Reversible photo/thermal solid-state transformation of a coordination polymer

CrystEngComm ◽  
2020 ◽  
Vol 22 (38) ◽  
pp. 6339-6346
Author(s):  
Sheng-En Qiu ◽  
Shi-Yao Yang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Single Crystal ◽  
State Transformation ◽  
Solid State Transformation ◽  
Thermal Pyrolysis

A 2D coordination polymer, 1, was synthesized, characterized, and investigated with single-crystal-to-single-crystal photoreaction and thermal pyrolysis.

Monocrystalline mesoporous metal oxide with perovskite structure: a facile solid-state transformation of a coordination polymer

2014 ◽  
Vol 50 (89) ◽  
pp. 13849-13852 ◽  
Author(s):  
Li Xu ◽  
Fan-Xing Bu ◽  
Ming Hu ◽  
Chuan-Yin Jin ◽  
Dong-Mei Jiang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Metal Oxide ◽  
Single Crystal ◽  
Perovskite Structure ◽  
State Transformation ◽  
Solid State Transformation ◽  
Crystal Transformation ◽  
Mesoporous Metal ◽  
Mesoporous Metal Oxide

Monocrystalline mesoporous BiFeO3 crystals were obtained via a multi-step single-crystal to single-crystal transformation of a coordination polymer, Bi[Fe(CN)6]·4H2O.

A cyano and end-to-end azido bridged 3D copper(ii)–copper(i) mixed-valence coordination polymer and its transformation to copper nitride nanoparticles

RSC Advances ◽  
2014 ◽  
Vol 4 (64) ◽  
pp. 34110-34116 ◽  
Author(s):  
Manoj Trivedi ◽  
Gurmeet Singh ◽  
Abhinav Kumar ◽  
Nigam P. Rath
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Mixed Valence ◽  
Three Dimensional ◽  
State Transformation ◽  
Solid State Transformation ◽  
Copper Nitride ◽  
End To End

Syntheses and characterization of a CN and end-to-end N3 bridged three-dimensional Cu(II)–Cu(I) mixed valence polymer (1), with Cu-N3 system without CN (2) and a CN-bridged Cu analogue without N3 (3) are reported and solid-state transformation of the 1 to copper nitride nanoparticles performed.

A Step Towards a [2.2]Paracyclophane: A Single Crystal to Single Crystal Reaction Involving a Hydrogen-Bonded Molecular Assembly with Multiple Reaction Centres

2006 ◽  
Vol 59 (9) ◽  
pp. 613 ◽  
Author(s):  
Tomislav Friščić ◽  
Leonard R. MacGillivray
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Absorption Edge ◽  
Molecular Assembly ◽  
Solid State Synthesis ◽  
State Transformation ◽  
Molecular Assemblies ◽  
Solid State Transformation ◽  
Reaction Centres ◽  
Hydrogen Bonded

A single crystal to single crystal [2+2] photodimerization has been achieved within a molecular cocrystal composed of finite, hydrogen-bonded molecular assemblies using the absorption-edge irradiation technique. The cocrystal is composed of a resorcinol template and a diolefin reactant that reacts to form a non-symmetrical cyclobutane product. The product is an intermediate in a two-step solid-state synthesis of a [2.2]paracyclophane. The ability to conduct the reaction in a single crystal to single crystal fashion attests to the robustness of the hydrogen-bonded assemblies during the course of the solid-state transformation.

Solid-state Transformation of Achiral Crystals to a Chiral Crystal by Guest Release from Host–Guest Inclusion Crystals of Achiral Host Compound

2009 ◽  
Vol 38 (11) ◽  
pp. 1080-1081 ◽  
Author(s):  
Hironori Saito ◽  
Mitsuaki Suzuki ◽  
Hiroshi Miyamae ◽  
Naoto Hayashi ◽  
Keiji Kobayashi
Keyword(s):  
Solid State ◽  
State Transformation ◽  
Solid State Transformation ◽  
Host Compound

scholarly journals Maskelynite formation via solid-state transformation: Evidence of infrared and X-ray anisotropy

2015 ◽  
Vol 120 (3) ◽  
pp. 570-587 ◽  
Author(s):  
Steven J. Jaret ◽  
William R. Woerner ◽  
Brian L. Phillips ◽  
Lars Ehm ◽  
Hanna Nekvasil ◽  
...  
Keyword(s):  
Solid State ◽  
State Transformation ◽  
Solid State Transformation ◽  
X Ray

Solid-State Reactions in Multilayer Ni/Ti Thin Film Composites

1990 ◽  
Vol 205 ◽  
Author(s):  
Gillian E. Winters ◽  
K.M. Unruh ◽  
C.P. Swann ◽  
M.E. Patt ◽  
B.E. White ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reactions ◽  
Metastable Solid Solution ◽  
State Transformation ◽  
Solid State Transformation ◽  
Scanning Calorimetry ◽  
The Individual ◽  
Thin Film Composites ◽  
Film Composites ◽  
Rf Sputter Deposition

AbstractMultilayer films, consisting of alternating layers of crystalline Ni and Ti, have been prepared by RF sputter deposition over a range of modulation wavelengths corresponding to an overall composition of Ni50Ti50. These films have been characterized by xray diffraction and Rutherford backscattering measurements. The solid-state transformation by interdiffusional mixing of the individual layers has been directly studied by differential scanning calorimetry and correlated with structural measurements. These measurements indicate that the solid-state reaction of Ni and Ti multilayers proceeds through the formation of a metastable solid solution of Ti in Ni followed by the formation of intermetallic equilibrium compounds. No direct calorimetric or structural evidence for the formation of an amorphous Ni-Ti phase has been found in these samples.

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