scholarly journals Synthesis of cellulose graft ionic liquid using silanization reaction

2019 ◽  
Vol 22 (2) ◽  
pp. 228-234 ◽  
Author(s):  
Ut Dong THACH ◽  
Thi Lan Nhi Do ◽  
Ngoc Lan Anh Do ◽  
Minh Huy Do
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
High Performance ◽  
High Efficiency ◽  
High Capacity ◽  
High Viscosity ◽  
Batch Adsorption ◽  
Hydroxyl Groups ◽  
Base Catalyst ◽  
Low Efficiency

Introduction: Ionic liquids (ILs) have attached many attentions due to their interesting physicochemical properties. However, ionic liquids have several disadvantages including high viscosity, difficult to purify, separate and recycle, and expensive. Therefore, supported ionic liquids (SIL) have been developed to overcome these problems. SIL based on cellulose material was conventionally synthesized by silanization reaction between ionic liquid trialkoxyl silane and hydroxyl groups on the surface of cellulose. However, low reactivity of cellulose hydroxyl groups causes the low efficiency of silanization reaction. With the aim to resolve these problems and improve the reactivity of cellulose silanization reaction, cellulose graft ionic liquid was synthesized and characterized. Methods: Cellulose graft ionic liquid (CL-IL) material was synthesized by silanization reaction. The influence of reaction condition such as IL/CL (w/w) ratio, base catalyst (NH3) and agent coupling tetraethyl orthosilicate (TEOS) on silanization reaction was investigated. The modified CL-IL materials were characterized using FT-IR, TGA, SEM. The ion exchange properties were evaluated via batch adsorption studies to evidence the efficiency of silanization reaction of cellulose. Results: The study indicated that adding TEOS with NH3 catalyst could significantly increase the number of imidazolium groups grafted on cellulose about 75% compared to the conventional approach. CL-IL material is an efficient anion exchange materials displaying fast kinetic adsorption and high capacity adsorption of MO up to 1.4 mmol g-1. Conclusion: High-efficiency of cellulose silanization was obtained by using coupling agent TEOS and base catalyst. Therefore, the silanization reaction can be used for synthesis divers of functional cellulose materials. This approach can be aimed for the design of cheaper and high-performance materials for catalysis, polymer composite and adsorption in water treatment and depollution of industrial wastewater.  

High-performance polymeric ionic liquid–silica hybrid ionogel electrolytes for lithium metal batteries

2016 ◽  
Vol 4 (36) ◽  
pp. 13822-13829 ◽  
Author(s):  
Xiaowei Li ◽  
Sijian Li ◽  
Zhengxi Zhang ◽  
Jun Huang ◽  
Li Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
High Performance ◽  
High Capacity ◽  
Electrochemical Stability ◽  
Rate Performance ◽  
Lithium Metal ◽  
Polymeric Ionic Liquid ◽  
Lithium Metal Batteries ◽  
Silica Hybrid

Hybrid ionogel electrolytes have high thermal and electrochemical stability, good ionic conductivity, and potential to suppress Li dendrite formation. Solid-state lithium metal batteries with hybrid electrolytes reveal high capacity and remarkable rate performance.

scholarly journals Modification of Chitin Particles with Ionic Liquids Containing Ethyl Substituent in a Cation

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Malgorzata M. Jaworska ◽  
Andrzej Górak ◽  
Joanna Zdunek
Keyword(s):  
Particle Size ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Hydrogen Bonds ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
High Viscosity ◽  
Physical Structure ◽  
Ethyl Group ◽  
Network Of Hydrogen Bonds

Chitin cannot be dissolved in conventional solvents due to the strong inter- and intrasheet network of hydrogen bonds and the large number of crystalline regions. Some ionic liquids (ILs) have been suggested in the literature as possible solvents for chitin. Seven of them, all having an ethyl group as substituent in the cationic ring, have been tested in this work: [Emim][Cl], [Emim][Br], [Emim][I], [Emim][OAc], [Emim][Lact], [Epyr][I], and [EMS][BFSI]. Chitin was insoluble in [EMS][BFSI] while for all other ILs solubility was limited due to high viscosity of solutions and equilibria have not been reached. Changes in physical structure, particle size distribution, and crystallinity of recovered chitin depended on ionic liquid used. Increase in porosity was observed for chitin treated with [Emim][Cl], [Emim][I], [Emim][Br], and [Emim][Lact]; changes in particle size distribution were observed for [Emim][AcOH] and [EMS][BFSI]; increase in crystallinity was noticed for chitin treated with [Epyr][I] while decrease in crystallinity for [Emim][I] was noticed. All tested ionic liquids were reused four times and changes in FTIR spectra could be observed for each IL.

