scholarly journals Kinetic data acquisition in high-throughput Fischer–Tropsch experimentation

2020 ◽  
Vol 10 (21) ◽  
pp. 7331-7343
Author(s):  
Paul Hazemann ◽  
Dominique Decottignies ◽  
Sylvie Maury ◽  
Séverine Humbert ◽  
Adrien Berliet ◽  
...  
Keyword(s):  
Data Acquisition ◽  
Chemical Reactions ◽  
High Throughput ◽  
Kinetic Data ◽  
Fischer Tropsch ◽  
Syngas Conversion ◽  
High Throughput Experimentation ◽  
Rapid Data Acquisition

The emergence of high-throughput experimentation gives new opportunities for accurate and rapid data acquisition for a wide variety of chemical reactions in different fields of application such as hydrocracking, isomerization and syngas conversion.

Voltammetric Studies of Some Novel Fe(III) Complexes with Quadridentate Ligands. The Axial Ligand-Exchange Reactions in DMF and DMSO

1995 ◽  
Vol 60 (7) ◽  
pp. 1140-1157 ◽  
Author(s):  
Ljiljana S. Jovanovic ◽  
Luka J. Bjelica
Keyword(s):  
Oxidation State ◽  
Chemical Reactions ◽  
Ligand Exchange ◽  
Kinetic Data ◽  
Central Atom ◽  
Axial Ligand ◽  
Exchange Reactions ◽  
Ligand Effect ◽  
Condensation Products ◽  
Voltammetric Studies

The electrochemistry of four novel Fe(III) complexes of the type [Fe(L)Cl], involving quadridentate ligands based on the condensation products of benzoylacetone-S-methylisothiosemicarbazone with salicylaldehyde, 5-chlorosalicylaldehyde, 3,5-dichlorosalicylaldehyde or 5-nitrosalicylaldehyde, was studied in DMF and DMSO at a GC electrode. All complexes undergo a two-step one-electron reductions, usually complicated by chemical reactions. In solutions containing Cl-, the ligand-exchange reactions Cl--DMF and Cl--DMSO take place. Stability of the chloride-containing complexes was discussed in terms of the coordinated ligand effect, oxidation state of the central atom and, in particular, of the donor effect of the solvent. Some relevant kinetic data were calculated.

scholarly journals Titanium Complexes with Functional Alkoxido Ligands for Selective Ethylene Dimerization – A High Throughput Experimentation Approach

ChemCatChem ◽  
2021 ◽  
Author(s):  
Fabien L. Grasset ◽  
Richard Welter ◽  
Pierre Braunstein ◽  
Hélène Olivier‐Bourbigou ◽  
Lionel Magna
Keyword(s):  
High Throughput ◽  
Titanium Complexes ◽  
Ethylene Dimerization ◽  
High Throughput Experimentation

scholarly journals Unlocking the Potential of High-Throughput Experimentation for Electrochemistry with a Standardized Microscale Reactor

2021 ◽  
Author(s):  
Jonas Rein ◽  
James R. Annand ◽  
Michael K. Wismer ◽  
Jiantao Fu ◽  
Juno C. Siu ◽  
...  
Keyword(s):  
High Throughput ◽  
High Throughput Experimentation

scholarly journals Preparation and High-Throughput Testing of TiO2-Supported Co Catalysts for Fischer‒Tropsch Synthesis

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 352
Author(s):  
Christian Schulz ◽  
Peter Kolb ◽  
Dennis Krupp ◽  
Lars Ritter ◽  
Alfred Haas ◽  
...  
Keyword(s):  
High Throughput ◽  
Anatase Phase ◽  
Rutile Phase ◽  
Tropsch Synthesis ◽  
Performance Tests ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Co Catalysts ◽  
Impregnation Technique ◽  
Co Conversion

A series of Co/TiO2 catalysts was tested in a parameters field study for Fischer‒Tropsch synthesis (FTS). All catalysts were prepared by the conventional impregnation technique to obtain an industrially relevant Co content of 10 wt % or 20 wt %, respectively. In summary, 10 different TiO2 of pure anatase phase, pure rutile phase, as well as mixed rutile and anatase phase were used as supports. Performance tests were conducted with a 32-fold high-throughput setup for accelerated catalyst benchmarking; thus, 48 experiments were completed within five weeks in a relevant operation parameters field (170 °C to 233.5 °C, H2/CO ratio 1 to 2.5, and 20 bar(g)). The most promising catalyst showed a CH4 selectivity of 5.3% at a relevant CO conversion of 60% and a C5+ productivity of 2.1 gC5+/(gCo h) at 207.5 °C. These TiO2-based materials were clearly differentiated with respect to the application as supports in Co-catalyzed FTS catalysis. The most prospective candidates are available for further FTS optimization at a commercial scale.

ChemInform Abstract: High Throughput Experimentation for the Synthesis of New Crystalline Microporous Solids.

ChemInform ◽  
2010 ◽  
Vol 33 (13) ◽  
pp. no-no
Author(s):  
John M. Newsam ◽  
Thomas Bein ◽  
Jens Klein ◽  
Wilhelm F. Maier ◽  
Wolfram Stichert
Keyword(s):  
High Throughput ◽  
High Throughput Experimentation ◽  
Microporous Solids

High throughput experimentation in oxidation catalysis: Higher integration and “intelligent” software

2006 ◽  
Vol 117 (1-3) ◽  
pp. 284-290 ◽  
Author(s):  
F SCHUTH ◽  
L BAUMES ◽  
F CLERC ◽  
D DEMUTH ◽  
D FARRUSSENG ◽  
...  
Keyword(s):  
High Throughput ◽  
Oxidation Catalysis ◽  
Intelligent Software ◽  
High Throughput Experimentation
Sign in / Sign up

Export Citation Format

Share Document