A dual supramolecular crosslinked polyurethane with superior mechanical properties and autonomous self-healing ability

2020 ◽  
Vol 44 (18) ◽  
pp. 7395-7400 ◽  
Author(s):  
Shaobin Xu ◽  
Dekun Sheng ◽  
Yan Zhou ◽  
Haohao Wu ◽  
Haopu Xie ◽  
...  

The dual-dynamic networks endow polyurethane with excellent mechanical properties and autonomous self-healing ability.

2022 ◽  
Author(s):  
Dong Wang ◽  
Dingyao Liu ◽  
JianHua Xu ◽  
JiaJun Fu ◽  
Kai Wu

It is still a formidable challenge to develop ideal thermal dissipation materials with simultaneous high thermal conductivity, excellent mechanical softness and toughness, and spontaneous self-healing. Herein, we report the introduction...


2020 ◽  
Vol 44 (23) ◽  
pp. 9903-9911 ◽  
Author(s):  
Xueqin Zhang ◽  
Ruqing Zhang ◽  
Shu Wu ◽  
Ying Sun ◽  
Hong Yang ◽  
...  

Using SDS-C18 micelle as a physical crosslinker and SiPU as a multifunctional chemical crosslinker, a new type of dual-crosslinked self-healing hydrogel with excellent stretchability, strength and resilience was synthesized.


2013 ◽  
Vol 1 (41) ◽  
pp. 5644 ◽  
Author(s):  
Nina Yu. Kostina ◽  
Shahriar Sharifi ◽  
Andres de los Santos Pereira ◽  
Jiří Michálek ◽  
Dirk W. Grijpma ◽  
...  

2018 ◽  
Vol 6 (46) ◽  
pp. 23425-23434 ◽  
Author(s):  
Youhao Zhang ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu

Novel transparent and foldable polysiloxane films simultaneously showing superior mechanical properties, repeatable self-healing ability and high heat-resistance have been developed.


2018 ◽  
Vol 42 (12) ◽  
pp. 10348-10356 ◽  
Author(s):  
Yang Wang ◽  
Ting Li ◽  
Piming Ma ◽  
Shengwen Zhang ◽  
Mingliang Du ◽  
...  

A fast NIR light-induced self-healing PCL nanocomposite with superior mechanical properties was achieved by tailoring the cyclic mechanical annealing process.


Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3538
Author(s):  
Jiawei Li ◽  
Weiming Yang ◽  
Zhao Ning ◽  
Bin Yang ◽  
Yanning Zeng

Rosin is an abundant natural product. In this paper, for the first time, a rosin derivative is employed as a monomer for the preparation of polyurethane vitrimers with improved properties. A novel rosin-based polyurethane vitrimers network was constructed by the reaction between isocyanates (HDI) as curing agent and monomers with alcohol groups modified from rosin. The dynamic rosin-based polyurethane vitrimers were characterized by FTIR and dynamic mechanical analysis. The obtained rosin-based polyurethane vitrimers possessed superior mechanical properties. Due to the dynamic urethane linkages, the network topologies of rosin-based polyurethane vitrimers could be altered, contributing self-healing and reprocessing abilities. Besides, we investigated the effects of healing time and temperature on the self-healing performance. Moreover, through a hot press, pulverized samples of 70%VPUOH could be reshaped several times, and the mechanical properties of the recycled samples were restored, with tensile strength being even higher than the of that of the original samples.


2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.


Author(s):  
Romaneh Jalilian ◽  
David Mudd ◽  
Neil Torrez ◽  
Jose Rivera ◽  
Mehdi M. Yazdanpanah ◽  
...  

Abstract The sample preparation for transmission electron microscope can be done using a method known as "lift-out". This paper demonstrates a method of using a silver-gallium nanoneedle array for a quicker sharpening process of tungsten probes with better sample viewing, covering the fabrication steps and performance of needle-tipped probes for lift-out process. First, an array of high aspect ratio silver-gallium nanoneedles was fabricated and coated to improve their conductivity and strength. Then, the nanoneedles were welded to a regular tungsten probe in the focused ion beam system at the desired angle, and used as a sharp probe for lift-out. The paper demonstrates the superior mechanical properties of crystalline silver-gallium metallic nanoneedles. Finally, a weldless lift-out process is described whereby a nano-fork gripper was fabricated by attaching two nanoneedles to a tungsten probe.


2021 ◽  
Author(s):  
Zhanyu Jia ◽  
Guangyao Li ◽  
Juan Wang ◽  
shouhua Su ◽  
Jie Wen ◽  
...  

Conductivity, self-healing and moderate mechanical properties are necessary for multifunctional hydrogels which have great potential in health-monitor sensor application. However, the combination of electrical conductivity, self-healing and good mechanical properties...


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