Mesoporous NiCo2Se4 tube as an efficient electrode material with enhanced performance for asymmetric supercapacitor applications

CrystEngComm ◽  
2021 ◽  
Author(s):  
Zhixiang Guo ◽  
Yuting Diao ◽  
Xinru Han ◽  
Zihao Liu ◽  
Yonghong Ni ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Power Density ◽  
Electrode Material ◽  
Asymmetric Supercapacitor ◽  
High Electrical Conductivity ◽  
Supercapacitor Applications

• One-component NiCo2Se4 is synthesized. • The unique mesoporous tubular micro-nanostructure greatly improves the electrochemical performance. • Selenium with high electrical conductivity is beneficial for improving the energy density and power density.

Tailoring the morphology followed by the electrochemical performance of NiMn-LDH nanosheet arrays through controlled Co-doping for high-energy and power asymmetric supercapacitors

2017 ◽  
Vol 46 (38) ◽  
pp. 12876-12883 ◽  
Author(s):  
Saurabh Singh ◽  
Nanasaheb M. Shinde ◽  
Qi Xun Xia ◽  
Chandu V. V. M. Gopi ◽  
Je Moon Yun ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Power Density ◽  
High Energy ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Co Doping ◽  
Nanosheet Arrays

A NiCoMn-LDH (10%)//rGO asymmetric supercapacitor device with 574 Wh kg−1 energy density at 749.9 W kg−1 power density and 89.4% retention even after 2500 cycles has been explored.

NiS nanosheets synthesized by one-step microwave for high-performance supercapacitor

2021 ◽  
Author(s):  
Jun Song ◽  
Lijun Du ◽  
Jingyi Wang ◽  
Huaiping Zhang ◽  
Yaodong Zhang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Power Density ◽  
Microwave Radiation ◽  
High Performance ◽  
Negative Electrode ◽  
Asymmetric Supercapacitor ◽  
Capacity Retention ◽  
One Step

The NiS nanosheets were fabricated using one-step microwave approach with the microwave radiation of 800 W for 1.5 min. Impressively, the NiS nanosheets revealed praiseworthy electrochemical performance, with a capacitance value of 1082.8 F ⋅ g[Formula: see text] at 1 A ⋅ g[Formula: see text] and 77.8% retention over 5000 cycles at 5 A ⋅ g[Formula: see text]. Moreover, an asymmetric supercapacitor was assembled with NiS as the positive electrode and activated carbon (AC) as the negative electrode. It shows 80.42% capacity retention after 8000 cycles and an energy density of 19.45 W ⋅ h ⋅ kg[Formula: see text] at a power density of 801.05 W ⋅ kg[Formula: see text].

A high-performance graphene based asymmetric supercapacitor

2019 ◽  
Vol 34 (01n03) ◽  
pp. 2040007
Author(s):  
Syeda Wishal Bokhari ◽  
Ahmad Hassan Siddique ◽  
Harshpreet Singh ◽  
Muhammad Dilawer Hayat ◽  
Shenmin Zhu ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Power Density ◽  
High Performance ◽  
Hybrid Nanocomposites ◽  
Asymmetric Supercapacitor ◽  
Galvanostatic Charge ◽  
Asymmetric Device ◽  
Charge Discharge

We present the design of a high-performance 2 V asymmetric supercapacitor made of graphene-based hybrid nanocomposites in 1 M KOH electrolyte. rGO-CNT-FeOOH (GC-F) was used as the cathode and rGO-CNC-MnO2 (GC-M) as the anode. Both composites well balanced each other in the asymmetric device and gave a high electrochemical performance. The energy density of this ASC is 66.6 W h kg[Formula: see text] at 3.8 kW kg[Formula: see text] power density with an excellent capacitance retention of 88% after 3000 galvanostatic charge-discharge cycles.

A hybrid aerogel of Co–Al layered double hydroxide/graphene with three-dimensional porous structure as a novel electrode material for supercapacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (33) ◽  
pp. 26017-26026 ◽  
Author(s):  
Aili Zhang ◽  
Cong Wang ◽  
Qunjie Xu ◽  
Haimei Liu ◽  
Yonggang Wang ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Electrochemical Performance ◽  
Porous Structure ◽  
Layered Double Hydroxide ◽  
Electrode Material ◽  
Three Dimensional ◽  
High Electrical Conductivity ◽  
Double Hydroxide ◽  
Hybrid Aerogel

3D porous Co–Al layered double hydroxide/graphene hybrid aerogel was prepared by a facile in situ hydrothermal method and showed high electrical conductivity, mechanical flexibility, and good electrochemical performance for supercapacitors.

A reduced graphene oxide modified metallic cobalt composite with superior electrochemical performance for supercapacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (78) ◽  
pp. 63553-63560 ◽  
Author(s):  
Guijing Liu ◽  
Lei Wang ◽  
Bo Wang ◽  
Tiantian Gao ◽  
Dianlong Wang
Keyword(s):  
Graphene Oxide ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Reduced Graphene Oxide ◽  
Power Density ◽  
Maximum Energy ◽  
Asymmetric Supercapacitor ◽  
Metallic Cobalt ◽  
Reduced Graphene

The prepared rGO/Co//AC asymmetric supercapacitor displayed good electrochemical performance, and it achieved a maximum energy density of 40.7 W h kg−1 at a power density of 1585.0 W kg−1.

