Unsaturated binuclear homoleptic nickel carbonyl anions Ni2(CO)n− (n = 4–6) featuring double three-center two-electron Ni–C–Ni bonds

The two nickel atoms in the Ni2(CO)n− (n = 4–6) complexes are joined by two bridging carbonyl ligands via the sharing three-center two-electron Ni–C–Ni bond in turn to achieve the (16,16), (16,18), and eventually the favored (18,18) configurations.