scholarly journals Tuning the transition barrier of H2 dissociation in the hydrogenation of CO2 to formic acid on Ti-doped Sn2O4 clusters

2021 ◽  
Vol 23 (1) ◽  
pp. 204-210
Author(s):  
Plaban J. Sarma ◽  
Dikshita Dowerah ◽  
Nand K. Gour ◽  
Andrew J. Logsdail ◽  
C. Richard A. Catlow ◽  
...  

Schematic representation of Ti-doping on a pure Sn2O4 cluster for the hydrogenation of CO2 to HCOOH via a hydride pathway.

2021 ◽  
Vol 23 (5) ◽  
pp. 1978-1982
Author(s):  
Zhaofu Zhang ◽  
Shuaishuai Liu ◽  
Minqiang Hou ◽  
Guangying Yang ◽  
Buxing Han

Continuous-flow formic acid production from the hydrogenation of CO2 without any base, and the concentration of formic acid by electrodialysis was tested both offline and online.


2016 ◽  
Vol 3 (7) ◽  
pp. 882-895 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Kwangho Park ◽  
Kwang-Deog Jung ◽  
Sungho Yoon

This review highlights the recent trends in the heterogeneous hydrogenation of CO2 to formic acid/formate.


2016 ◽  
Vol 6 (2) ◽  
pp. 404-408 ◽  
Author(s):  
S. Oldenhof ◽  
J. I. van der Vlugt ◽  
J. N. H. Reek

Catalytic hydrogenation of CO2 to formate with an IrIII(METAMORPhos) complex in the presence of DBU requires a trans-dihydride for catalytic turnover, with an off-cycle trihydride as the dormant species.


2016 ◽  
Vol 18 (16) ◽  
pp. 4553-4558 ◽  
Author(s):  
Sheng-Mei Lu ◽  
Zhijun Wang ◽  
Jun Li ◽  
Jianliang Xiao ◽  
Can Li

Hydrogenation of CO2 in the absence of a base in water is achieved with high activity using an iridium complex bearing a non-aromatic N,N′-diimine ligand.


2015 ◽  
Vol 51 (7) ◽  
pp. 1271-1274 ◽  
Author(s):  
Zhen-Zhen Yang ◽  
Hongye Zhang ◽  
Bo Yu ◽  
Yanfei Zhao ◽  
Guipeng Ji ◽  
...  

Efficient CO2/H2 adsorption and subsequent hydrogenation of CO2 to HCOOH were realized adopting a Tröger's base-functionalized microporous organic polymer.


2021 ◽  
pp. 149-177
Author(s):  
Kwangho Park ◽  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon

2021 ◽  
Vol 54 ◽  
pp. 101751
Author(s):  
Jiehong He ◽  
Shaoshuai Chang ◽  
Haoran Du ◽  
Bo Jiang ◽  
Wenzhao Yu ◽  
...  

2019 ◽  
Vol 43 (35) ◽  
pp. 13985-13997 ◽  
Author(s):  
Claire E. Mitchell ◽  
Umberto Terranova ◽  
Ihfaf Alshibane ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  

We report the development of palladium nanoparticles supported on Mo2C as an active catalyst for the liquid-phase hydrogenation of CO2 to formate under mild reaction conditions (100 °C and 2.0 MPa of a 1 : 1 CO2 : H2 mixture).


2019 ◽  
Vol 488 ◽  
pp. 1-9 ◽  
Author(s):  
Junmei Ma ◽  
Hongwei Gong ◽  
Tong Zhang ◽  
Hong Yu ◽  
Rong Zhang ◽  
...  

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