Solid-state 1D → 3D transformation of polynitrile-based coordination polymers by dehydration reaction

2020 ◽  
Vol 49 (21) ◽  
pp. 7084-7092
Author(s):  
Artem O. Dmitrienko ◽  
Mikhail I. Buzin ◽  
Zouaoui Setifi ◽  
Fatima Setifi ◽  
Eugeny V. Alexandrov ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Topological Analysis ◽  
Dehydration Reaction

The first topological analysis of solid-state transformations caused by the dehydration reaction and rearrangement of a flexible polytopic ligand is reported.

scholarly journals Solid-state thermal degradation behaviour of 1-D coordination polymers of Ni(II) and Cu(II) bridged by conjugated ligand

2013 ◽  
Vol 114 (2) ◽  
pp. 653-664 ◽  
Author(s):  
Ram Lakhan Prasad ◽  
Anita Kushwaha ◽  
Rajesh Kumar ◽  
Imre Miklós Szilágyi ◽  
László Kótai
Keyword(s):  
Solid State ◽  
Thermal Degradation ◽  
Coordination Polymers ◽  
Degradation Behaviour

scholarly journals Topological Analysis of the Electron Density Illustrating the Stabilizing Interactions in Some Basic Solid-state Systems

2019 ◽  
Vol 7 (2) ◽  
pp. 115 ◽  
Author(s):  
James Tembei Titah ◽  
Franklin Che Ngwa ◽  
Peter Sirsch ◽  
Coulibaly Wacothon Karime ◽  
Mamadou Guy-Richard Kone
Keyword(s):  
Solid State ◽  
Electron Density ◽  
Topological Analysis

ChemInform Abstract: Structures, Spectroscopic Studies and Solid-State Thermal Transformations of Coordination Polymers from P4Se3 and CuX (X: Cl, Br, I).

ChemInform ◽  
2011 ◽  
Vol 42 (42) ◽  
pp. no-no
Author(s):  
Andreas Biegerl ◽  
Christian Groeger ◽  
Hans R. Kalbitzer ◽  
Arno Pfitzner ◽  
Joachim Wachter ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Spectroscopic Studies ◽  
Thermal Transformations

scholarly journals Different Benzendicarboxylate-Directed Structural Variations and Properties of Four New Porous Cd(II)-Pyridyl-Triazole Coordination Polymers

2020 ◽  
Vol 8 ◽  
Author(s):  
Ying Zhao ◽  
Jin Jing ◽  
Ning Yan ◽  
Min-Le Han ◽  
Guo-Ping Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Gas Sorption ◽  
Structural Variations ◽  
Benzenedicarboxylic Acid ◽  
Topological Framework ◽  
The Stability

Four new different porous crystalline Cd(II)-based coordination polymers (CPs), i. e., [Cd(mdpt)2]·2H2O (1), [Cd2(mdpt)2(m-bdc)(H2O)2] (2), [Cd(Hmdpt)(p-bdc)]·2H2O (3), and [Cd3(mdpt)2(bpdc)2]·2.5NMP (4), were obtained successfully by the assembly of Cd(II) ions and bitopic 3-(3-methyl-2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (Hmdpt) in the presence of various benzendicarboxylate ligands, i.e., 1,3/1,4-benzenedicarboxylic acid (m-H2bdc, p-H2bdc) and biphenyl-4,4′-bicarboxylate (H2bpdc). Herein, complex 1 is a porous 2-fold interpenetrated four-connected 3D NbO topological framework based on the mdpt− ligand; 2 reveals a two-dimensional (2D) hcb network. Interestingly, 3 presents a three-dimensional (3D) rare interpenetrated double-insertion supramolecular net via 2D ···ABAB··· layers and can be viewed as an fsh topological net, while complex 4 displays a 3D sqc117 framework. Then, the different gas sorption performances were carried out carefully for complexes 1 and 4, the results of which showed 4 has preferable sorption than that of 1 and can be the potential CO2 storage and separation material. Furthermore, the stability and luminescence of four complexes were performed carefully in the solid state.

The mechanochemical conversion of potassium coordination polymer nanostructures to interpenetrated sodium coordination polymers with halogen bond, metal–carbon and metal–metal interactions

CrystEngComm ◽  
2020 ◽  
Vol 22 (5) ◽  
pp. 888-894 ◽  
Author(s):  
Ashkan Kianimehr ◽  
Kamran Akhbari ◽  
Jonathan White ◽  
Anukorn Phuruangrat
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Halogen Bond ◽  
Metal Interactions ◽  
Polymer Nanostructures ◽  
Hydrogen Bonding Interactions ◽  
Metal Metal

Two new Na and K coordination polymers with halogen bond, metallophilic and hydrogen bonding interactions were synthesized. These two compounds were synthesized sonochemically and solid-state conversions of them to each other were investigated.

Solid-State Reactivity of Supramolecular Isomers: A Study of the s-Block Coordination Polymers

2014 ◽  
Vol 14 (5) ◽  
pp. 2605-2613 ◽  
Author(s):  
Anjana Chanthapally ◽  
Hong Sheng Quah ◽  
Jagadese J. Vittal
Keyword(s):  
Solid State ◽  
Coordination Polymers
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