The novel two-dimensional photocatalyst SnN3 with enhanced visible-light absorption for overall water splitting

Nanoscale ◽  
2019 ◽  
Vol 11 (40) ◽  
pp. 18628-18639 ◽  
Author(s):  
Shengyao Wu ◽  
Yanqing Shen ◽  
Xu Gao ◽  
Yanyan Ma ◽  
Zhongxiang Zhou

SnN3 monolayer can conduct overall photocatalytic splitting of water and has ultra-high visible light absorption capacity.

Author(s):  
Xin Zou ◽  
Xueyang Han ◽  
Chengxiong Wang ◽  
Yunkun Zhao ◽  
Chun Du ◽  
...  

Ta3N5 is regarded as a promising candidate material with adequate visible light absorption and band structure for photoelectrochemical water splitting. However, the performance of Ta3N5 is severely limited by the...


Nanoscale ◽  
2021 ◽  
Author(s):  
Hanpu Liang ◽  
Yifeng Duan

GaN-ZnO alloys are more promising semiconductors than their counterparts for optoelectronic applications due to the abrupt red shift in the visible-light range. Unfortunately, the strong internal electrostatic field (IEF) seriously...


2022 ◽  
Author(s):  
Hong Li ◽  
Xingqiang Cui ◽  
Weizhe Song ◽  
Zhanyuan Yang ◽  
Yanhui Li ◽  
...  

Abstract To improve the photocathodic protection performance of traditional TiO2 photoanodes for metals, constructing a Z-scheme heterojunction is one of the most promising and creative strategies. Herein, we fabricated a novel Z-scheme MgIn2S4 nanosheets/TiO2 nanotube nanocomposite through anodization and hydrothermal method. The optimized Z-scheme MgIn2S4/TiO2 nanocomposites exhibited stronger visible light absorption, higher separation efficiency of photoelectrons and photocathodic protection performances in comparison to pure TiO2. The theoretical analysis and experimental results show that the Z-scheme heterojunction and oxygen vacancies jointly improved the separation efficiency of photogenerated electron-hole pairs and visible light absorption capacity, thereby improving the photoelectric conversion performance of the MgIn2S4/TiO2 nanocomposites. Furthermore, the influence of the precursor solution concentration on the photocathodic protection performances of the composites was investigated. As a result, when the concentration of magnesium source in the precursor solution was 0.06 mmol, the prepared MgIn2S4/TiO2-0.06 displayed the best photocathodic protection performance. In addition, the hydroxyl radicals (•OH) generated in the electron spin resonance (ESR) experiment verified the Z-scheme heterojunction mechanism of the MgIn2S4/TiO2 composite, and also demonstrated the excellent redox performance of the composite. This work provides valuable reference for the construction of high-performance Z-scheme heterojunctions for photocathode protection of metals.


RSC Advances ◽  
2019 ◽  
Vol 9 (30) ◽  
pp. 17165-17178 ◽  
Author(s):  
Smilja Marković ◽  
Ivana Stojković Simatović ◽  
Sanita Ahmetović ◽  
Ljiljana Veselinović ◽  
Stevan Stojadinović ◽  
...  

Employing CTAB in the microwave synthesis of ZnO particles enables improvement of their visible light absorption capacity and photo(electro)catalytic activity.


2019 ◽  
Vol 7 (10) ◽  
pp. 5702-5711 ◽  
Author(s):  
Yawei Wang ◽  
Shu Jin ◽  
Guoxiang Pan ◽  
Zuxin Li ◽  
Long Chen ◽  
...  

Zr doping maintains the visible light absorption of LaTaON2 and contributes to enhanced photocatalytic activities for water splitting.


2020 ◽  
Vol 22 (42) ◽  
pp. 24446-24454 ◽  
Author(s):  
Guangzhao Wang ◽  
Zongfeng Li ◽  
Weikang Wu ◽  
Hao Guo ◽  
Cong Chen ◽  
...  

A metal-free type-II h-BN/C2N heterostructure is shown as a potential visible light water-splitting photocatalyst.


2020 ◽  
Vol 63 (8) ◽  
pp. 1134-1141
Author(s):  
Cen-Feng Fu ◽  
Chuanyu Zhao ◽  
Qijing Zheng ◽  
Xingxing Li ◽  
Jin Zhao ◽  
...  

2017 ◽  
Vol 1 (9) ◽  
pp. 1968-1980 ◽  
Author(s):  
Yang Yang ◽  
Weijie Zheng ◽  
Daojian Cheng ◽  
Dapeng Cao

Development of an efficient photocatalyst with both strong visible light absorption and high charge mobility is highly desirable but still remains a great challenge.


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