scholarly journals In situ K2S activated electrospun carbon nanofibers with hierarchical meso/microporous structures for supercapacitors

RSC Advances ◽  
2019 ◽  
Vol 9 (57) ◽  
pp. 33539-33548
Author(s):  
Hua Liu ◽  
Weiguo Song ◽  
Aihua Xing

K2S was found to be an excellent in situ activation agent for the fabrication of electrospun carbon nanofibers with large surface area (835.0 m2 g−1) and hierarchical meso/microporous structures.

2017 ◽  
Vol 50 ◽  
pp. 1-17
Author(s):  
M. Alejandra Mazo ◽  
Javier Sanguino ◽  
Aitana Tamayo ◽  
Juan Rubio

Carbon nanofibers (CNFs) were grown in situ on porous glass at different temperatures and times using a Ni acetate catalyst and CH4/N2 as a carbon source. The porous glass was obtained by acid leaching of phase separated borosilicate glass, which generates a broad size distribution of mesopores (≈20 nm). Subsequent impregnation with Ni acetate reduces the pore size to ≈ 4 nm but also creates new micropores, thus increasing the surface area. During thermal treatment the surface area decreases as temperature rises, mainly due to shrinkage of the glassy matrix; however new pores are created at ≈ 70 nm (mainly at 600 oC) associated to the generation of CNFs on the glass surface, indicating this temperature offers the best conditions. The CNFs grow inside and fill in the micro-mesopores in the porous glass. They do not grow at 500 oC as the Ni acetate is not transformed into metallic Ni. Ni deactivation occurs at temperatures over 700 oC, thus reducing the formation of CNFs. At 1000 oC the degradation of CH4 leads to a thickening of the CNFs. The thermal degradation of the CNFs occurs in two steps, the first (360-416oC) corresponding to CNFs grown on the glass surface and the second (518-649oC) to CNFs grown inside the glass pores. Treatment times over 2 h lead to the deactivation of Ni, pore shrinkage and hence lower CNF yields.


RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47414-47420 ◽  
Author(s):  
Zi Ping Wu ◽  
Man Zhao ◽  
Jing Wei Hu ◽  
Wei Bo Zhang ◽  
Yan Hong Yin ◽  
...  

H2WO4 sheets approximately 50 nm long and 20 nm wide were prepared using a DWCNT template, and WC nanosheets with large surface areas were obtained when the H2WO4 was carbonized at a low temperature using a liquid carbon source.


RSC Advances ◽  
2019 ◽  
Vol 9 (40) ◽  
pp. 23324-23333 ◽  
Author(s):  
Xia Jiang ◽  
Chao Liu ◽  
Gaofeng Shi ◽  
Guoying Wang ◽  
Zhao Wang ◽  
...  

Carbon nanofibers (CNFs) have been widely used in electrochemical energy storage devices because of their excellent conductivity, extremely large surface area and structural stability.


2019 ◽  
Vol 33 (14n15) ◽  
pp. 1940016 ◽  
Author(s):  
Rounak R. Atram ◽  
Bhawana A. Manekar ◽  
Subhash B. Kondawar ◽  
Ramdas G. Atram ◽  
Pankaj Koinkar

Novel unique fabrication of ZnO nanoparticles decorated graphene beaded carbon nanofibers (G-CNF) encapsulated by polyaniline (PANI) nanocomposites through three steps by electrospinning, hydrothermal and in-situ polymerization is reported. As-synthesized G-CNF/ZnO/PANI and CNF/ZnO/PANI nanocomposites were comparatively studied by scanning electron microscopy and electrochemical characterizations for supercapacitor application. Electrochemical measurements of G-CNF/ZnO/PANI electrode revealed the maximum specific capacitance, discharge time, energy density and power density as compared to that of CNF/ZnO/PANI indicating the increase in surface area due to graphene incorporation in electrospinning of carbon nanofibers. The combination of electric double layer charge (EDLC) capacitance from high surface area of G-CNF and pseudo-capacitance from PANI and ZnO nanoparticles facilitates the synergistic effect of ternary components to enhance the electrochemical performance of G-CNF/ZnO/PANI nanocomposite.


Author(s):  
Mengke Wang ◽  
Jun Zhu ◽  
You Zi ◽  
Zheng-Guang Wu ◽  
Haiguo Hu ◽  
...  

In recent years, two-dimensional (2D) black phosphorus (BP) has been widely applied in many fields, such as (opto)electronics, transistors, catalysis and biomedical applications due to its large surface area, tunable...


Author(s):  
Chunmei Tang ◽  
Xiaoxu Wang ◽  
Shengli Zhang

Two-dimensional MXene nanomaterials are promising anode materials for Li-ion batteries (LIBs) due to their excellent conductivity, large surface area, and high Li capability.


2019 ◽  
Vol 11 (1) ◽  
pp. 38-54 ◽  
Author(s):  
Anand Maurya ◽  
Anurag Kumar Singh ◽  
Gaurav Mishra ◽  
Komal Kumari ◽  
Arati Rai ◽  
...  

Since the development of first lipid-based nanocarrier system, about 15% of the present pharmaceutical market uses nanomedicines to achieve medical benefits. Nanotechnology is an advanced area to meliorate the delivery of compounds for improved medical diagnosis and curing disease. Nanomedicines are gaining significant interest due to the ultra small size and large surface area to mass ratio. In this review, we discuss the potential of nanotechnology in delivering of active moieties for the disease therapy including their toxicity evidences. This communication will help the formulation scientists in understanding and exploring the new aspects of nanotechnology in the field of nanomedicine.


2021 ◽  
Vol 875 ◽  
pp. 160034
Author(s):  
Na Liu ◽  
Fan Fan ◽  
Wei Xu ◽  
Hao Zhang ◽  
Qi Zhou ◽  
...  

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