scholarly journals Electrospun silk fibroin/TiO2 mats. Preparation, characterization and efficiency for the photocatalytic solar treatment of pesticide polluted water

RSC Advances ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 1917-1924 ◽  
Author(s):  
Salvador Aznar-Cervantes ◽  
Marina Aliste ◽  
Isabel Garrido ◽  
María J. Yañez-Gascón ◽  
Nuria Vela ◽  
...  

The photocatalytic properties of silk fibroin (SF) incorporating TiO2 nanoparticles using an electrospinning technique were examined.

Author(s):  
Oguz Bayraktar ◽  
Ali Bora Balta ◽  
Guldemet Basal Bayraktar

The objective of this study was to investigate the adsorption/desorption behavior of oleuropein on different types of silk fibroin matrices including silk fibroin microfibers (MF), regenerated silk fibroin (RSF), and silk fibroin nanofibers (NF). Nanofibers with an average diameter of ranging between 24 and 326 nm were successfully prepared using the electrospinning technique. The effects of the silk fibroin concentration, the voltage applied and the distance between needle tip and collector plate on the morphology of the NF were investigated. The adsorption capacities of MF, RSF and NF were determined as 104.92, 163.07 and 228.34 mg oleuropein per gram of material, respectively. The percentage of initially adsorbed oleuropein that was desorbed was 86.08, 91.29 and 96.67% for MF, RSF and NF, respectively.NF and RSF discs loaded with oleuropein were subjected to disc diffusion assays to determine their antibacterial activity against test microorganisms Staphylococcus epidermidis (Gram +) and Escherichia coli (Gram – ). The results showed that both biomaterials possessed antibacterial properties after loading with oleuropein. Wound scratch assays using oleuropein released from NF revealed an enhancement of cell migration, indicating a wound healing property of the material.In conclusion, the NF can be utilized as a biofunctional polymeric material with better performance for the adsorption and desorption of oleuropein compared with MF and RSF.


2018 ◽  
Vol 5 (2) ◽  
pp. 024004 ◽  
Author(s):  
K Bhuvaneswari ◽  
R Divya Bharathi ◽  
T Pazhanivel
Keyword(s):  

RSC Advances ◽  
2017 ◽  
Vol 7 (89) ◽  
pp. 56550-56558 ◽  
Author(s):  
Huijun Li ◽  
Jingxin Zhu ◽  
Song Chen ◽  
Lan Jia ◽  
Yanlong Ma

This paper presents a new nanofabrication method for dual drug loaded regenerated silk fibroin (RSF) nanofibers, based on a simple, colloid-electrospinning technique.


2016 ◽  
Vol 172 ◽  
pp. 62-68 ◽  
Author(s):  
Faheem A. Sheikh ◽  
Richard Appiah-Ntiamoah ◽  
Mohammad Afzal Zargar ◽  
Jeyasselan Chandradass ◽  
Wook-Jin Chung ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2102 ◽  
Author(s):  
Chun-Yu Chen ◽  
Szu Ying Huang ◽  
Hung-Yu Wan ◽  
Yi-Ting Chen ◽  
Sheng-Ka Yu ◽  
...  

Electronic textiles (E-textiles) have been an area of intense industrial and academic research for years due to their advanced applications. Thus, the goal of this study was to develop highly conductive silk fibroin electrochromic nanofibers for use in E-textiles. The silk nanofibers were prepared by an electrospinning technique, and the conductive polyaniline (PANI) was added to impart the electrical conductivity and electroactive property to the resultant electrospun silk composite nanofibers. The experimental results showed that tuning the electrospinning procedure could control the morphology of the composite nanofibers, thus altering their mechanical properties and surface wettability. Furthermore, the developed PANI/silk composite fibers possess electroactive and electrochromic properties, such as adjusting the applied voltage. The developed strategy demonstrated the feasibility of incorporating not only electrical functionality but also electroactivity into sustainable silk nanofibers using electrospinning technique.


2016 ◽  
Vol 320 ◽  
pp. 469-478 ◽  
Author(s):  
Luminita Andronic ◽  
Luminita Isac ◽  
Sara Miralles-Cuevas ◽  
Maria Visa ◽  
Isabel Oller ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 110 ◽  
Author(s):  
Isabel Garrido ◽  
Salvador Aznar-Cervantes ◽  
Marina Aliste ◽  
María J. Yáñez-Gascón ◽  
Nuria Vela ◽  
...  

We have evaluated the efficiency of silk fibroin (SF) coated with ZnO nanoparticles in the photocatalytic disappearance of one acaricide (etoxazole) and three fungicides (difenoconazole, myclobutanil and penconazole) in water exposed to sunlight irradiation. Electrospun SF/ZnO mats were successfully synthesized by electrospinning technique and characterized by XRD, FE-SEM, XPS, XDS, FTIR, and BET. The influence of catalyst loading on the degradation kinetics of the different pesticides was examined in order to gain knowledge of maximum degradation efficiency. A significant increment in degradation rates was observed with the addition of ZnO. SF mats with 25 mg of ZnO were finally selected since no significant differences (p < 0.05) were detected when the loading was enlarged from 25 to 50 mg for the majority of the compounds. In the experimental conditions, the half-lives ranged from 33 min to 93 min for etoxazole and myclobutanil, respectively. The comparison of SF materials coated with similar amount of TiO2 and ZnO showed that the later was slightly more efficient to remove pesticide residues. Hence, the use of electrospun SF/ZnO nanostructures would provide an environmentally friendly approach with photocatalytic activity to be applied in the reclamation of water polluted by pesticides.


2016 ◽  
Vol 695 ◽  
pp. 273-277 ◽  
Author(s):  
Pornpen Siridamrong ◽  
Penchom Phrotjanatharee ◽  
Niyom Thamronganaskul

Silk fibroin (SF), chitosan (C), and gelatin (G) blend composition in formic acid have been manufactured by using electrospinning technique in our previous work. The SF: G: C at weight ratios of 10: 20: 1 and 20: 10: 1 (%wt: %wt: ml) were used for crosslinking testing. Glutaraldehyde (GA), and 1-ethyl-3-(3-dimethylaminopropyl) cabodiimide (EDC) / N-hydroxy succcinimide (NHS) (EDC/NHS) were chose as crosslinking agents. All samples were treated in such agents by fumigation for 72 hours followed by dipping for 10 minutes. Then those samples were washed in distill water for 3 times (1 time per 10 minutes) and dried in desiccator at room temperature. GA caused immediately shrink in both nanofiber mats and became clearly visible yellowish. However, a little shrinkage occurred after dipping in EDC/NHS. It possibly concluded that the EDC / NHS appropriated for SF: G: C blend nanofiber mats.


RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
pp. 58452-58457 ◽  
Author(s):  
Minghui Wang ◽  
Liying Cui ◽  
Songyang Li ◽  
Zhuoxin Li ◽  
Tianliang Ma ◽  
...  

Hollow nano-tubes of TiO2 and TiO2@ZnO hybrids were produced by a facile and mild approach combining an electrospinning technique and soaking method, followed by calcination.


RSC Advances ◽  
2020 ◽  
Vol 10 (41) ◽  
pp. 24653-24662 ◽  
Author(s):  
Parisa Aliahmadipoor ◽  
Dadkhoda Ghazanfari ◽  
Rasoul Jamshidi Gohari ◽  
Mohammad Reza Akhgar

In this study, novel electrospun nanofibers composed of organic polyvinylidine fluoride and inorganic Fe–Mn binary oxide nanoparticles were fabricated using an electrospinning technique for adsorptive removal of As(v) from polluted water.


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