A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

2019 ◽  
Vol 48 (48) ◽  
pp. 17780-17791
Author(s):  
Agnieszka Mielcarek ◽  
Alina Bieńko ◽  
Paulina Saramak ◽  
Julia Jezierska ◽  
Anna Dołęga
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Catalytic Activity ◽  
Open Access ◽  
Heterometallic Complex ◽  
Binding Cavity

Cu/Zn metallocycle efficiently catalyzes oxidation of phenylethanol. The catalytic activity is ascribed to the open access to Cu(ii) ions at the walls of the cavity of the complex and spatial restraints imposed by its rigid molecular structure.

Molecular structure, magnetic properties and catalytic activity in selective ethylene dimerization of nickel (II) complexes with bis(3,5-dimethylpyrazol-1-yl)methane

2020 ◽  
Vol 1206 ◽  
pp. 127692 ◽  
Author(s):  
Sergey V. Zubkevich ◽  
Vladislav A. Tuskaev ◽  
Svetlana Ch Gagieva ◽  
Alexander A. Pavlov ◽  
Viktor N. Khrustalev ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Catalytic Activity ◽  
Ethylene Dimerization

Designing heterostructurated core@satellites Prussian Blue Analogue@Au-Ag nanoparticles: effect on the magnetic properties and catalytic activity

2021 ◽  
Author(s):  
Ekaterina Mamontova ◽  
María Rodríguez-Castillo ◽  
Erwan Oliviero ◽  
Yannick Guari ◽  
Joulia Larionova ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Catalytic Activity ◽  
Prussian Blue ◽  
Molecular Complex ◽  
Ag Nanoparticles ◽  
Prussian Blue Analogue

We report in this article new magneto-plasmonic core@satellites Prussian Blue Analogue (PBA)@Au-Ag nanoheterostructures obtained by using a post-synthetic impregnation of a bimetallic [AuI2AgI2(C6F5)4(OEt2)2]n molecular complex with the ferromagnetic K+/Ni2+/[Cr(CN)6]3− PBA...

Molecular Structure and Magnetic Properties of Pentapyridyl-based Iron(II) and Cobalt(II) Complexes

2012 ◽  
Vol 41 (6) ◽  
pp. 620-621 ◽  
Author(s):  
Young Hoon Lee ◽  
Kazuya Kato ◽  
Emi Kubota ◽  
Satoshi Kawata ◽  
Shinya Hayami
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties
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