Effect of Ionic Liquid on the Properties of Nanocomposites Based on Epoxy/CNT Hardened with MCDEA

2021 ◽  
Vol 1165 ◽  
pp. 31-38
Author(s):  
Danielle Ferreira dos Santos ◽  
Bluma Guenther Soares
Keyword(s):  
Ionic Liquid ◽  
High Performance ◽  
High Viscosity ◽  
Van Der Waals Interactions ◽  
Great Tendency ◽  
Excellent Performance ◽  
Rigid System ◽  
Dispersion Agent ◽  
Thermal And Electrical Properties ◽  
Diethyl Phosphate

Thermosetting systems based on epoxy resin (RE) with the dispersion of carbon nanotubes (CNT), have been extensively studied by the development of high-performance materials with interesting mechanical, thermal and electrical properties that the thermo-rigid system achieves with the addition of CNT, and thus contribute to obtain composites with excellent performance in low amounts of this filler. However, ensuring a good dispersion of these systems is not easy, as CNTs have a great tendency to cluster due to Van der Waals interactions. To assist in the dispersion of the systems, a phosphonium-based ionic liquid, tributyl (ethyl) -phosphonium diethyl phosphate, acted with a double role, as a dispersion agent and catalyst in systems hardened with MCDEA (4,4’-methylenebis (3 - chloro-2,6-diethylaniline), which is a solid compound giving the systems high viscosity, and with the addition of LI improved the dispersion of the systems, as well as the processability in the preparation of the nanocomposites.

Improvement of efficiency and its roll-off at high brightness in white organic light-emitting diodes by strategically managing triplet excitons in the emission layer

2018 ◽  
Vol 6 (40) ◽  
pp. 10793-10803 ◽  
Author(s):  
Shian Ying ◽  
Dezhi Yang ◽  
Xianfeng Qiao ◽  
Yanfeng Dai ◽  
Qian Sun ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Organic Light Emitting Diodes ◽  
Emission Layer ◽  
High Brightness ◽  
Light Emitting ◽  
Organic Light ◽  
Low Efficiency ◽  
Triplet Excitons

High-performance WOLEDs realizing high efficiency and low efficiency roll-off simultaneously were achieved by strategically managing triplet excitons in the emission layer.

Simultaneous high efficiency/CRI/spectral stability and low efficiency roll-off hybrid white organic light-emitting diodes via simple insertion of ultrathin red/green phosphorescent emitters in a blue exciplex

2020 ◽  
Vol 8 (36) ◽  
pp. 12450-12456 ◽  
Author(s):  
Yuwen Chen ◽  
Yibing Wu ◽  
Chengwei Lin ◽  
Yanfeng Dai ◽  
Qian Sun ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Light Emitting Diodes ◽  
Spectral Stability ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Organic Light ◽  
Low Efficiency

High performance hybrid WOLEDs have been realized by precisely inserting ultrathin red/green phosphorescent layers in a blue exciplex emitter.

scholarly journals Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves

Processes ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 412 ◽  
Author(s):  
Dan Yu ◽  
Shintaro Morisada ◽  
Hidetaka Kawakita ◽  
Keisuke Ohto ◽  
Katsutoshi Inoue ◽  
...  
Keyword(s):  
Alkali Metals ◽  
High Efficiency ◽  
Polluted Water ◽  
Batch Adsorption ◽  
Hydroxyl Groups ◽  
Radioactive Cesium ◽  
Tea Leaves ◽  
Inorganic Ion ◽  
Langmuir Isotherm Model ◽  
Cationic Exchange

To remove the radioactive cesium from the polluted environment, tea leaves were chosen as cheap, and abundantly available environment-friendly bio-adsorbents to investigate the alkali metals adsorption. Fresh and used tea leaves (FT and UT) were found to have high efficiency and selectivity for cesium adsorption, after the crosslinking with concentrated sulfuric acid. Calculation of the proton-exchanged amount suggested adsorption mechanism of three alkali metals on crosslinked tea leaves involve a cationic exchange with a proton from the hydroxyl groups of the crosslinked tea leaves, as well as coordination with ethereal oxygen atoms to form the chelation. Further, considering the practical application of the polluted water treatment, the competitive adsorption of Cs+ and Na+ ions was investigated by the batch-wise method and column chromatography separation. Unlike the conventional ion exchange and chelate resins with less selectivity for Cs+ coexisting cations, both crosslinked fresh tea leaves (CFT) and crosslinked used tea leaves (CUT) exhibited Cs selectivity over Na. In addition, batch adsorption studies revealed that the cesium adsorptions were driven by the Langmuir isotherm model; the capacity of both crosslinked tea leaves for cesium adsorption was determined to be around 2.5 mmol g−1. The adsorption capacities are sufficiently higher in comparison with those of synthetic polymers, inorganic ion-exchangers, and other bio-adsorbents.

scholarly journals High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes

2018 ◽  
Vol 115 (22) ◽  
pp. 5676-5680 ◽  
Author(s):  
Qiuwei Shi ◽  
Yiren Zhong ◽  
Min Wu ◽  
Hongzhi Wang ◽  
Hailiang Wang
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Coulombic Efficiency ◽  
High Capacity ◽  
Protective Layer ◽  
Rechargeable Batteries ◽  
Metal Electrodes ◽  
Lithium Metal Anodes ◽  
Low Efficiency ◽  
Almost All

