A facile biomimetic catalytic activity through hydrogen atom abstraction by the secondary coordination sphere in manganese(iii) complexes

2020 ◽  
Vol 49 (40) ◽  
pp. 14216-14230
Author(s):  
Narayan Ch. Jana ◽  
Paula Brandão ◽  
Antonio Frontera ◽  
Anangamohan Panja
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Hydrogen Atom ◽  
Coordination Sphere ◽  
Hydrogen Atom Abstraction ◽  
Schiff Base Ligands ◽  
Secondary Coordination Sphere ◽  
Catalytic Reactivity ◽  
Hydrogen Bonded

Four hydrogen bonded supramolecular manganese(iii) complexes with N3O donor Schiff base ligands and a facile biomimetic catalytic reactivity through hydrogen atom abstraction by the secondary coordination sphere have been reported.

Some new Schiff base ligands giving a NNOS coordination sphere and their nickel(II) complexes: Synthesis, characterization and complex formation

Polyhedron ◽  
2009 ◽  
Vol 28 (8) ◽  
pp. 1409-1418 ◽  
Author(s):  
Mozaffar Asadi ◽  
Khosro Mohammadi ◽  
Sheida Esmaielzadeh ◽  
Bijan Etemadi ◽  
Hoon Kun Fun
Keyword(s):  
Schiff Base ◽  
Complex Formation ◽  
Coordination Sphere ◽  
Schiff Base Ligands

Synthesis, structure, and catalytic activity of organolanthanide complexes with chiral biaryl Schiff-base ligands

2014 ◽  
Vol 758 ◽  
pp. 65-72 ◽  
Author(s):  
Wenshan Ren ◽  
Liang Chen ◽  
Ning Zhao ◽  
Qiuwen Wang ◽  
Guohua Hou ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Schiff Base Ligands

Two palladium(II) complexes based on Schiff base ligands: synthesis, characterization, luminescence, and catalytic activity

2013 ◽  
Vol 38 (3) ◽  
pp. 299-305 ◽  
Author(s):  
Hai-Fu Guo ◽  
Xin Zhao ◽  
De-Yun Ma ◽  
Ai-Ping Xie ◽  
Wei-Bo Shen
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Schiff Base Ligands

Hydrogen Atom Abstraction Kinetics from Intramolecularly Hydrogen Bonded Ubiquinol-0 and Other (Poly)methoxy Phenols

2000 ◽  
Vol 122 (10) ◽  
pp. 2355-2360 ◽  
Author(s):  
Martine I. de Heer ◽  
Peter Mulder ◽  
Hans-Gert Korth ◽  
Keith U. Ingold ◽  
Janusz Lusztyk
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Abstraction ◽  
Hydrogen Bonded

The effect of Schiff base ligands on the structure and catalytic activity of cobalt complexes in hydrosilylation of olefins

2020 ◽  
Vol 602 ◽  
pp. 117665
Author(s):  
Aleksandra Bocian ◽  
Maciej Skrodzki ◽  
Maciej Kubicki ◽  
Adam Gorczyński ◽  
Piotr Pawluć ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Cobalt Complexes ◽  
Schiff Base Ligands

scholarly journals Crystal structure of bis(2-{[(pyridin-2-yl)methylidene]amino}benzoato-κ3N,N′,O)cobalt(II)N,N-dimethylformamide sesquisolvate

2014 ◽  
Vol 70 (10) ◽  
pp. 164-166 ◽  
Author(s):  
Elena A. Buvaylo ◽  
Vladimir N. Kokozay ◽  
Olga Yu. Vassilyeva ◽  
Brian W. Skelton
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Schiff Base ◽  
Coordination Sphere ◽  
Anthranilic Acid ◽  
Crystal Packing ◽  
Schiff Base Ligands ◽  
Complex Molecules ◽  
Hydrogen Bonding Interactions ◽  
Solvent Molecules

The title compound, [Co(C13H9N2O2)2]·1.5C3H7NO, is formed as a neutral CoIIcomplex with dimethylformamide (DMF) solvent molecules. The CoIIatom has a distorted O2N4octahedral coordination sphere defined by two tridentate anionic Schiff base ligands with the O atoms beingcis. The coordination sphere around the CoIIatom is geometrically different from that reported for the co-crystal [Co(C13H9N2O2)2]·AA·H2O (AA is anthranilic acid). One of the DMF solvent molecules was modelled as being disordered about a crystallographic inversion centre with half-occupancy. The crystal structure is made up from alternating layers of complex molecules and DMF molecules parallel to (010). C—H...O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing.

Synthesis and catalytic activity of heterogeneous rare-earth metal catalysts coordinated with multitopic Schiff-base ligands

2012 ◽  
Vol 41 (32) ◽  
pp. 9682 ◽  
Author(s):  
Yilin Sun ◽  
Guangming Wu ◽  
Dinghai Cen ◽  
Yaofeng Chen ◽  
Limin Wang
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Metal Catalysts ◽  
Schiff Base Ligands
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