A mechanism study on the efficient conversion of cellulose to acetol over Sn–Co catalysts with low Sn content

2020 ◽  
Vol 22 (19) ◽  
pp. 6579-6587
Author(s):  
Xiaohao Liu ◽  
Xiaodong Liu ◽  
Haiyong Wang ◽  
Tianci Xiao ◽  
Ying Zhang ◽  
...  

Sn–Co/SiO2 with low Sn content can effectively catalyze cellulose conversion to acetol, but Sn–Ni/SiO2 cannot. The catalytic mechanism was studied systematically.

RSC Advances ◽  
2020 ◽  
Vol 10 (57) ◽  
pp. 34738-34751 ◽  
Author(s):  
Isabella Romeo ◽  
Fabrizio Olivito ◽  
Antonio Tursi ◽  
Vincenzo Algieri ◽  
Amerigo Beneduci ◽  
...  

Innovative and efficient conversion of cellulose in furan-based bio-oil and cellulose citrate.


2019 ◽  
Vol 655 ◽  
pp. 614-621 ◽  
Author(s):  
Xiaofeng Zhang ◽  
Qintie Lin ◽  
Haoyu Luo ◽  
Runlin Huang ◽  
Rongbo Xiao ◽  
...  

2019 ◽  
Vol 21 (20) ◽  
pp. 5647-5656 ◽  
Author(s):  
Xiaohao Liu ◽  
Xiaodong Liu ◽  
Guangyue Xu ◽  
Ying Zhang ◽  
Chenguang Wang ◽  
...  

61.6% yield of acetol was obtained by one pot conversion of cellulose using Ni–Sn/SiO2 catalysts, and the catalytic mechanism was studied.


RSC Advances ◽  
2015 ◽  
Vol 5 (59) ◽  
pp. 47488-47497 ◽  
Author(s):  
Xiuqin Dong ◽  
Ya’nan Zhang ◽  
Yongwei Xu ◽  
Minhua Zhang

MnO2and Mn2O3transform into each other, and the mixture acts as an electron relay to promote the generation of strong oxidizing agents and the catalytic oxidation of nitrobenzene during catalytic supercritical water oxidation.


Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1451
Author(s):  
Dequan Yu ◽  
Hao Fang ◽  
Peikai Qiu ◽  
Fancong Meng ◽  
Haixia Liu ◽  
...  

ZnS is a promising photocatalyst in water purification, whereas its low photon efficiency and poor visible-light response restrict its application. Constructing composites may help solve these problems. In this work, Ag2O was introduced to ZnS for the first time based on their energy band characteristics to form a novel ZnS/Ag2O composite photocatalyst. In the model reaction of degrading methylene blue, the as-designed catalyst exhibited high catalytic activity among a series of ZnS-based composite photocatalysts under similar conditions. The catalytic rate constant was up to 0.138 min−1, which is 27.4- and 15.6-times higher than those of ZnS and Ag2O. This composite degraded 92.4% methylene blue in 50 min, while the ratios were 31.9% and 68.8% for ZnS and Ag2O. Catalytic mechanism study based on photoluminescence and radical-scavenging experiments revealed that the enhanced photocatalytic activity was attributed to the composite structure of ZnS/Ag2O. The structure not only facilitated the separation and transmission of photogenerated carriers but also extended the light response range of the catalyst. The as-designed ZnS/Ag2O composite is promising in degrading organic pollutants in water.


Nanoscale ◽  
2020 ◽  
Vol 12 (25) ◽  
pp. 13249-13275 ◽  
Author(s):  
Zhaoping Shi ◽  
Xian Wang ◽  
Junjie Ge ◽  
Changpeng Liu ◽  
Wei Xing

A systematic summary of the acidic OER catalytic mechanism and catalysts is given, and some experimental phenomena are explained.


Polymer ◽  
2007 ◽  
Vol 48 (13) ◽  
pp. 3726-3731 ◽  
Author(s):  
Wei-Wei Han ◽  
Yi-Han Zhou ◽  
Quan Luo ◽  
Yuan Yao ◽  
Ze-Sheng Li

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