Trivalent metal ions promote the malic enzyme-catalyzed building of carbon–carbon bonds from CO2 and pyruvate

2020 ◽  
Vol 44 (40) ◽  
pp. 17208-17214
Author(s):  
Takayuki Katagiri ◽  
Yutaka Amao
Keyword(s):  
Metal Ions ◽  
Malic Enzyme ◽  
Metal Ion ◽  
Trivalent Metal ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
Trivalent Metal Ions

ME is an attractive biocatalyst for building carbon–carbon bonds through carboxylation of pyruvate with CO2. The carboxylation of pyruvate with CO2 was promoted by adding a trivalent metal ion. In particular, Al3+ accelerates ME-catalyzed carboxylation of pyruvate with CO2.

New multidentate ligands. XXI. Synthesis, proton, and metal ion binding affinities of N,N′,N″-tris[2-(N-hydroxycarbamoyl)ethyl]-1,3,5-benzenetricarboxamide (BAMTPH)

1983 ◽  
Vol 61 (12) ◽  
pp. 2740-2744 ◽  
Author(s):  
Isao Yoshida ◽  
Ichiro Murase ◽  
Ramunas J. Motekaitis ◽  
Arthur E. Martell
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Binding Constants ◽  
Cation Binding ◽  
Ion Binding ◽  
Binding Affinities ◽  
Metal Ion Binding ◽  
Trivalent Metal ◽  
Equilibrium Data ◽  
Trivalent Metal Ions

Synthesis of a new tris-bidentate multidentate ligand, N,N′,N″-tris[2-(N-hydroxycarbamoyl)ethyl]-1,3,5-benzenetricarboxamide (BAMTPH), designed for the binding of trivalent metal ions such as Fe(III), Ga(III), and Al(III), is described. Its cation binding affinities for hydrogen ion and for Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Ga(III), and Al(III) ions are described, and the equilibrium data are compared with those of analogous ligands. The binding constants of trivalent metal ions with the ligand do not show a chelate effect relative to the binding to individual bidentate hydroxamic acids.

Complexes of Oxamic Acid with Al(III), Ga(III), In(III), Tl(III), Y(III), Fe(III), Mn(II) and V(III)

1978 ◽  
Vol 33 (9) ◽  
pp. 987-989 ◽  
Author(s):  
J. K. Kouinis ◽  
J. M. Tsangaris ◽  
A. G. Galinos
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Diffuse Reflectance ◽  
Magnetic Moments ◽  
Reflectance Spectra ◽  
Trivalent Metal ◽  
Diffuse Reflectance Spectra ◽  
Trivalent Metal Ions

The preparation of complexes of oxamic acid with Al(III), Ga(III), In(III), Tl(III), Y(III), Fe(III), Mn(II) and V(III) is reported. From the study of the infrared and diffuse reflectance spectra and the magnetic moments (for the complexes of Fe(III), Mn(II) and V(III)) it is concluded that in all complexes the metal ion is coordinated with the carboxyl oxygen and the amidic nitrogen, after the ionization of one of the amidic hydrogens.Octahedral structures are proposed for all the complexes of the trivalent metal ions and the complex K2{Mn(oxamic)2} · 2 H2O.

Reactivity and Infrared Spectroscopy of Gaseous Hydrated Trivalent Metal Ions

2008 ◽  
Vol 130 (28) ◽  
pp. 9122-9128 ◽  
Author(s):  
Matthew F. Bush ◽  
Richard J. Saykally ◽  
Evan R. Williams
Keyword(s):  
Infrared Spectroscopy ◽  
Metal Ions ◽  
Trivalent Metal ◽  
Trivalent Metal Ions

ChemInform Abstract: Transesterification of a Phosphate Diester by Divalent and Trivalent Metal Ions.

ChemInform ◽  
2010 ◽  
Vol 23 (19) ◽  
pp. no-no
Author(s):  
J. R. MORROW ◽  
L. A. BUTTREY ◽  
K. A. BERBACK
Keyword(s):  
Metal Ions ◽  
Trivalent Metal ◽  
Phosphate Diester ◽  
Trivalent Metal Ions

Gelation of xanthan with trivalent metal ions

1992 ◽  
Vol 18 (4) ◽  
pp. 243-251 ◽  
Author(s):  
Heike Nolte ◽  
Sabine John ◽  
Olav Smidsrød ◽  
Bjørn T. Stokke
Keyword(s):  
Metal Ions ◽  
Trivalent Metal ◽  
Trivalent Metal Ions
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