Influence of treating parameters on thermomechanical properties of recycled epoxy-acid vitrimers

Soft Matter ◽  
2020 ◽  
Vol 16 (6) ◽  
pp. 1668-1677 ◽  
Author(s):  
Honggeng Li ◽  
Biao Zhang ◽  
Kai Yu ◽  
Chao Yuan ◽  
Cong Zhou ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Thermomechanical Properties ◽  
Epoxy Acid ◽  
Temperature Time

The effects of particle size, temperature, time, and pressure on the mechanical properties of regenerated epoxy-acid vitrimers were investigated, which helped to refine the vitrimer reprocessing condition parameter toolbox.

scholarly journals Micro-Structure and Thermomechanical Properties of Crosslinked Epoxy Composite Modified by Nano-SiO2: A Molecular Dynamics Simulation

Polymers ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 801 ◽  
Author(s):  
Qing Xie ◽  
Kexin Fu ◽  
Shaodong Liang ◽  
Bowen Liu ◽  
Lu Lu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Molecular Dynamics ◽  
Particle Size ◽  
Rational Design ◽  
Thermomechanical Properties ◽  
Composite Model ◽  
Dynamics Simulation ◽  
Thermal And Mechanical Properties ◽  
Micro Structure ◽  
Nano Sio2

Establishing the relationship among the composition, structure and property of the associated materials at the molecular level is of great significance to the rational design of high-performance electrical insulating Epoxy Resin (EP) and its composites. In this paper, the molecular models of pure Diglycidyl Ether of Bisphenol A resin/Methyltetrahydrophthalic Anhydride (DGEBA/MTHPA) and their nanocomposites containing nano-SiO2 with different particle sizes were constructed. The effects of nano-SiO2 dopants and the crosslinked structure on the micro-structure and thermomechanical properties were investigated using molecular dynamics simulations. The results show that the increase of crosslinking density enhances the thermal and mechanical properties of pure EP and EP nanocomposites. In addition, doping nano-SiO2 particles into EP can effectively improve the properties, as well, and the effectiveness is closely related to the particle size of nano-SiO2. Moreover, the results indicate that the glass transition temperature (Tg) value increases with the decreasing particle size. Compared with pure EP, the Tg value of the 6.5 Å composite model increases by 6.68%. On the contrary, the variation of the Coefficient of Thermal Expansion (CTE) in the glassy state demonstrates the opposite trend compared with Tg. The CTE of the 10 Å composite model is the lowest, which is 7.70% less than that of pure EP. The mechanical properties first increase and then decrease with the decreasing particle size. Both the Young’s modulus and shear modulus reach the maximum value at 7.6 Å, with noticeable increases by 12.60% and 8.72%, respectively compared to the pure EP. In addition, the thermal and mechanical properties are closely related to the Fraction of Free Volume (FFV) and Mean Squared Displacement (MSD). The crosslinking process and the nano-SiO2 doping reduce the FFV and MSD value in the model, resulting in better thermal and mechanical properties.

scholarly journals Experimental Analysis of the Mechanical Properties and Resistivity of Tectonic Coal Samples with Different Particle Sizes

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2303
Author(s):  
Congyu Zhong ◽  
Liwen Cao ◽  
Jishi Geng ◽  
Zhihao Jiang ◽  
Shuai Zhang
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Compressive Strength ◽  
Elastic Modulus ◽  
Uniaxial Compressive Strength ◽  
Coalbed Methane ◽  
Coal Sample ◽  
Fine Particles ◽  
Particle Sizes ◽  
Tectonic Coal

Because of its weak cementation and abundant pores and cracks, it is difficult to obtain suitable samples of tectonic coal to test its mechanical properties. Therefore, the research and development of coalbed methane drilling and mining technology are restricted. In this study, tectonic coal samples are remodeled with different particle sizes to test the mechanical parameters and loading resistivity. The research results show that the particle size and gradation of tectonic coal significantly impact its uniaxial compressive strength and elastic modulus and affect changes in resistivity. As the converted particle size increases, the uniaxial compressive strength and elastic modulus decrease first and then tend to remain unchanged. The strength of the single-particle gradation coal sample decreases from 0.867 to 0.433 MPa and the elastic modulus decreases from 59.28 to 41.63 MPa with increasing particle size. The change in resistivity of the coal sample increases with increasing particle size, and the degree of resistivity variation decreases during the coal sample failure stage. In composite-particle gradation, the proportion of fine particles in the tectonic coal sample increases from 33% to 80%. Its strength and elastic modulus increase from 0.996 to 1.31 MPa and 83.96 to 125.4 MPa, respectively, and the resistivity change degree decreases. The proportion of medium particles or coarse particles increases, and the sample strength, elastic modulus, and resistivity changes all decrease.

scholarly journals Influences of B4C content and particle size on the mechanical properties of hot pressed TiB2–B4C composites

2021 ◽  
pp. 1-9
Author(s):  
Jun Zhao ◽  
Qinggui Li ◽  
Weixiao Cao ◽  
Zetan Liu ◽  
Xiangong Deng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Particle Size

