ZnO nanoarray-modified nickel foam as a lithiophilic skeleton to regulate lithium deposition for lithium-metal batteries

2019 ◽  
Vol 7 (13) ◽  
pp. 7752-7759 ◽  
Author(s):  
Changzhi Sun ◽  
Yanpei Li ◽  
Jun Jin ◽  
Jianhua Yang ◽  
Zhaoyin Wen
Keyword(s):  
Nickel Foam ◽  
Zno Nanorods ◽  
Lithium Metal ◽  
Ni Foam ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

Tightly arranged ZnO nanorods are artfully designed to enhance the lithiophilicity of pristine Ni foam and regulate lithium deposition.

Dendrite‐Free Reverse Lithium Deposition Induced by Ion Rectification Layer toward Superior Lithium Metal Batteries

2021 ◽  
pp. 2104081
Author(s):  
Liang Lin ◽  
Fang Liu ◽  
Xiaolin Yan ◽  
Qiulin Chen ◽  
Yanping Zhuang ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

Li–Zn Overlayer to Facilitate Uniform Lithium Deposition for Lithium Metal Batteries

2021 ◽  
Vol 13 (8) ◽  
pp. 9985-9993
Author(s):  
Qiulin Chen ◽  
Hao Li ◽  
Melissa L. Meyerson ◽  
Rodrigo Rodriguez ◽  
Kenta Kawashima ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

scholarly journals A 3D conductive scaffold with lithiophilic modification for stable lithium metal batteries

2018 ◽  
Vol 6 (37) ◽  
pp. 17967-17976 ◽  
Author(s):  
Rensheng Song ◽  
Bo Wang ◽  
Ying Xie ◽  
Tingting Ruan ◽  
Fei Wang ◽  
...  
Keyword(s):  
Hydrothermal Method ◽  
Functional Groups ◽  
Nickel Foam ◽  
Porous Electrode ◽  
Lithium Metal ◽  
Electrode Structure ◽  
Simple Hydrothermal Method ◽  
Lithium Metal Batteries ◽  
The Poor ◽  
Doped Graphene

A 3D lithiophilic N-doped graphene/nickel foam (NGNF) scaffold to host Li has been successfully prepared by a simple hydrothermal method. This scaffold can improve the poor lithiophilicity of nickel foam (NF) due to the presence of N-doped graphene (NG) with lithiophilic functional groups while maintaining its 3D porous electrode structure, leading to uniform Li plating/stripping.

scholarly journals Lithiophilic montmorillonite serves as lithium ion reservoir to facilitate uniform lithium deposition

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Wei Chen ◽  
Yin Hu ◽  
Weiqiang Lv ◽  
Tianyu Lei ◽  
Xianfu Wang ◽  
...  
Keyword(s):  
Specific Capacity ◽  
Lithium Ion ◽  
Ion Concentration ◽  
Anode Surface ◽  
Lithium Metal ◽  
Ion Distribution ◽  
Interfacial Engineering ◽  
Lithium Metal Batteries ◽  
Lithium Deposition ◽  
Current Densities

Abstract The growing demand for lithium batteries with higher energy densities requires new electrode chemistries. Lithium metal is a promising candidate as the anode material due to its high theoretical specific capacity, negative electrochemical potential and favorable density. However, during cycling, low and uneven lithium ion concentration on the surface of anode usually results in uncontrolled dendrite growth, especially at high current densities. Here we tackle this issue by using lithiophilic montmorillonite as an additive in the ether-based electrolyte to regulate the lithium ion concentration on the anode surface and thus facilitate the uniform lithium deposition. The lithiophilic montmorillonite demonstrates a pumping feature that improves the self-concentrating kinetics of the lithium ion and thus accelerates the lithium ion transfer at the deposition/electrolyte interface. The signal intensity of TFSI− shows negligible changes via in situ Raman tracking of the ion flux at the electrochemical interface, indicating homogeneous ion distribution, which can lead to a stable and uniform lithium deposition on the anode surface. Our study indicates that the interfacial engineering induced by the lithiophilic montmorillonite could be a promising strategy to optimize the lithium deposition for next-generation lithium metal batteries.

Regulating Lithium Deposition via Electropolymerization of Acrylonitrile in Rechargeable Lithium Metal Batteries

Nano Energy ◽  
2021 ◽  
pp. 106298
Author(s):  
Jian Zhang ◽  
Musen Zhou ◽  
Jiayan Shi ◽  
Yifan Zhao ◽  
Xiaoyu Wen ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition
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