Improving photoelectrochemical response of ZnO nanowire arrays by coating with p-type ZnO-resembling metal–organic framework

2019 ◽  
Vol 48 (25) ◽  
pp. 9310-9316 ◽  
Author(s):  
Qianqian Gao ◽  
Huihui Kang ◽  
Yun Cai ◽  
Daxiang Xue ◽  
Fengjiao Yu ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Metal Organic Framework ◽  
Nanowire Arrays ◽  
Zno Nanowire ◽  
Photoelectrochemical Performance ◽  
Type Conductivity ◽  
Photoelectrochemical Response ◽  
Metal Organic ◽  
Zinc Oxide Nanowire ◽  
P Type

Superior photoelectrochemical performance of zinc oxide nanowire arrays is achieved by compactly coating MOF zinc glycolate with p-type conductivity.

scholarly journals Enhancing photovoltages at p-type semiconductors through a redox-active metal-organic framework surface coating

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Anna M. Beiler ◽  
Brian D. McCarthy ◽  
Ben A. Johnson ◽  
Sascha Ott
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensions ◽  
Photoelectrochemical Performance ◽  
Naphthalene Diimide ◽  
Thermodynamic Potentials ◽  
Redox Active ◽  
Active Metal ◽  
Metal Organic ◽  
Conductive Substrates ◽  
P Type

AbstractSurface modification of semiconductors can improve photoelectrochemical performance by promoting efficient interfacial charge transfer. We show that metal-organic frameworks (MOFs) are viable surface coatings for enhancing cathodic photovoltages. Under 1-sun illumination, no photovoltage is observed for p-type Si(111) functionalized with a naphthalene diimide derivative until the monolayer is expanded in three dimensions in a MOF. The surface-grown MOF thin film at Si promotes reduction of the molecular linkers at formal potentials >300 mV positive of their thermodynamic potentials. The photocurrent is governed by charge diffusion through the film, and the MOF film is sufficiently conductive to power reductive transformations. When grown on GaP(100), the reductions of the MOF linkers are shifted anodically by >700 mV compared to those of the same MOF on conductive substrates. This photovoltage, among the highest reported for GaP in photoelectrochemical applications, illustrates the power of MOF films to enhance photocathodic operation.

Rational Synthesis of p-Type Zinc Oxide Nanowire Arrays Using Simple Chemical Vapor Deposition

Nano Letters ◽  
2007 ◽  
Vol 7 (2) ◽  
pp. 323-328 ◽  
Author(s):  
Bin Xiang ◽  
Pengwei Wang ◽  
Xingzheng Zhang ◽  
Shadi. A. Dayeh ◽  
David P. R. Aplin ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Chemical Vapor Deposition ◽  
Vapor Deposition ◽  
Chemical Vapor ◽  
Nanowire Arrays ◽  
Simple Chemical ◽  
Zinc Oxide Nanowire ◽  
P Type

p-type Sodium-doped Zinc Oxide Nanowire Arrays Grown by High-pressure Pulsed Laser Deposition

2014 ◽  
Vol 29 (2) ◽  
pp. 155-161
Author(s):  
Zhi-Wen QIU ◽  
Xiao-Peng YANG ◽  
Jun HAN ◽  
Xue-Song ZENG ◽  
Xin-Hua LI ◽  
...  
Keyword(s):  
High Pressure ◽  
Zinc Oxide ◽  
Pulsed Laser Deposition ◽  
Pulsed Laser ◽  
Nanowire Arrays ◽  
Laser Deposition ◽  
Zinc Oxide Nanowire ◽  
P Type

Selective micro laser annealing for fluorescence tuning of carbon-incorporated zinc oxide nanowire arrays

2019 ◽  
Vol 7 (21) ◽  
pp. 6279-6288 ◽  
Author(s):  
Sing Teng Chua ◽  
Kim Yong Lim ◽  
Zheng Zhang ◽  
Chorng Haur Sow
Keyword(s):  
Zinc Oxide ◽  
Laser Beam ◽  
Laser Annealing ◽  
Nanowire Arrays ◽  
Zno Nanowire ◽  
Zinc Oxide Nanowire

Carbon-incorporated zinc oxide (C-ZnO) nanowire (NW) arrays display controllable optical changes after being selectively annealed by a focused violet laser beam.

Efficient intracellular delivery of biomacromolecules employing clusters of zinc oxide nanowires

Nanoscale ◽  
2017 ◽  
Vol 9 (40) ◽  
pp. 15371-15378 ◽  
Author(s):  
Prashant Sharma ◽  
Hyun Ah Cho ◽  
Jae-Won Lee ◽  
Woo Seung Ham ◽  
Bum Chul Park ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Intracellular Delivery ◽  
Nanowire Arrays ◽  
Zno Nanowire ◽  
Zinc Oxide Nanowires ◽  
Oxide Nanowires ◽  
Zno Nanowire Arrays

Fan-shaped ZnO nanowire arrays can mediate intracellular delivery of non-covalently associated peptides and DNA.

Nanorods of a novel highly conductive 2D metal–organic framework based on perthiolated coronene for thermoelectric conversion

2020 ◽  
Vol 8 (24) ◽  
pp. 8199-8205
Author(s):  
Zhijun Chen ◽  
Yutao Cui ◽  
Yigang Jin ◽  
Liyao Liu ◽  
Jie Yan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Thermoelectric Performance ◽  
Thermoelectric Conversion ◽  
Metal Organic ◽  
P Type ◽  
Organic Framework

Ni-PTC, a perthiolated coronene-based conducting MOF displays p-type thermoelectric performance with a ZT value of 0.003 at 300 K.

A p-type Ti(iv)-based metal–organic framework with visible-light photo-response

2014 ◽  
Vol 50 (29) ◽  
pp. 3786-3788 ◽  
Author(s):  
Junkuo Gao ◽  
Jianwei Miao ◽  
Pei-Zhou Li ◽  
Wen Yuan Teng ◽  
Ling Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Type Semiconductor ◽  
Visible Light Driven ◽  
Metal Organic ◽  
Photo Response ◽  
P Type ◽  
Photoelectrochemical Studies ◽  
Organic Framework

Photoelectrochemical studies on a new Ti(iv)-based porous metal–organic framework (NTU-9, bandgap 1.72 eV) indicated that NTU-9 is a p-type semiconductor with visible-light-driven photoactivity.

Dimensional Tailoring of Hydrothermally Grown Zinc Oxide Nanowire Arrays

Nano Letters ◽  
2015 ◽  
Vol 16 (1) ◽  
pp. 753-759 ◽  
Author(s):  
Jayce J. Cheng ◽  
Samuel M. Nicaise ◽  
Karl K. Berggren ◽  
Silvija Gradečak
Keyword(s):  
Zinc Oxide ◽  
Nanowire Arrays ◽  
Zinc Oxide Nanowire
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