A new route to achiral and chiral 1,2-bis(phosphino)ethanes, 1-arsino-2-phosphinoethanes, and 1,3-bis(phosphino)propanes and the molecular structure and catalytic activity of some rhodium(i) complexes derived thereof Dedicated to Professor Wolfdieter A. Schenk, a respected colleague and creative scientist, on the occasion of his 60th birthday.

2004 ◽  
pp. 1873 ◽  
Author(s):  
Guido Fries ◽  
Justin Wolf ◽  
Kerstin Ilg ◽  
Bernhard Walfort ◽  
Dietmar Stalke ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Catalytic Activity ◽  
60Th Birthday ◽  
Creative Scientist

Molecular Structure–Catalytic Activity Relationship in the Ring-Opening Polymerization of (Macro)lactones

2016 ◽  
Vol 49 (3) ◽  
pp. 796-806 ◽  
Author(s):  
Mark P. F. Pepels ◽  
Inge Hermsen ◽  
Geert J. Noordzij ◽  
Rob Duchateau
Keyword(s):  
Molecular Structure ◽  
Catalytic Activity ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Activity Relationship

Magnesium(II) Complexes of the dpp-BIAN Radical-Anion: Synthesis, Molecular Structure, and Catalytic Activity in Lactide Polymerization

2009 ◽  
Vol 2009 (33) ◽  
pp. 4995-5003 ◽  
Author(s):  
Igor L. Fedushkin ◽  
Alexander G. Morozov ◽  
Valentina A. Chudakova ◽  
Georgy K. Fukin ◽  
Vladimir K. Cherkasov
Keyword(s):  
Molecular Structure ◽  
Catalytic Activity ◽  
Radical Anion ◽  
Lactide Polymerization

A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

2019 ◽  
Vol 48 (48) ◽  
pp. 17780-17791
Author(s):  
Agnieszka Mielcarek ◽  
Alina Bieńko ◽  
Paulina Saramak ◽  
Julia Jezierska ◽  
Anna Dołęga
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Catalytic Activity ◽  
Open Access ◽  
Heterometallic Complex ◽  
Binding Cavity

Cu/Zn metallocycle efficiently catalyzes oxidation of phenylethanol. The catalytic activity is ascribed to the open access to Cu(ii) ions at the walls of the cavity of the complex and spatial restraints imposed by its rigid molecular structure.

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