Discovering new chemistry and materials to enable rechargeable batteries with higher capacity and energy density is of paramount importance. While Li metal is the ultimate choice of a battery anode, its low efficiency is still yet to be overcome. Many strategies have been developed to improve the reversibility and cycle life of Li metal electrodes. However, almost all of the results are limited to shallow cycling conditions (e.g., 1 mAh cm−2) and thus inefficient utilization (<1%). Here we achieve Li metal electrodes that can be deeply cycled at high capacities of 10 and 20 mAh cm−2 with average Coulombic efficiency >98% in a commercial LiPF6/carbonate electrolyte. The high performance is enabled by slow release of LiNO3 into the electrolyte and its subsequent decomposition to form a Li3N and lithium oxynitrides (LiNxOy)-containing protective layer which renders reversible, dendrite-free, and highly dense Li metal deposition. Using the developed Li metal electrodes, we construct a Li-MoS3 full cell with the anode and cathode materials in a close-to-stoichiometric amount ratio. In terms of both capacity and energy, normalized to either the electrode area or the total mass of the electrode materials, our cell significantly outperforms other laboratory-scale battery cells as well as the state-of-the-art Li ion batteries on the market.

Preconcentration and Determination of Aromatic Amines with Temperature-Controlled Ionic Liquid Dispersive Liquid Phase Microextraction in Combination with High Performance Liquid Chromatography

2012 ◽  
Vol 95 (5) ◽  
pp. 1534-1540 ◽  
Author(s):  
Qingxiang Zhou ◽  
Yuantuan Gao ◽  
Junping Xiao ◽  
Guohong Xie
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Liquid Phase ◽  
Aromatic Amines ◽  
High Performance ◽  
Correlation Coefficients ◽  
Detection Sensitivity ◽  
Liquid Phase Microextraction ◽  
Temperature Controlled

Abstract This paper reports a new method for the determination of aromatic amines with temperature-controlled ionic liquid dispersive liquid-phase microextraction in combination with HPLC and results of investigation of the influence of anions in ionic liquids on the extraction performance. In these experiments, 1-octyl-3-methylimidazolium hexafluorophosphate ([C8MIM][PF6]), 1-octyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imide ([C8MIM][NTf2]), and 1-octyl-3-methylimidazolium tetrafluoroborate ([C8MIM][BF4]) were used as the extraction solvents for the investigation of the effect of anions in ionic liquids. Other parameters affecting the microextraction performance were also investigated. Under the optimal conditions, the proposed method had good linearity over the concentration ranges of 1.0–100 μg/L for 2, 4-dimethylaniline, 2-chloroanline, and N,N-dimethylaniline, and 1.5–150 μg/L for N,N-dimethylaniline and alpha-naphthylamine, with excellent correlation coefficients (R2 ≥ 0.999), excellent detection sensitivity with LODs (S/N = 3) in the range of 0.39–0.63 μg/L, and precision in the range of 3.2–5.4% RSD (n = 6). Real water samples were analyzed with the established method, and good spike recoveries in the range of 86.3 to 98.9% were obtained. These results indicated that this method would be useful in the routine analysis of such pollutants.

Volume-invariant ionic liquid microbands as highly durable wearable biomedical sensors

2016 ◽  
Vol 3 (3) ◽  
pp. 208-213 ◽  
Author(s):  
Yan Wang ◽  
Shu Gong ◽  
Stephen Jia Wang ◽  
George P. Simon ◽  
Wenlong Cheng
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
High Performance ◽  
Wearable Sensors ◽  
Flow Properties ◽  
Biomedical Sensors

Non-volatile and flow properties of ionic liquids allow for simple ‘fill and seal’ approach to fabricate high-performance wearable sensors without materials delamination or cracking.

Synthesis of Functional Ionic Liquids by Thermal Heating and Ultrasonic-Assisted Methods

2012 ◽  
Vol 581-582 ◽  
pp. 326-329
Author(s):  
Zhe Zhang ◽  
Yi He Li ◽  
Hua Xiao ◽  
Chi Zhou Tu ◽  
Chun Hua Wang
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Mild Condition ◽  
High Efficiency ◽  
Ester Group ◽  
Synthesis Condition ◽  
Synthesis Methods ◽  
Thermal Heating ◽  
Heating Method ◽  
Ultrasonic Assisted

1-(2-Methacryloyloxy)ethyl-3-butylimidazolium bromide, a kind of functional ionic liquid containing ester group, was synthesized by two synthesis methods, denoted as thermal heating method and ultrasonic-assisted method. The optimal synthesis condition of the thermal heating method is discussed. Comparison of the two methods shows that ultrasound significantly enhances the efficiency of the reaction. The ultrasonic-assisted method is quite promising in synthesis of ionic liquids with mild condition and high efficiency.

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