Rational design of self-supported Ni3S2 nanoparticles as a battery type electrode material for high-voltage (1.8 V) symmetric supercapacitor applications

CrystEngComm ◽  
2021 ◽  
Author(s):  
Muhammad Sajjad ◽  
Yaqoob Khan
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
High Voltage ◽  
Electrode Material ◽  
High Performance ◽  
Rational Design ◽  
Rate Capability ◽  
Excellent Electrochemical Performance ◽  
Symmetric Supercapacitor ◽  
Supercapacitor Applications

We developed a high performance SSC device with excellent electrochemical performance in terms of specific capacitance, rate capability, energy density and power density which surpasses most of the reports.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

Flexible high-energy asymmetric supercapacitors based on MnO@C composite nanosheet electrodes

2017 ◽  
Vol 5 (2) ◽  
pp. 804-813 ◽  
Author(s):  
Neng Yu ◽  
Kai Guo ◽  
Wei Zhang ◽  
Xianfu Wang ◽  
Ming-Qiang Zhu
Keyword(s):  
Energy Density ◽  
Power Density ◽  
High Energy ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Positive Electrodes

A flexible asymmetric supercapacitor assembled with novel MnO@C composite nanosheets and Co3O4 nanosheets as negative and positive electrodes achieves an exceptional energy density of 59.6 W h kg−1 at a power density of 1529.8 W kg−1.

scholarly journals Electrochemical Performance of Aluminum Doped Ni1−xAlxCo2O4 Hierarchical Nanostructure: Experimental and Theoretical Study

Processes ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 1750
Author(s):  
Deepa Guragain ◽  
Romakanta Bhattarai ◽  
Jonghyun Choi ◽  
Wang Lin ◽  
Ram Krishna Gupta ◽  
...  
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Band Gap ◽  
Specific Capacitance ◽  
Surface Area ◽  
Power Density ◽  
High Power ◽  
Energy Band ◽  
High Specific Capacitance ◽  
High Power Density

For electrochemical supercapacitors, nickel cobaltite (NiCo2O4) has emerged as a new energy storage material. The electrocapacitive performance of metal oxides is significantly influenced by their morphology and electrical characteristics. The synthesis route can modulate the morphological structure, while their energy band gaps and defects can vary the electrical properties. In addition to modifying the energy band gap, doping can improve crystal stability and refine grain size, providing much-needed surface area for high specific capacitance. This study evaluates the electrochemical performance of aluminum-doped Ni1−xAlxCo2O4 (0 ≤ x ≤ 0.8) compounds. The Ni1−xAlxCo2O4 samples were synthesized through a hydrothermal method by varying the Al to Ni molar ratio. The physical, morphological, and electrochemical properties of Ni1−xAlxCo2O4 are observed to vary with Al3+ content. A morphological change from urchin-like spheres to nanoplate-like structures with a concomitant increase in the surface area, reaching up to 189 m2/g for x = 0.8, was observed with increasing Al3+ content in Ni1−xAlxCo2O4. The electrochemical performance of Ni1−xAlxCo2O4 as an electrode was assessed in a 3M KOH solution. The high specific capacitance of 512 F/g at a 2 mV/s scan rate, 268 F/g at a current density of 0.5 A/g, and energy density of 12.4 Wh/kg was observed for the x = 0.0 sample, which was reduced upon further Al3+ substitution. The as-synthesized Ni1−xAlxCo2O4 electrode exhibited a maximum energy density of 12.4 W h kg−1 with an outstanding high-power density of approximately 6316.6 W h kg−1 for x = 0.0 and an energy density of 8.7 W h kg−1 with an outstanding high-power density of approximately 6670.9 W h kg−1 for x = 0.6. The capacitance retention of 97% and 108.52% and the Coulombic efficiency of 100% and 99.24% were observed for x = 0.0 and x = 0.8, respectively. First-principles density functional theory (DFT) calculations show that the band-gap energy of Ni1−xAlxCo2O4 remained largely invariant with the Al3+ substitution for low Al3+ content. Although the capacitance performance is reduced upon Al3+ doping, overall, the Al3+ doped Ni1−xAlxCo2O4 displayed good energy, powder density, and retention performance. Thus, Al3+ could be a cost-effective alternative in replacing Ni with the performance trade off.

A high performance solid state asymmetric supercapacitor device based upon NiCo2O4nanosheets//MnO2microspheres

RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 70292-70302 ◽  
Author(s):  
Syed Khalid ◽  
Chuanbao Cao ◽  
Lin Wang ◽  
Youqi Zhu ◽  
Yu Wu
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Power Density ◽  
High Performance ◽  
Asymmetric Supercapacitor ◽  
State Device ◽  
Solid State Device

The volumetric energy density and power density of a novel solid state device (NiCo2O4//MnO2) are much higher than most reported devices.

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