scholarly journals Design and performance study of high efficiency/low efficiency roll-off/high CRI hybrid WOLEDs based on aggregation-induced emission materials as fluorescent emitters

2019 ◽  
Vol 3 (12) ◽  
pp. 2652-2658 ◽  
Author(s):  
Zeng Xu ◽  
Jiabao Gu ◽  
Jian Huang ◽  
Chengwei Lin ◽  
Yuanzhao Li ◽  
...  

AIEgens TPB-AC and CP-BP-PXZ are used as non-doped blue and green layers, and Ir(dmppr-mp)2(divm) doped TCTA is used as red layer to construct high-performance hybrid WOLEDs.

2018 ◽  
Vol 6 (40) ◽  
pp. 10793-10803 ◽  
Author(s):  
Shian Ying ◽  
Dezhi Yang ◽  
Xianfeng Qiao ◽  
Yanfeng Dai ◽  
Qian Sun ◽  
...  

High-performance WOLEDs realizing high efficiency and low efficiency roll-off simultaneously were achieved by strategically managing triplet excitons in the emission layer.


2020 ◽  
Vol 8 (36) ◽  
pp. 12450-12456 ◽  
Author(s):  
Yuwen Chen ◽  
Yibing Wu ◽  
Chengwei Lin ◽  
Yanfeng Dai ◽  
Qian Sun ◽  
...  

High performance hybrid WOLEDs have been realized by precisely inserting ultrathin red/green phosphorescent layers in a blue exciplex emitter.


Nanoscale ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 2648-2656 ◽  
Author(s):  
Dechao Guo ◽  
Zeng Xu ◽  
Dezhi Yang ◽  
Dongge Ma ◽  
Benzhong Tang ◽  
...  

High performance photomultiplication-type organic photodetectors based on an AIE material were successfully fabricated by designing a device structure.


2020 ◽  
Vol 4 (4) ◽  
pp. 1206-1211 ◽  
Author(s):  
Jiabao Gu ◽  
Zeng Xu ◽  
Dongge Ma ◽  
Anjun Qin ◽  
Ben Zhong Tang

AIE polymers pTPE-DPA-Cz and pTPE-DPA-Flu are synthesized and used as emitting layers in doped and non-doped polymeric LEDs through a solution process, and show maximum EQE of 3.26% in the doped PLEDs and CE of 3.69 cd A−1 for the non-doped PLEDs and low efficiency roll-off.


Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5438
Author(s):  
Danijela S. Kretić ◽  
Ivana S. Veljković ◽  
Aleksandra B. Đunović ◽  
Dušan Ž. Veljković

The existence of areas of strongly positive electrostatic potential in the central regions of the molecular surface of high-energy molecules is a strong indicator that these compounds are very sensitive towards detonation. Development of high-energy compounds with reduced sensitivity towards detonation and high efficiency is hard to achieve since the energetic molecules with high performance are usually very sensitive. Here we used Density Functional Theory (DFT) calculations to study a series of bis(acetylacetonato) and nitro-bis(acetylacetonato) complexes and to elucidate their potential application as energy compounds with moderate sensitivities. We calculated electrostatic potential maps for these molecules and analyzed values of positive potential in the central portions of molecular surfaces in the context of their sensitivity towards detonation. Results of the analysis of the electrostatic potential demonstrated that nitro-bis(acetylacetonato) complexes of Cu and Zn have similar values of electrostatic potential in the central regions (25.25 and 25.06 kcal/mol, respectively) as conventional explosives like TNT (23.76 kcal/mol). Results of analysis of electrostatic potentials and bond dissociation energies for the C-NO2 bond indicate that nitro-bis(acetylacetonato) complexes could be used as potential energetic compounds with satisfactory sensitivity and performance.


