Basic Ionic Liquids: Facile Solvents for Carbon–Carbon Bond Formation Reactions and Ready Access to Palladium Nanoparticles

2007 ◽  
Vol 2007 (30) ◽  
pp. 5095-5100 ◽  
Author(s):  
Chengfeng Ye ◽  
Ji-Chang Xiao ◽  
Brendan Twamley ◽  
Aaron D. LaLonde ◽  
M. Grant Norton ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Ready Access ◽  
Bond Formation Reactions

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

Regio- and Stereoselective Carbon—Carbon Bond Formation in Ionic Liquids

ChemInform ◽  
2005 ◽  
Vol 36 (1) ◽  
Author(s):  
Vincenzo Calo ◽  
Angelo Nacci ◽  
Antonio Monopoli
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond
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