Effects of maximum particle size of coarse aggregates and steel fiber contents on the mechanical properties and impact resistance of recycled aggregate concrete

2021 ◽  
pp. 136943322110179
Author(s):  
DongTao Xia ◽  
ShaoJun Xie ◽  
Min Fu ◽  
Feng Zhu
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Steel Fiber ◽  
Impact Resistance ◽  
Recycled Aggregate Concrete ◽  
Recycled Aggregate ◽  
Aggregate Concrete ◽  
Coarse Aggregates ◽  
Maximum Particle Size ◽  
Maximum Particle

Fiber reinforced recycled aggregate concrete has become a new type of green concrete material. The maximum particle size of coarse aggregates and steel fiber contents affect the mechanical properties and impact resistance of recycled aggregate concrete. However, such studies are rare in literature. The present paper shortens the gap through experimental study. A total of 144 specimens of 12 kinds of concrete mixtures were tested, which adopted different steel fiber volume admixtures (0%, 0.8%, 1.0%, 1.2%) and recycled coarse aggregates in different maximum particle sizes (9.5, 19, 31.5 mm) replacing 30% natural coarse aggregate. The compressive strength, splitting tensile strength, and impact resistance of the 12 concrete mixtures were tested. The results showed that the compressive strength, splitting tensile strength, and impact resistance of recycled aggregate concrete increased first and then decreased with the increase of the maximum particle size. The recycled aggregate concrete with the maximum particle size of 19 mm had the highest mechanical properties and impact resistance. Besides, with the increase of steel fiber content, the compressive strength, splitting tensile strength, and impact resistance of recycled aggregate concrete showed an increasing trend. Considering a large amount of experimental data and the coupling effect of steel fiber contents and the maximum particle size of coarse aggregates, the Weibull distribution function was introduced to analyze the impact test results and predict the number of resistance to impact under different failure probabilities. The results showed that the number of blows of the recycled aggregate concrete followed a two-parameter Weibull distribution, and the estimated value of the number of resistance to impact for failure increased with the increase of the failure probability.

scholarly journals Improving the mechanical properties of polypropylene composites with coconut shell particles

2021 ◽  
Vol 30 ◽  
pp. 263498332110074
Author(s):  
Henry C Obasi ◽  
Uchechi C Mark ◽  
Udochukwu Mark
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Flexural Modulus ◽  
Filler Particle ◽  
Tensile Modulus ◽  
Coconut Shell ◽  
Polypropylene Composites ◽  
Increase With Increase ◽  
Pp Composites ◽  
Shell Particles

Conventional inorganic fillers are widely used as fillers for polymer-based composites. Though, their processing difficulties and cost have demanded the quest for credible alternatives of organic origin like coconut shell fillers. Dried shells of coconut were burnt, ground, and sifted to sizes of 63, 150, 300, and 425 µm. The ground coconut shell particles (CSP) were used as a filler to prepare polypropylene (PP) composites at filler contents of 0% to 40% via injection melt blending process to produce PP composite sheets. The effect of the filler particle size on the mechanical properties was investigated. The decrease in the size of filler (CSP) was found to improve the yield strength, tensile strength, tensile modulus, flexural strength, flexural modulus, and hardness of PP by 8.5 MPa, 15.75 MPa, 1.72 GPa, 7.5 MPa, 100 MPa, and 10.5 HR for 63 µm at 40%, respectively. However, the elongation at break and modulus of resilience of the PP composites were seen to increase with increase in the filler size. Scanning electron microscope analysis showed that fillers with 63 µm particle size had the best distribution and interaction with the PP matrix resulting in enhanced properties.

scholarly journals Effect of Particle Size Distribution on Laser Powder Bed Fusion Manufacturability of Copper

2021 ◽  
Author(s):  
Massimiliano Bonesso ◽  
Pietro Rebesan ◽  
Claudio Gennari ◽  
Simone Mancin ◽  
Razvan Dima ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Physical And Mechanical Properties ◽  
Powder Bed Fusion ◽  
Laser Powder Bed Fusion ◽  
Powder Bed ◽  
Cooling Channels ◽  
Scan Speed

AbstractOne of the major benefits of the Laser Powder Bed Fusion (LPBF) technology is the possibility of fabrication of complex geometries and features in only one-step of production. In the case of heat exchangers in particular, this is very convenient for the fabrication of conformal cooling channels which can improve the performance of the heat transfer capability. Yet, obtaining dense copper parts printed via LPBF presents two major problems: the high reflectivity of 1 μm (the wavelength of commonly used laser sources) and the high thermal conductivity of copper that limits the maximum local temperature that can be attained. This leads to the formation of porous parts.In this contribution, the influence of the particle size distribution of the powder on the physical and mechanical properties of parts produced via LPBF is studied. Three copper powders lots with different particle size distributions are used in this study. The effect on densification from two laser scan parameters (scan speed and hatching distance) and the influence of contours scans on the lateral surface roughness is reported. Subsequently, samples manufactured with the optimal process parameters are tested for thermal and mechanical properties evaluation.

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