Author(s):  
Maher A. El-Masri

Intercooled/Recuperated gas turbine systems provide high-efficiency and power density for naval propulsion. Current aero-derivative systems are capable of about 43% thermal efficiency in this configuration. With continued progress in gas-turbine materials and cooling technology, the possibility of further improving system performance by incorporation of gas-turbine reheat arises. A preliminary scan of this class of cycles is presented and compared with non-reheat intercooled/recuperated cycles at two levels of component technology. For conservative component technology, the reheat is found to provide very modest performance advantages. With advanced components and ceramic thermal barrier coatings, the reheat is found to offer potential for specific power improvements of up to 33% and for modest efficiency gains, on the order of one percentage point, while enabling turbine inlet temperatures well below those for the most efficient non-reheat cycles. The high-performance reheat systems, however, require reheat-combustor inlet temperatures beyond current practice. The use of water-injection in the intercooler, together with an aftercooler and a water-injected evaporative-recuperator is found to produce very large gains in efficiency as well as specific power. This modification may be feasible for land-based systems, where it can compete favourably with combined cycles. Despite the difficulty of obtaining pure water for a shipboard propulsion system, those large gains may justify further studies of this system and of means to provide its water supply in marine applications.


Author(s):  
A Engeda

Vaned diffusers for centrifugal compressors have decades of development history, but most of it is of a proprietary and empirical nature. Centrifugal compressor designers are continuously searching for a diffuser system that combines the good qualities of vaneless and vaned diffuser systems. Vaneless diffusers are known to possess wide operating range with relatively low efficiency while current conventional vaned diffusers have narrow range and high efficiency. The low solidity vaned diffuser (LSVD) has shown good performance from both range and efficiency standpoints. Its relatively high efficiency and wide flow range potentials are strong current factors, leading the compressor manufacturer to seriously consider it as the best compromise diffuser that has been sought through the years. This paper discusses the design and experimental performance results of eight flat plate LSVDs. These diffusers had a solidity of 0.9, 0.8, 0.7 and 0.6. Eight low solidity vaned diffusers (LSVD1 to LSVD8) and for comparison purposes two vaneless diffusers (VNL1 and VNL2) and a conventional vaned diffuser (CVND) were all tested downstream of the same impeller at three speeds.


2019 ◽  
Vol 22 (2) ◽  
pp. 228-234 ◽  
Author(s):  
Ut Dong THACH ◽  
Thi Lan Nhi Do ◽  
Ngoc Lan Anh Do ◽  
Minh Huy Do

Introduction: Ionic liquids (ILs) have attached many attentions due to their interesting physicochemical properties. However, ionic liquids have several disadvantages including high viscosity, difficult to purify, separate and recycle, and expensive. Therefore, supported ionic liquids (SIL) have been developed to overcome these problems. SIL based on cellulose material was conventionally synthesized by silanization reaction between ionic liquid trialkoxyl silane and hydroxyl groups on the surface of cellulose. However, low reactivity of cellulose hydroxyl groups causes the low efficiency of silanization reaction. With the aim to resolve these problems and improve the reactivity of cellulose silanization reaction, cellulose graft ionic liquid was synthesized and characterized. Methods: Cellulose graft ionic liquid (CL-IL) material was synthesized by silanization reaction. The influence of reaction condition such as IL/CL (w/w) ratio, base catalyst (NH3) and agent coupling tetraethyl orthosilicate (TEOS) on silanization reaction was investigated. The modified CL-IL materials were characterized using FT-IR, TGA, SEM. The ion exchange properties were evaluated via batch adsorption studies to evidence the efficiency of silanization reaction of cellulose. Results: The study indicated that adding TEOS with NH3 catalyst could significantly increase the number of imidazolium groups grafted on cellulose about 75% compared to the conventional approach. CL-IL material is an efficient anion exchange materials displaying fast kinetic adsorption and high capacity adsorption of MO up to 1.4 mmol g-1. Conclusion: High-efficiency of cellulose silanization was obtained by using coupling agent TEOS and base catalyst. Therefore, the silanization reaction can be used for synthesis divers of functional cellulose materials. This approach can be aimed for the design of cheaper and high-performance materials for catalysis, polymer composite and adsorption in water treatment and depollution of industrial wastewater.  


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