scholarly journals Lithiophilic Cu‐Li 2 O matrix on a Cu Collector to Stabilize Lithium Deposition for Lithium Metal Batteries

2021 ◽  
Author(s):  
Zhe Gong ◽  
Cheng Lian ◽  
Pengfei Wang ◽  
Kai Huang ◽  
Kai Zhu ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

Dendrite‐Free Reverse Lithium Deposition Induced by Ion Rectification Layer toward Superior Lithium Metal Batteries

2021 ◽  
pp. 2104081
Author(s):  
Liang Lin ◽  
Fang Liu ◽  
Xiaolin Yan ◽  
Qiulin Chen ◽  
Yanping Zhuang ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

Li–Zn Overlayer to Facilitate Uniform Lithium Deposition for Lithium Metal Batteries

2021 ◽  
Vol 13 (8) ◽  
pp. 9985-9993
Author(s):  
Qiulin Chen ◽  
Hao Li ◽  
Melissa L. Meyerson ◽  
Rodrigo Rodriguez ◽  
Kenta Kawashima ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

scholarly journals Lithiophilic montmorillonite serves as lithium ion reservoir to facilitate uniform lithium deposition

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Wei Chen ◽  
Yin Hu ◽  
Weiqiang Lv ◽  
Tianyu Lei ◽  
Xianfu Wang ◽  
...  
Keyword(s):  
Specific Capacity ◽  
Lithium Ion ◽  
Ion Concentration ◽  
Anode Surface ◽  
Lithium Metal ◽  
Ion Distribution ◽  
Interfacial Engineering ◽  
Lithium Metal Batteries ◽  
Lithium Deposition ◽  
Current Densities

Abstract The growing demand for lithium batteries with higher energy densities requires new electrode chemistries. Lithium metal is a promising candidate as the anode material due to its high theoretical specific capacity, negative electrochemical potential and favorable density. However, during cycling, low and uneven lithium ion concentration on the surface of anode usually results in uncontrolled dendrite growth, especially at high current densities. Here we tackle this issue by using lithiophilic montmorillonite as an additive in the ether-based electrolyte to regulate the lithium ion concentration on the anode surface and thus facilitate the uniform lithium deposition. The lithiophilic montmorillonite demonstrates a pumping feature that improves the self-concentrating kinetics of the lithium ion and thus accelerates the lithium ion transfer at the deposition/electrolyte interface. The signal intensity of TFSI− shows negligible changes via in situ Raman tracking of the ion flux at the electrochemical interface, indicating homogeneous ion distribution, which can lead to a stable and uniform lithium deposition on the anode surface. Our study indicates that the interfacial engineering induced by the lithiophilic montmorillonite could be a promising strategy to optimize the lithium deposition for next-generation lithium metal batteries.

Regulating Lithium Deposition via Electropolymerization of Acrylonitrile in Rechargeable Lithium Metal Batteries

Nano Energy ◽  
2021 ◽  
pp. 106298
Author(s):  
Jian Zhang ◽  
Musen Zhou ◽  
Jiayan Shi ◽  
Yifan Zhao ◽  
Xiaoyu Wen ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

Uniform lithium deposition and dissolution via metallic phosphides medium for stable cycling lithium metal batteries

2021 ◽  
Vol 407 ◽  
pp. 126861
Author(s):  
Zhe Wang ◽  
Jin Wang ◽  
Qianjiang Mao ◽  
Shitu Yang ◽  
Dan Cheng ◽  
...  
Keyword(s):  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Lithium Deposition

A Diffusion‐‐Reaction Competition Mechanism to Tailor Lithium Deposition for Lithium‐Metal Batteries

2020 ◽  
Vol 59 (20) ◽  
pp. 7743-7747 ◽  
Author(s):  
Xiao‐Ru Chen ◽  
Yu‐Xing Yao ◽  
Chong Yan ◽  
Rui Zhang ◽  
Xin‐Bing Cheng ◽  
...  
Keyword(s):  
Diffusion Reaction ◽  
Lithium Metal ◽  
Competition Mechanism ◽  
Lithium Metal Batteries ◽  
Lithium Deposition
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