Ba3Ca4(BO3)3(SiO4)Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

2019 ◽  
Vol 6 (8) ◽  
pp. 2200-2208 ◽  
Author(s):  
Zixiu Lu ◽  
Fangfang Zhang ◽  
Abudukadi Tudi ◽  
Sujuan Yu ◽  
Zhihua Yang ◽  
...  

The first complex alkaline-earth metal borosilicate chloride, Ba3Ca4(BO3)3(SiO4)Cl, as a potential ultraviolet nonlinear optical material.

2017 ◽  
Vol 46 (24) ◽  
pp. 7911-7916 ◽  
Author(s):  
Qi Wei ◽  
Li Sun ◽  
Jie Zhang ◽  
Guo-Yu Yang

Two non-centrosymmetric alkaline-earth metal borates were synthesized, showing the layered structures constructed from different oxoboron clusters and potentially new candidates for deep-UV NLO materials.


2016 ◽  
Vol 4 (35) ◽  
pp. 8189-8196 ◽  
Author(s):  
Chao Wu ◽  
Junling Song ◽  
Longhua Li ◽  
Mark G. Humphrey ◽  
Chi Zhang

A new deep-UV nonlinear optical borate, with the formula LiBa3(OH)(B9O16)[B(OH)4] is synthesized using a facile hydrothermal method.


2019 ◽  
Vol 6 (4) ◽  
pp. 914-919 ◽  
Author(s):  
Qiong Liu ◽  
Cong Hu ◽  
Xin Su ◽  
Maierhaba Abudoureheman ◽  
Shilie Pan ◽  
...  

LiGeBO4 is found to be a material that can balance a large band gap (>6.2 eV) and strong SHG coefficient (2 × KDP), which is rarely seen in tetrahedral-based crystals.


2018 ◽  
Vol 6 (45) ◽  
pp. 12240-12244 ◽  
Author(s):  
Yanqiang Li ◽  
Sangen Zhao ◽  
Pai Shan ◽  
Xianfeng Li ◽  
Qingran Ding ◽  
...  

A new sulfate Li8NaRb3(SO4)6·2H2O exhibits a short cutoff edge below λ < 190 nm and has a moderate second-harmonic generation response in type-I phase-matchable behavior.


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