scholarly journals Tailoring Li6PS5Br ionic conductivity and understanding of its role in cathode mixtures for high performance all-solid-state Li–S batteries

2019 ◽  
Vol 7 (17) ◽  
pp. 10412-10421 ◽  
Author(s):  
Chuang Yu ◽  
Jart Hageman ◽  
Swapna Ganapathy ◽  
Lambert van Eijck ◽  
Long Zhang ◽  
...  

By tailoring the Br ordering over the 4a and 4c sites, Li6PS5Br with ultrafast ionic conductivity was achieved, which can be worked as both active material and solid electrolyte in all-solid-state Li–S batteries.

Nanoscale ◽  
2021 ◽  
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

As flexible all-solid-state batteries are highly safe and lightweight, they can be considered as candidates for wearable energy sources. However, their performance needs to be first improved, which can be...


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 989
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

All-solid-state batteries (ASSBs) are attractive for energy storage, mainly because introducing solid-state electrolytes significantly improves the battery performance in terms of safety, energy density, process compatibility, etc., compared with liquid electrolytes. However, the ionic conductivity of the solid-state electrolyte and the interface between the electrolyte and the electrode are two key factors that limit the performance of ASSBs. In this work, we investigated the structure of a Li0.33La0.55TiO3 (LLTO) thin-film solid electrolyte and the influence of different interfaces between LLTO electrolytes and electrodes on battery performance. The maximum ionic conductivity of the LLTO was 7.78 × 10−5 S/cm. Introducing a buffer layer could drastically improve the battery charging and discharging performance and cycle stability. Amorphous SiO2 allowed good physical contact with the electrode and the electrolyte, reduced the interface resistance, and improved the rate characteristics of the battery. The battery with the optimized interface could achieve 30C current output, and its capacity was 27.7% of the initial state after 1000 cycles. We achieved excellent performance and high stability by applying the dense amorphous SiO2 buffer layer, which indicates a promising strategy for the development of ASSBs.


Author(s):  
Diego Holanda Pereira de Souza ◽  
Kasper T. Møller ◽  
Stephen A. Moggach ◽  
Terry D Humphries ◽  
Anita D’Angelo ◽  
...  

Metal boron-hydrogen compounds are considered as promising solid electrolyte candidates for the development of all-solid-state batteries (ASSB), owing to the high ionic conductivity exhibited by closo- and nido-boranes. In this...


2019 ◽  
Vol 12 (9) ◽  
pp. 2665-2671 ◽  
Author(s):  
Xiaona Li ◽  
Jianwen Liang ◽  
Jing Luo ◽  
Mohammad Norouzi Banis ◽  
Changhong Wang ◽  
...  

Ambient-air-stable Li3InCl6 halide solid electrolyte, with high ionic conductivity of 1.49 × 10−3 S cm−1 at 25 °C, delivers essential advantages over commercial sulfide-based solid electrolyte.


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