scholarly journals An efficient hydrogenation catalytic model hosted in a stable hyper-crosslinked porous-organic-polymer: from fatty acid to bio-based alkane diesel synthesis

2020 ◽  
Vol 22 (6) ◽  
pp. 2049-2068 ◽  
Author(s):  
Chitra Sarkar ◽  
Subhash Chandra Shit ◽  
Duy Quang Dao ◽  
Jihyeon Lee ◽  
Ngoc Han Tran ◽  
...  

A novel Pd-based catalyst hosted over a nitrogen enriched fibrous porous-organic-polymer with a high density of step sites and exhibits versatile catalytic performance over different types of vegetable oils to furnish long chain diesel-range alkanes.

2017 ◽  
Vol 8 (30) ◽  
pp. 4327-4331 ◽  
Author(s):  
Wei Zhu ◽  
Zheng-Dong Ding ◽  
Xuan Wang ◽  
Tao Li ◽  
Rui Shen ◽  
...  

A porphyrin-based porous organic polymer PPOP-1(Fe) with a three-dimensional diamond structure was synthesized, which exhibits high stability and excellent catalytic efficiency as a biomimetic catalyst.


RSC Advances ◽  
2015 ◽  
Vol 5 (46) ◽  
pp. 36240-36261 ◽  
Author(s):  
M. M. Rashed ◽  
M. A. Kalam ◽  
H. H. Masjuki ◽  
H. K. Rashedul ◽  
A. M. Ashraful ◽  
...  

Biodiesel consists of long chain fatty acid esters derived from vegetable oils, animal fats, and used oils.


2011 ◽  
Vol 108 (1) ◽  
pp. 71-79 ◽  
Author(s):  
Soressa M. Kitessa ◽  
Paul Young ◽  
Greg Nattrass ◽  
Graham Gardner ◽  
Kelly Pearce ◽  
...  

Vegetable oils containing stearidonic acid (SDA, 18 : 4n-3) are considered better precursors of long-chain n-3 PUFA (LC n-3 PUFA) than those with only α-linolenic acid (ALA, 18 : 3n-3). The present study re-examined this premise using treatments where added ALA from linseed oil was matched with ALA plus SDA from echium oil. Lambs (n 6) were abomasally infused with saline (control (C), 25 ml), echium oil low (EL, 25 ml), echium oil high (EH, 50 ml), linseed oil low (LL, 25 ml) or linseed oil high (LH, 50 ml) for 4 weeks. The basal ration used was identical across all treatments. EPA (20 : 5n-3) in meat increased from 6·5 mg in the C lambs to 16·8, 17·7, 13·5 and 11·7 (sem 0·86) mg/100 g muscle in the EL, EH, LL and LH lambs, respectively. For muscle DPA (docosapentaenoic acid; 22 : 5n-3), the corresponding values were 14·3, 22·2, 18·6 18·2 and 19·4 (sem 0·57) mg/100 g muscle. The DHA (22 : 6n-3) content of meat was 5·8 mg/100 g in the C lambs and ranged from 4·53 to 5·46 (sem 0·27) mg/100 g muscle in the oil-infused groups. Total n-3 PUFA content of meat (including ALA and SDA) increased from 39 mg to 119, 129, 121 and 150 (sem 12·3) mg/100 g muscle. We conclude that both oil types were effective in enhancing the EPA and DPA, but not DHA, content of meat. Furthermore, we conclude that, when balanced for precursor n-3 fatty acid supply, differences between linseed oil and echium oil in enriching meat with LC n-3 PUFA were of little, if any, nutritional significance.


2017 ◽  
Vol 1 (8) ◽  
pp. 1541-1549 ◽  
Author(s):  
Yizhu Lei ◽  
Yali Wan ◽  
Guangxing Li ◽  
Xiao-Yu Zhou ◽  
Yanlong Gu ◽  
...  

An amphiphilic porous organic polymer supported palladium catalyst was successfully prepared, showing excellent catalytic performance for aminocarbonylation reactions in water.


2021 ◽  
Author(s):  
Yali Wei ◽  
Yan Meng ◽  
Na Li ◽  
Qian Wang ◽  
Liyong Chen

The purpose of the systematic review and meta-analysis was to determine if low-ratio n-6/n-3 long-chain polyunsaturated fatty acid (PUFA) supplementation affects serum inflammation markers based on current studies.


1997 ◽  
Vol 78 (02) ◽  
pp. 808-812 ◽  
Author(s):  
María-Luisa Pita ◽  
José-María Rubio ◽  
María-Luisa Murillo ◽  
Olimpia Carreras ◽  
Mariá-José Delgado

SummaryThe effect of chronic ethanol ingestion on fatty acid composition of plasma, erythrocyte and platelet phospholipids and on plasma 6-keto-PGF1α was studied. Two groups of alcoholic subjects, one of them with chronic liver disease, were studied and compared to a control group of healthy subjects. Linoleic acid was not affected by alcoholism but its larger metabolites arachidonic acid (20:4n6) and docosatetraenoic acid (22: 4n6) tended to be lower in erythrocytes and platelets of both groups of alcoholic patients; the decrease was more marked in the presence of chronic liver disease. Docosahexaenoic acid (22:6n3) was markedly decreased in plasma, erythrocytes and platelets obtained from alcoholic patients with chronic liver disease. Plasma levels of 6-keto-PGF1α, a metabolite of prostacyclin (PGI2), remained unchanged. We conclude that chronic ethanol ingestion induces important changes in long-chain polyunsaturated fatty acids, mainly in platelets, and that these changes are exacerbated when patients suffer from chronic liver disease.


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