Silicon-Doped Argyrodite Solid Electrolyte Li6PS5I with Improved Ionic Conductivity and Interfacial Compatibility for High-Performance All-Solid-State Lithium Batteries

2020 ◽  
Vol 12 (37) ◽  
pp. 41538-41545 ◽  
Author(s):  
Jun Zhang ◽  
Lujie Li ◽  
Chao Zheng ◽  
Yang Xia ◽  
Yongping Gan ◽  
...  
Nanoscale ◽  
2021 ◽  
Author(s):  
Erqing Zhao ◽  
Yudi Guo ◽  
Awei Zhang ◽  
Hongliang Wang ◽  
Guang-ri Xu

Polyethylene oxide (PEO) solid electrolyte is a promising candidate for all solid state lithium-ion batteries (ASSLIBs), but its low ionic conductivity and poor interfacial compatibility against lithium limit the rate...


2019 ◽  
Vol 7 (17) ◽  
pp. 10412-10421 ◽  
Author(s):  
Chuang Yu ◽  
Jart Hageman ◽  
Swapna Ganapathy ◽  
Lambert van Eijck ◽  
Long Zhang ◽  
...  

By tailoring the Br ordering over the 4a and 4c sites, Li6PS5Br with ultrafast ionic conductivity was achieved, which can be worked as both active material and solid electrolyte in all-solid-state Li–S batteries.


Nanoscale ◽  
2021 ◽  
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

As flexible all-solid-state batteries are highly safe and lightweight, they can be considered as candidates for wearable energy sources. However, their performance needs to be first improved, which can be...


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 989
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

All-solid-state batteries (ASSBs) are attractive for energy storage, mainly because introducing solid-state electrolytes significantly improves the battery performance in terms of safety, energy density, process compatibility, etc., compared with liquid electrolytes. However, the ionic conductivity of the solid-state electrolyte and the interface between the electrolyte and the electrode are two key factors that limit the performance of ASSBs. In this work, we investigated the structure of a Li0.33La0.55TiO3 (LLTO) thin-film solid electrolyte and the influence of different interfaces between LLTO electrolytes and electrodes on battery performance. The maximum ionic conductivity of the LLTO was 7.78 × 10−5 S/cm. Introducing a buffer layer could drastically improve the battery charging and discharging performance and cycle stability. Amorphous SiO2 allowed good physical contact with the electrode and the electrolyte, reduced the interface resistance, and improved the rate characteristics of the battery. The battery with the optimized interface could achieve 30C current output, and its capacity was 27.7% of the initial state after 1000 cycles. We achieved excellent performance and high stability by applying the dense amorphous SiO2 buffer layer, which indicates a promising strategy for the development of ASSBs.


Author(s):  
Diego Holanda Pereira de Souza ◽  
Kasper T. Møller ◽  
Stephen A. Moggach ◽  
Terry D Humphries ◽  
Anita D’Angelo ◽  
...  

Metal boron-hydrogen compounds are considered as promising solid electrolyte candidates for the development of all-solid-state batteries (ASSB), owing to the high ionic conductivity exhibited by closo- and nido-boranes. In this...


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