scholarly journals Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species

2016 ◽  
Vol 6 (2) ◽  
pp. 404-408 ◽  
Author(s):  
S. Oldenhof ◽  
J. I. van der Vlugt ◽  
J. N. H. Reek
Keyword(s):  
Formic Acid ◽  
Catalytic Hydrogenation ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

Catalytic hydrogenation of CO2 to formate with an IrIII(METAMORPhos) complex in the presence of DBU requires a trans-dihydride for catalytic turnover, with an off-cycle trihydride as the dormant species.

Recent developments in the catalytic hydrogenation of CO2 to formic acid/formate using heterogeneous catalysts

2016 ◽  
Vol 3 (7) ◽  
pp. 882-895 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Kwangho Park ◽  
Kwang-Deog Jung ◽  
Sungho Yoon
Keyword(s):  
Formic Acid ◽  
Catalytic Hydrogenation ◽  
Heterogeneous Catalysts ◽  
Hydrogenation Of Co2 ◽  
Recent Developments ◽  
Recent Trends ◽  
Heterogeneous Hydrogenation ◽  
Hydrogenation Of Co

This review highlights the recent trends in the heterogeneous hydrogenation of CO2 to formic acid/formate.

Continuous-flow formic acid production from the hydrogenation of CO2 without any base

2021 ◽  
Vol 23 (5) ◽  
pp. 1978-1982
Author(s):  
Zhaofu Zhang ◽  
Shuaishuai Liu ◽  
Minqiang Hou ◽  
Guangying Yang ◽  
Buxing Han
Keyword(s):  
Formic Acid ◽  
Continuous Flow ◽  
Acid Production ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

Continuous-flow formic acid production from the hydrogenation of CO2 without any base, and the concentration of formic acid by electrodialysis was tested both offline and online.

Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

2020 ◽  
Vol 7 (9) ◽  
pp. 1845-1850
Author(s):  
Jonghoon Choi ◽  
Yunho Lee
Keyword(s):  
Catalytic Hydrogenation ◽  
Catalytic Performance ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co ◽  
Cobalt Center

Catalytic hydrogenation of CO2 occurs at a cobalt center supported by a rigidified PNP ligand revealing higher catalytic performance.

Base-free hydrogenation of CO2 to formic acid in water with an iridium complex bearing a N,N′-diimine ligand

2016 ◽  
Vol 18 (16) ◽  
pp. 4553-4558 ◽  
Author(s):  
Sheng-Mei Lu ◽  
Zhijun Wang ◽  
Jun Li ◽  
Jianliang Xiao ◽  
Can Li
Keyword(s):  
Formic Acid ◽  
High Activity ◽  
Iridium Complex ◽  
Hydrogenation Of Co2 ◽  
Diimine Ligand ◽  
Hydrogenation Of Co

Hydrogenation of CO2 in the absence of a base in water is achieved with high activity using an iridium complex bearing a non-aromatic N,N′-diimine ligand.

A Tröger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

2015 ◽  
Vol 51 (7) ◽  
pp. 1271-1274 ◽  
Author(s):  
Zhen-Zhen Yang ◽  
Hongye Zhang ◽  
Bo Yu ◽  
Yanfei Zhao ◽  
Guipeng Ji ◽  
...  
Keyword(s):  
Formic Acid ◽  
Organic Polymer ◽  
Hydrogenation Of Co2 ◽  
Troger's Base ◽  
Hydrogenation Of Co

Efficient CO2/H2 adsorption and subsequent hydrogenation of CO2 to HCOOH were realized adopting a Tröger's base-functionalized microporous organic polymer.

Catalytic Hydrogenation of CO2 by Fe Complexes Containing Pendant Amines: Role of Water and Base

2016 ◽  
Vol 120 (47) ◽  
pp. 26652-26662 ◽  
Author(s):  
Kuber Singh Rawat ◽  
Arup Mahata ◽  
Biswarup Pathak
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogenation Of Co2 ◽  
Fe Complexes

scholarly journals Tuning the transition barrier of H2 dissociation in the hydrogenation of CO2 to formic acid on Ti-doped Sn2O4 clusters

2021 ◽  
Vol 23 (1) ◽  
pp. 204-210
Author(s):  
Plaban J. Sarma ◽  
Dikshita Dowerah ◽  
Nand K. Gour ◽  
Andrew J. Logsdail ◽  
C. Richard A. Catlow ◽  
...  
Keyword(s):  
Formic Acid ◽  
Schematic Representation ◽  
Hydrogenation Of Co2 ◽  
Transition Barrier ◽  
Pure Sn ◽  
Ti Doping ◽  
Hydrogenation Of Co

Schematic representation of Ti-doping on a pure Sn2O4 cluster for the hydrogenation of CO2 to HCOOH via a hydride pathway.

New Ru(ii) N′NN′-type pincer complexes: synthesis, characterization and the catalytic hydrogenation of CO2 or bicarbonates to formate salts

2017 ◽  
Vol 41 (8) ◽  
pp. 3055-3060 ◽  
Author(s):  
Zengjin Dai ◽  
Qi Luo ◽  
Hengjiang Cong ◽  
Jing Zhang ◽  
Tianyou Peng
Keyword(s):  
Catalytic Hydrogenation ◽  
Catalytic Efficiency ◽  
Homogeneous System ◽  
Pincer Complexes ◽  
Hydrogenation Of Co2 ◽  
Hydrogenation Of Co

A new homogeneous system based on new Ru(ii)-N′NN′ pincer complexes has been successfully applied to the hydrogenation of CO2 to the formate, and complex 4 exhibits the best catalytic efficiency.

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