukerblat
Keyword(s):  
Cellular Automata ◽  
Ab Initio ◽  
Mixed Valence ◽  
Cation Radical ◽  
Quantum Cellular Automata ◽  
Parametric Approach

Here we propose a two-mode vibronic model of a molecular cell for quantum cellular automata. The interconnection between the parametric approach and ab initio evaluations for the cation-radical of tetramethyleneethane molecule is established.

Mixed-Valence, Layered, Cation Radical Salts of the Ethane-Bridged Dimeric Tetrathiafulvalene [(EDT-TTF−CH2−)2•+][X-][THF]0.5, X-= FeCl4-, GaCl4-

2000 ◽  
Vol 12 (8) ◽  
pp. 2250-2256 ◽  
Author(s):  
Cécile Mézière ◽  
Marc Fourmigué ◽  
Enric Canadell ◽  
Rodolphe Clérac ◽  
Klaus Bechgaard ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Cation Radical
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