Synthesis of bimetallic iron-nickel carbonyl clusters: crystal structure of the iron-nickel carbonyl cluster [N(CH3)3CH2Ph][Fe3Ni(CO)8(.mu.-CO)4(.mu.3-H)]

1984 ◽  
Vol 23 (10) ◽  
pp. 1363-1368 ◽  
Author(s):  
Allesandro Ceriotti ◽  
Paolo Chini ◽  
Allesandro Fumagalli ◽  
Thomas F. Koetzle ◽  
Giuliano Longoni ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Nickel Carbonyl ◽  
Iron Nickel

scholarly journals Crystal structure of iron nickel phosphide,Fe1.65Ni1.35P,a Rhabdite extracted from Morasko meteorite

2003 ◽  
Vol 218 (JG) ◽  
pp. 425-426
Author(s):  
O. Moretzki ◽  
Th. Doering ◽  
V. Geist ◽  
W. Morgenroth ◽  
M. Wendschuhm
Keyword(s):  
Crystal Structure ◽  
Nickel Phosphide ◽  
Iron Nickel

Substitution chemistry of pentaosmium carbonyl clusters: crystal structure of H2Os5(CO)13P(OMe)3PEt3

1990 ◽  
Vol 385 (3) ◽  
pp. 387-398 ◽  
Author(s):  
Brian F.G. Johnson ◽  
Rajesh Khattar ◽  
Jack Lewis ◽  
Paul R. Raithby ◽  
Maria J. Rosales
Keyword(s):  
Crystal Structure ◽  
Carbonyl Clusters ◽  
Substitution Chemistry

Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

2011 ◽  
Vol 396-398 ◽  
pp. 2485-2488
Author(s):  
Bao Hua Zhu ◽  
Guo Hua Xu ◽  
Zhi Wei Xia
Keyword(s):  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Iron Carbonyl ◽  
Carbonyl Cluster ◽  
Carbonyl Clusters ◽  
Excellent Yield ◽  
Ruthenium Carbonyl ◽  
Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

scholarly journals Crystal structure of iron nickel phosphide, Fe1.8Ni1.2P, a Schreibersite extracted from Orange River meteorite

2003 ◽  
Vol 218 (JG) ◽  
pp. 427-428
Author(s):  
O. Moretzki ◽  
Th. Doering ◽  
Y. Geist ◽  
W. Morgenrothn ◽  
M. Wendschuhm
Keyword(s):  
Crystal Structure ◽  
Nickel Phosphide ◽  
Iron Nickel
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