scholarly journals On the absence of triplet exciton loss pathways in non-fullerene acceptor based organic solar cells

2020 ◽  
Vol 7 (6) ◽  
pp. 1641-1649 ◽  
Author(s):  
Maria S. Kotova ◽  
Giacomo Londi ◽  
Johannes Junker ◽  
Stefanie Dietz ◽  
Alberto Privitera ◽  
...  

Recombination to donor and acceptor triplet states should be energetically favourable. However, this recombination channel is not observed in operational devices.

Organic solar cells (OSCs) are discussed at length in terms of its performance leading to the generation of electricity. The key materials required for OSCs are the small organic molecules having donor and acceptor with suitable light absorption and electro-chemical properties of low energy band gap. Various structural scaffolds are highlighted with their structural design leading to film forming in an orderly manner and this morphology of film having a pivotal role in photo-induced charge separation, migration and collection at an electrode. Present day research informs that OSCs involving non fullerene based donors and acceptors are functioning with high photo conversion efficiency [PCE] of >17% and are promising candidates for practical applications.


2019 ◽  
Vol 9 (12) ◽  
pp. 1803541 ◽  
Author(s):  
Huanran Feng ◽  
Yuan‐Qiu‐Qiang Yi ◽  
Xin Ke ◽  
Jing Yan ◽  
Yamin Zhang ◽  
...  

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Hiroki Nojima ◽  
Takashi Kobayashi ◽  
Takashi Nagase ◽  
Hiroyoshi Naito

AbstractCarrier drift mobility is an important physical constant in the charge transport process of organic solar cells (OSCs). Although time-of-flight and space-charge-limited current techniques have been frequently utilized for mobility measurements, the validity of a new method using modulation photocurrent spectroscopy is discussed in this contribution. The advantages of this method are its applicability to working OSCs with optimized device structures and the simultaneous determination of the electron and hole mobilities. These features make it possible to study the relation between the mobility balance and the solar cell characteristics, such as the power conversion efficiency, using only a single working OSC; hence, it is not necessary to fabricate electron-only and hole-only devices for mobility measurements. After carrying out numerical simulations to examine the validity of this method for mobility determination, the dependence of the mobility balance on the mixing ratio of the electron-donor and –acceptor materials is presented.


2009 ◽  
Vol 1211 ◽  
Author(s):  
Yoshinori Nishikitani ◽  
Takaya Kubo ◽  
Hideki Masuda

AbstractNew materials and structures have been developed for efficient organic solar cells, dye-sensitized solar cells (DCSs) and organic thin-film solar cells (OPVs). Some strategies for achieving high photon-to-electricity conversion efficiency in these solar cells are discussed, focusing on nanostructured materials. In the case of DSCs, unlike TiO2 nanoparticles, TiO2 nanotubes with suitable dimensions are expected to work as efficient light scatterers as well as to give large surface areas for charge separation. A strategy for designing triarylamine-functionalized ruthenium dyes, which display the high efficiency, is also proposed. Furthermore, OPVs based on donor/acceptor (D/A) block copolymers are discussed, focusing on the phase separation of donor and acceptor segments and their domain sizes.


Nano Energy ◽  
2019 ◽  
Vol 66 ◽  
pp. 104176 ◽  
Author(s):  
Zhaozhao Bi ◽  
Hafiz Bilal Naveed ◽  
Xinyu Sui ◽  
Qinglian Zhu ◽  
Xianbin Xu ◽  
...  

2020 ◽  
Vol 13 (7) ◽  
pp. 2134-2141 ◽  
Author(s):  
Dingqin Hu ◽  
Qianguang Yang ◽  
Haiyan Chen ◽  
Friso Wobben ◽  
Vincent M. Le Corre ◽  
...  

A fullerene additive adjusts the miscibility between donor and acceptor for morphology optimization and reduces bimolecular recombination, assisting significant improvement of fill factor and efficiency.


2013 ◽  
Vol 4 ◽  
pp. 680-689 ◽  
Author(s):  
Gisela L Schulz ◽  
Marta Urdanpilleta ◽  
Roland Fitzner ◽  
Eduard Brier ◽  
Elena Mena-Osteritz ◽  
...  

The optimization of solution-processed organic bulk-heterojunction solar cells with the acceptor-substituted quinquethiophene DCV5T-Bu 4 as donor in conjunction with PC61BM as acceptor is described. Power conversion efficiencies up to 3.0% and external quantum efficiencies up to 40% were obtained through the use of 1-chloronaphthalene as solvent additive in the fabrication of the photovoltaic devices. Furthermore, atomic force microscopy investigations of the photoactive layer gave insight into the distribution of donor and acceptor within the blend. The unique combination of solubility and thermal stability of DCV5T-Bu 4 also allows for fabrication of organic solar cells by vacuum deposition. Thus, we were able to perform a rare comparison of the device characteristics of the solution-processed DCV5T-Bu 4 :PC61BM solar cell with its vacuum-processed DCV5T-Bu 4 :C60 counterpart. Interestingly in this case, the efficiencies of the small-molecule organic solar cells prepared by using solution techniques are approaching those fabricated by using vacuum technology. This result is significant as vacuum-processed devices typically display much better performances in photovoltaic cells.


2019 ◽  
Vol 131 (43) ◽  
pp. 15678-15686 ◽  
Author(s):  
Cheng Li ◽  
Xianxin Wu ◽  
Xinyu Sui ◽  
Hongbo Wu ◽  
Chao Wang ◽  
...  

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