Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

2020 ◽  
Vol 22 (8) ◽  
pp. 2605-2612 ◽  
Author(s):  
Jikuan Qiu ◽  
Huiyong Wang ◽  
Yuling Zhao ◽  
Pengxin Guan ◽  
Zhiyong Li ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Catalytic Performance ◽  
Environmentally Benign ◽  
Coupling Reactions ◽  
Covalent Organic Frameworks ◽  
Hierarchically Porous ◽  
Highly Effective ◽  
Bond Formation Reactions

A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.

Double C–H Activation for the C–C bond Formation Reactions

2018 ◽  
Vol 15 (7) ◽  
pp. 882-903 ◽  
Author(s):  
Jialin Liu ◽  
Xiaoyu Xiong ◽  
Jie Chen ◽  
Yuntao Wang ◽  
Ranran Zhu ◽  
...  
Keyword(s):  
Molecular Design ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Hypervalent Iodine ◽  
Coupling Reactions ◽  
Bond Forming ◽  
Direct Functionalization ◽  
Catalyzed Reactions ◽  
Medium Ring ◽  
Bond Formation Reactions

Background: Among the numerous bond-forming patterns, C–C bond formation is one of the most useful tools for building molecules for the chemical industry as well as life sciences. Recently, one of the most challenging topics is the study of the direct coupling reactions via multiple C–H bond cleavage/activation processes. A number of excellent reviews on modern C–H direct functionalization have been reported by Bergman, Bercaw, Yu and others in recent years. Among the large number of available methodologies, Pdcatalyzed reactions and hypervalent iodine reagent mediated reactions represent the most popular metal and non-metal involved transformations. However, the comprehensive summary of the comparison of metal and non-metal mediated transformations is still not available. Objective: The review focuses on comparing these two types of reactions (Pd-catalyzed reactions and hypervalent iodine reagent mediated reactions) based on the ways of forming new C–C bonds, as well as the scope and limitations on the demonstration of their synthetic applications. Conclusion: Comparing the Pd-catalyzed strategies and hypervalent iodine reagent mediated methodologies for the direct C–C bond formation from activation of C-H bonds, we clearly noticed that both strategies are powerful tools for directly obtaining the corresponding pruducts. On one hand, the hypervalent iodine reagents mediated reactions are normally under mild conditions and give the molecular diversity without the presence of transition-metal, while the Pd-catalyzed approaches have a broader scope for the wide synthetic applications. On the other hand, unlike Pd-catalyzed C-C bond formation reactions, the study towards hypervalent iodine reagent mediated methodology mainly focused on the stoichiometric amount of hypervalent iodine reagent, while few catalytic reactions have been reported. Meanwhile, hypervalent iodine strategy has been proved to be more efficient in intramolecular medium-ring construction, while there are less successful examples on C(sp3)–C(sp3) bond formation. In summary, we have demonstrated a number of selected approaches for the formation of a new C–C bond under the utilization of Pd-catalyzed reaction conditions or hyperiodine reagents. The direct activations of sp2 or sp3 hybridized C–H bonds are believed to be important strategies for the future molecular design as well as useful chemical entity synthesis.

Fe–Nxmoiety-modified hierarchically porous carbons derived from porphyra for highly effective oxygen reduction reaction

2017 ◽  
Vol 5 (4) ◽  
pp. 1526-1532 ◽  
Author(s):  
Zhengping Zhang ◽  
Xinjin Gao ◽  
Meiling Dou ◽  
Jing Ji ◽  
Feng Wang
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Porous Carbon ◽  
Catalytic Performance ◽  
Reduction Reaction ◽  
Porous Carbons ◽  
Hierarchically Porous ◽  
Nitrogen Doped ◽  
Highly Effective ◽  
Excellent Catalytic Performance

Fe–Nxmoiety-modified nitrogen-doped hierarchically porous carbon, which is derived from porphyra, exhibits an excellent catalytic performance for oxygen reduction.

Palladium nanoparticles supported on agarose-functionalized magnetic nanoparticles of Fe3O4 as a recyclable catalyst for C–C bond formation via Suzuki–Miyaura, Heck–Mizoroki and Sonogashira–Hagihara coupling reactions

RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17060-17070 ◽  
Author(s):  
Habib Firouzabadi ◽  
Nasser Iranpoor ◽  
Mohammad Gholinejad ◽  
Samira Akbari ◽  
Neda Jeddi
Keyword(s):  
Magnetic Nanoparticles ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Recyclable Catalyst ◽  
Coupling Reactions ◽  
Functionalized Magnetic Nanoparticles ◽  
Bond Formation Reactions

Palladium nanoparticles supported on agarose functionalized Fe3O4 catalyzed C–C bond formation reactions.

Nickel–glycerol: an efficient, recyclable catalysis system for Suzuki cross coupling reactions using aryl diazonium salts

2016 ◽  
Vol 40 (2) ◽  
pp. 1564-1570 ◽  
Author(s):  
Jeevan Manohar Bhojane ◽  
Sachin Ashok Sarode ◽  
Jayashree Milind Nagarkar
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Environmentally Benign ◽  
Diazonium Salts ◽  
Coupling Reactions ◽  
Formation Reaction ◽  
Cross Coupling Reactions

A palladium free, chemoselective and environmentally benign protocol for a C–C bond formation reaction.

Efficient three-component coupling reactions catalyzed by Cu0-nanoparticles stabilized on modified montmorillonite

2014 ◽  
Vol 4 (4) ◽  
pp. 1047-1054 ◽  
Author(s):  
Bibek Jyoti Borah ◽  
Subrat Jyoti Borah ◽  
Lakshi Saikia ◽  
Dipak Kumar Dutta
Keyword(s):  
Catalytic Performance ◽  
Montmorillonite Clay ◽  
Environmentally Benign ◽  
Coupling Reactions ◽  
Modified Montmorillonite ◽  
Three Component Coupling

In situgeneration of Cu0-nanoparticles into the nanopores of environmentally benign modified montmorillonite clay and their catalytic performance in three component (A3) coupling reactions of aldehyde, amine and alkyne to synthesize propargylamines with excellent yields and selectivity.

Newly designed pyridine and piperidine based Ionic Liquids: Aggregation behavior in ESI-MS and catalytic activity in C C bond formation reactions

2018 ◽  
Vol 272 ◽  
pp. 84-91 ◽  
Author(s):  
Muhammad Naveed Javed ◽  
Shoaib Muhammad ◽  
Imran Ali Hashmi ◽  
Ahmed Bari ◽  
Syed Ghulam Musharraf ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Bond Formation ◽  
Aggregation Behavior ◽  
Esi Ms ◽  
Bond Formation Reactions

Basic Ionic Liquids: Facile Solvents for Carbon–Carbon Bond Formation Reactions and Ready Access to Palladium Nanoparticles

2007 ◽  
Vol 2007 (30) ◽  
pp. 5095-5100 ◽  
Author(s):  
Chengfeng Ye ◽  
Ji-Chang Xiao ◽  
Brendan Twamley ◽  
Aaron D. LaLonde ◽  
M. Grant Norton ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Ready Access ◽  
Bond Formation Reactions
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