scholarly journals Enhanced yield-mobility products in hybrid halide Ruddlesden–Popper compounds with aromatic ammonium spacers

2019 ◽  
Vol 48 (37) ◽  
pp. 14019-14026 ◽  
Author(s):  
Naveen R. Venkatesan ◽  
Ali Mahdi ◽  
Brian Barraza ◽  
Guang Wu ◽  
Michael L. Chabinyc ◽  
...  

Two hybrid halide Ruddlesden–Popper compounds using the cation 2-(4-biphenyl)ethylammonium show higher yield-carrier mobility products by time-resolved microwave conductivity than compounds with n-butylammonium cations.

2020 ◽  
Vol 8 (31) ◽  
pp. 10761-10766
Author(s):  
Shirsopratim Chattopadhyay ◽  
Robert S. Kokenyesi ◽  
Min Ji Hong ◽  
C Lowell Watts ◽  
John G. Labram

A strategy is demonstrated to evaluate the carrier mobility in-plane and out-of-plane using contactless time resolved microwave conductivity.


2015 ◽  
Vol 6 (32) ◽  
pp. 5860-5868 ◽  
Author(s):  
Takahiro Fukumatsu ◽  
Akinori Saeki ◽  
Shu Seki

Non-contact measurements with time-resolved microwave conductivity and absorption spectroscopy offer direct access to the charge carrier mobility in conjugated backbones.


2017 ◽  
Vol 5 (24) ◽  
pp. 5930-5938 ◽  
Author(s):  
John G. Labram ◽  
Naveen R. Venkatesan ◽  
Christopher J. Takacs ◽  
Hayden A. Evans ◽  
Erin E. Perry ◽  
...  

Time-resolved microwave conductivity reveals good carrier mobility and long carrier lifetimes in the layered organic metal halide compound (CH3NH3)2Pb(SCN)2I2.


2003 ◽  
Vol 07 (05) ◽  
pp. 342-350 ◽  
Author(s):  
John M. Warman ◽  
Jessica E. Kroeze ◽  
Pieter G. Schouten ◽  
Anick M. van de Craats

The pulse-radiolysis time-resolved microwave conductivity technique, “PR-TRMC”, has been used to determine the charge carrier mobility within columnar stacks of mesomorphic discotic porphyrins and phthalocyanines. The influences of temperature, morphology and variations in the primary molecular structure are demonstrated and discussed. Both the mesomorphic and conductive properties are shown to be dramatically influenced by subtle changes in the peripheral alkyl chain structure or the core-to-chain coupling element. Mobilities close to 1 cm2.V−1.s−1 are found in crystalline solids, and well in excess of 0.1 cm2.V−1.s−1 in columnar, liquid crystalline phases. These values which are even larger than those determined by PR-TRMC for conjugated polymers and similar to values found for electrons and holes in organic single crystals.


1993 ◽  
Vol 65 (8) ◽  
pp. 1723-1728 ◽  
Author(s):  
J. M. Warman ◽  
S. A. Jonker ◽  
W. Schuddeboom ◽  
M. P. de Haas ◽  
M. N. Paddon-Row ◽  
...  

2006 ◽  
Vol 910 ◽  
Author(s):  
Steve Reynolds

AbstractThe use of transient photoconductivity techniques in the investigation of carrier transport in microcrystalline silicon is described. Results are presented which highlight variations in transport parameters such as carrier mobility and density of states with structure composition. Hole mobility is significantly enhanced by crystalline content in the film of 10% or less. The density of states inferred from transport measurements parallel to and at right angles to the direction of film growth differ somewhat, suggesting that transport may be anisotropic.


1994 ◽  
Vol 90 (21) ◽  
pp. 3315-3322 ◽  
Author(s):  
Scot T. Martin ◽  
Hartmut Herrmann ◽  
Wonyong Choi ◽  
Michael R. Hoffmann

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