Magnesium-induced preparation of boron nitride nanotubes and their application in thermal interface materials

Nanoscale ◽  
2019 ◽  
Vol 11 (24) ◽  
pp. 11457-11463 ◽  
Author(s):  
Chaowei Li ◽  
Xiaoyang Long ◽  
Songfeng E ◽  
Qichong Zhang ◽  
Taotao Li ◽  
...  

The Mg induction strategy is low cost and efficiently generates BNNTs, which can be widely used in thermal interface materials.

Polymers ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 799 ◽  
Author(s):  
Chun-An Liao ◽  
Yee-Kwan Kwan ◽  
Tien-Chan Chang ◽  
Yiin-Kuen Fuh

A simple and sustainable production of nanoplatelet graphite at low cost is presented using carbon-based materials, including the recycled lead-graphite pencils. In this work, exfoliated graphite nanoplatelets (EGNs), ball-milled exfoliated graphite nanoplatelets (BMEGNs) and recycled lead-graphite pencils (recycled 2B), as well as thermally cured polydimethylsiloxane (PDMS), are used to fabricate highly stretchable thermal-interface materials (TIMs) with good thermally conductive and mechanically robust properties. Several characterization techniques including scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) showed that recycled nanoplatelet graphite with lateral size of tens of micrometers can be reliably produced. Experimentally, the thermal conductivity was measured for EGNs, BMEGNs and recycled 2B fillers with/without the effect of ball milling. The in-plane thermal conductivities of 12.97 W/mK (EGN), 13.53 W/mK (recycled 2B) and 14.56 W/mK (BMEGN) and through-plane thermal conductivities of 0.76 W/mK (EGN), 0.84 W/mK (recycled 2B) and 0.95 W/mK (BMEGN) were experimentally measured. Anisotropies were calculated as 15.31, 15.98 and 16.95 for EGN, recycled 2B and BMEGN, respectively. In addition, the mechanical robustness of the developed TIMs is such that they are capable of repeatedly bending at 180 degrees with outstanding flexibility, including the low-cost renewable material of recycled lead-graphite pencils. For heat dissipating application in high-power electronics, the TIMs of recycled 2B are capable of effectively reducing temperatures to approximately 6.2 °C as favorably compared with thermal grease alone.


Thermal management is one of the most critical issues in electronics due to increasing power densities. This problem is getting even worse for small and sophisticated devices due to air gaps present between the heat source and heat sink. Thermal interface materials (TIM) are used to reduce the air gaps and significantly increase the heat transfer capability of the system. A high-thermal-performance, cost-effective and reliable TIM would be needed to dissipate the generated heat, which could enable significant reductions in weight, volume and cost of the thermal management system. In this study a number of different nanostructured materials are reviewed for potential use as a filler material in our effort to develop advanced TIM composite. Some of the candidate filler materials considered is Carbon Nanotubes, Graphene and Few Layer Graphene (FLG), Boron Nitride Nanotubes (BNNT) and Boron Nitride Nanomesh (BNNM) and Boron Arsenide (BAs). Objective is to identify composition of boron arsenide as filler in polymer-nanostructured material composite TIM for high heat flux applications. In order to design boron-arsenide-based TIM composite with enhanced effective thermal conductivity, a number of metallic and nonmetallic base-filler material composites are considered with varying filler fractions. Empirical mixture models based on effective medium theories (EMT) are evaluated for estimating effective conductivity of the two-component boron arsenide-filler composite TIM structure.


Author(s):  
Wei Yu ◽  
◽  
Changqing Liu ◽  
Lin Qiu ◽  
Ping Zhang ◽  
...  

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