Theoretical investigation of perfect fullerene-like borospherene Ih-B20 protected by alkaline earth metal: multi-layered spherical electride molecules as electric field manipulated second-order nonlinear optical switches

2020 ◽  
Vol 49 (43) ◽  
pp. 15267-15275
Author(s):  
Weihong Chen ◽  
Jing Li ◽  
Jiayuan Liu ◽  
Weiming Sun ◽  
Zhiru Li ◽  
...  

A perfect fullerene-like borospherene B20 with 12 B5 rings stabilized in the electride molecule (Mg2+)12&B2018− + 6e−.

2017 ◽  
Vol 46 (24) ◽  
pp. 7911-7916 ◽  
Author(s):  
Qi Wei ◽  
Li Sun ◽  
Jie Zhang ◽  
Guo-Yu Yang

Two non-centrosymmetric alkaline-earth metal borates were synthesized, showing the layered structures constructed from different oxoboron clusters and potentially new candidates for deep-UV NLO materials.


2020 ◽  
Vol 7 (19) ◽  
pp. 3674-3686
Author(s):  
Xianghe Meng ◽  
Kaijin Kang ◽  
Fei Liang ◽  
Jian Tang ◽  
Wenlong Yin ◽  
...  

Optimal arrangements of π-conjugated anions in alkaline earth metal hydro-isocyanurates with rich structures result in large birefringence and a giant nonlinear optical effect.


2019 ◽  
Vol 6 (8) ◽  
pp. 2200-2208 ◽  
Author(s):  
Zixiu Lu ◽  
Fangfang Zhang ◽  
Abudukadi Tudi ◽  
Sujuan Yu ◽  
Zhihua Yang ◽  
...  

The first complex alkaline-earth metal borosilicate chloride, Ba3Ca4(BO3)3(SiO4)Cl, as a potential ultraviolet nonlinear optical material.


2016 ◽  
Vol 4 (35) ◽  
pp. 8189-8196 ◽  
Author(s):  
Chao Wu ◽  
Junling Song ◽  
Longhua Li ◽  
Mark G. Humphrey ◽  
Chi Zhang

A new deep-UV nonlinear optical borate, with the formula LiBa3(OH)(B9O16)[B(OH)4] is synthesized using a facile hydrothermal method.


2017 ◽  
Vol 5 (29) ◽  
pp. 7230-7235 ◽  
Author(s):  
Congxin Xia ◽  
Qiang Gao ◽  
Wenqi Xiong ◽  
Juan Du ◽  
Xu Zhao ◽  
...  

In X(OH)2/graphene (X = Ca, Mg) vdW heterostructures, the Schottky barrier height and contact types are effectively tuned by electric fields.


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