Metal–organic frameworks as acid- and/or base-functionalized catalysts for tandem reactions

2020 ◽  
Vol 49 (42) ◽  
pp. 14723-14730
Author(s):  
Yingying Zhang ◽  
Chao Huang ◽  
Liwei Mi
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Tandem Reactions ◽  
Domino Reactions ◽  
Basic Sites ◽  
The Past ◽  
Metal Organic

In this article, we have reviewed the development of MOFs anchored with acidic and/or basic sites as heterogeneous catalysts for tandem/cascade (domino) reactions over the past five years.

An Overview of Metal-organic Frameworks-based Acid/Base Catalysts for Biofuel Synthesis

2020 ◽  
Vol 24 (16) ◽  
pp. 1876-1891
Author(s):  
Qiuyun Zhang ◽  
Yutao Zhang ◽  
Jingsong Cheng ◽  
Hu Li ◽  
Peihua Ma
Keyword(s):  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Supported Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Flexible Structures ◽  
Biodiesel Production ◽  
Biodiesel Synthesis ◽  
Metal Organic ◽  
Organic Framework

Biofuel synthesis is of great significance for producing alternative fuels. Among the developed catalytic materials, the metal-organic framework-based hybrids used as acidic, basic, or supported catalysts play major roles in the biodiesel production. This paper presents a timely and comprehensive review of recent developments on the design and preparation of metal-organic frameworks-based catalysts used for biodiesel synthesis from various oil feedstocks, including MILs-based catalysts, ZIFs-based catalysts, UiO-based catalysts, Cu-BTC-based catalysts, and MOFs-derived porous catalysts. Due to their unique and flexible structures, excellent thermal and hydrothermal stability, and tunable host-guest interactions, as compared with other heterogeneous catalysts, metal-organic framework-based catalysts have good opportunities for application in the production of biodiesel at industrial scale.

Metal–organic frameworks as catalytic selectivity regulators for organic transformations

2021 ◽  
Author(s):  
Jun Guo ◽  
Yutian Qin ◽  
Yanfei Zhu ◽  
Xiaofei Zhang ◽  
Chang Long ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Research Topic ◽  
Organic Transformations ◽  
Catalytic Selectivity ◽  
Challenging Research ◽  
Metal Organic

Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based heterogeneous catalysts have been an intriguing but challenging research topic in both the chemistry and materials communities.

Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

2021 ◽  
Author(s):  
Panyapat Ponchai ◽  
Kanyaporn Adpakpang ◽  
Sareeya Bureekaew
Keyword(s):  
Hydrogen Peroxide ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Porous Structures ◽  
Cyclohexene Oxidation ◽  
Catalytic Sites ◽  
P Utilization ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

Cu(I)-Based Metal–Organic Frameworks as Efficient and Recyclable Heterogeneous Catalysts for Aqueous-Medium C–H Oxidation

2018 ◽  
Vol 19 (2) ◽  
pp. 976-982 ◽  
Author(s):  
Kuan Gao ◽  
Chao Huang ◽  
Yisen Yang ◽  
Hong Li ◽  
Jie Wu ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Achieving blue-excitable yellow-emitting Ca-LMOF phosphor via water induced phase transformation

2022 ◽  
Author(s):  
Zhao-Feng Wu ◽  
Bin Tan ◽  
Zhi-Hua Fu ◽  
Ever Velasco ◽  
Xingwu Liu ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Metal Organic Frameworks ◽  
The Past ◽  
Metal Organic

Luminescent metal organic frameworks (LMOFs) with diverse structure features and promising fluorescence-based applications have attracted a wide attention in the past two decades. In this work, a LMOF with formula...

Heterogeneous catalytic wet peroxide oxidation of simulated phenol wastewater by copper metal–organic frameworks

RSC Advances ◽  
2015 ◽  
Vol 5 (41) ◽  
pp. 32795-32803 ◽  
Author(s):  
Kai Huang ◽  
Yang Xu ◽  
Lianguang Wang ◽  
Dongfang Wu
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Peroxide Oxidation ◽  
Copper Metal ◽  
Heterogeneous Catalytic ◽  
Wet Peroxide Oxidation ◽  
Porous Copper ◽  
Metal Organic ◽  
Catalytic Wet Peroxide Oxidation ◽  
Phenol Wastewater

Two different porous copper metal–organic frameworks (Cu-MOFs) named as Cu3(BTC)2 and Cu(BDC) were synthesized and applied as heterogeneous catalysts for the catalytic wet peroxide oxidation (CWPO) of simulated phenol wastewater (100 mg L−1).

Recent advances in biomolecule immobilization based on self-assembly: organic–inorganic hybrid nanoflowers and metal–organic frameworks as novel substrates

2018 ◽  
Vol 6 (11) ◽  
pp. 1581-1594 ◽  
Author(s):  
Zhixian Lei ◽  
Chenling Gao ◽  
Lei Chen ◽  
Yanting He ◽  
Wende Ma ◽  
...  
Keyword(s):  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Inorganic Hybrid ◽  
The Past ◽  
Biomolecule Immobilization ◽  
Recent Advances ◽  
Metal Organic

In the past few years, the immobilization of biomolecules on hybrid nanoflowers and metal–organic frameworks (MOFs) via self-assembly synthesis has received much attention due to its superior advantages.

Cu and Au Metal-Organic Frameworks Bridge the Gap between Homogeneous and Heterogeneous Catalysts for Alkene Cyclopropanation Reactions

2010 ◽  
Vol 16 (32) ◽  
pp. 9789-9795 ◽  
Author(s):  
Avelino Corma ◽  
Marta Iglesias ◽  
Francesc X. Llabrés i Xamena ◽  
Félix Sánchez
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Metal Organic
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