scholarly journals Six-flow operations for catalyst development in Fischer-Tropsch synthesis: Bridging the gap between high-throughput experimentation and extensive product evaluation

2013 ◽  
Vol 84 (12) ◽  
pp. 124101 ◽  
Author(s):  
Sina Sartipi ◽  
Harrie Jansma ◽  
Duco Bosma ◽  
Bart Boshuizen ◽  
Michiel Makkee ◽  
...  
Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 352
Author(s):  
Christian Schulz ◽  
Peter Kolb ◽  
Dennis Krupp ◽  
Lars Ritter ◽  
Alfred Haas ◽  
...  

A series of Co/TiO2 catalysts was tested in a parameters field study for Fischer‒Tropsch synthesis (FTS). All catalysts were prepared by the conventional impregnation technique to obtain an industrially relevant Co content of 10 wt % or 20 wt %, respectively. In summary, 10 different TiO2 of pure anatase phase, pure rutile phase, as well as mixed rutile and anatase phase were used as supports. Performance tests were conducted with a 32-fold high-throughput setup for accelerated catalyst benchmarking; thus, 48 experiments were completed within five weeks in a relevant operation parameters field (170 °C to 233.5 °C, H2/CO ratio 1 to 2.5, and 20 bar(g)). The most promising catalyst showed a CH4 selectivity of 5.3% at a relevant CO conversion of 60% and a C5+ productivity of 2.1 gC5+/(gCo h) at 207.5 °C. These TiO2-based materials were clearly differentiated with respect to the application as supports in Co-catalyzed FTS catalysis. The most prospective candidates are available for further FTS optimization at a commercial scale.


2014 ◽  
Vol 4 (8) ◽  
pp. 2210-2229 ◽  
Author(s):  
Hessam Jahangiri ◽  
James Bennett ◽  
Parvin Mahjoubi ◽  
Karen Wilson ◽  
Sai Gu

2015 ◽  
Vol 6 (2) ◽  
pp. 935-944 ◽  
Author(s):  
Paul Boldrin ◽  
James R. Gallagher ◽  
Gary B. Combes ◽  
Dan I. Enache ◽  
David James ◽  
...  

High-throughput XRD and TGA are used to screen hundreds of candidate Fischer–Tropsch synthesis catalyst samples per month for particle size, reducibility and stability under operating conditions. A series of highly stable catalysts based on Co-Ru-Mg-Al2O3 are identified.


2010 ◽  
Vol 31 (8) ◽  
pp. 919-927 ◽  
Author(s):  
Yuhan SUN ◽  
Jiangang CHEN ◽  
Jungang WANG ◽  
Litao JIA ◽  
Bo HOU ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document