Core-mediated synthesis, growth mechanism and near-infrared luminescence enhancement of α-NaGdF4@β-NaLuF4:Nd3+ core–shell nanocrystals

CrystEngComm ◽  
2020 ◽  
Vol 22 (8) ◽  
pp. 1359-1367 ◽  
Author(s):  
Qinqin Shao ◽  
Chao Yang ◽  
Xiaoxu Chen ◽  
Hong Zhang ◽  
Guoying Feng ◽  
...  

High-performance α-NaGdF4@β-NaLuF4:Nd3+ nanocrystals have been constructed based on a core-mediated method. Their near-infrared emission intensity was eventually enhanced by more than 2 times.

CrystEngComm ◽  
2019 ◽  
Vol 21 (4) ◽  
pp. 741-748 ◽  
Author(s):  
Qinqin Shao ◽  
Hong Zhang ◽  
Jiangyun Dai ◽  
Chao Yang ◽  
Xiaoxu Chen ◽  
...  

The near-infrared emission intensity of NaYF4:3% Nd3+ doped with 20 mol% Ca2+ is 3 times that of the Ca2+-free samples.


2009 ◽  
Vol 24 (2) ◽  
pp. 516-519 ◽  
Author(s):  
Jian Ruan ◽  
Botao Wu ◽  
Danping Chen ◽  
Yanbo Qiao ◽  
Jianrong Qiu

In this article, we report on enhanced broadband near-infrared emission in Yb–Bi codoped phosphate glasses. The emission intensity of Yb–Bi codoped glass was ˜32 times larger than that of Bi-doped glass when excited with 980-nm laser diode. The highest 1/e fluorescent lifetime of Yb–Bi codoped glass reached 1650 μs. The dependence of emission intensity and fluorescent lifetime on Yb2O3 concentration was investigated. The enhancement of the near-infrared emission is due to energy transfer from Yb3+ (2F5/2–2F7/2) transition to Bi ions, and the highest energy transfer efficiency reached 50%. Yb–Bi codoped phosphate glass should be a promising candidate for broadband optical amplification.


2017 ◽  
Vol 4 (6) ◽  
pp. 1110-1114 ◽  
Author(s):  
Wenbo Wu ◽  
Duo Mao ◽  
Shidang Xu ◽  
Shenglu Ji ◽  
Fang Hu ◽  
...  

A series of D–A′–π–A type photosensitizers were designed and synthesized to show strong aggregation-induced far red and near infrared emission and very effective 1O2 generation simultaneously, and have been successfully used for image-guided photodynamic anticancer therapy.


Nanoscale ◽  
2019 ◽  
Vol 11 (24) ◽  
pp. 11642-11648 ◽  
Author(s):  
Er Pan ◽  
Gongxun Bai ◽  
Jun Zhou ◽  
Lei Lei ◽  
Shiqing Xu

Exceptional enhancement in both upconversion and downconversion near-infrared emission has been realized in the developed ferroelectric photonic nanocomposite.


2013 ◽  
Author(s):  
V. A. G. Rivera ◽  
F. A. Ferri ◽  
J. L. Clabel H. ◽  
M. K. Kawamura ◽  
M. A. Pereira-da-Silva ◽  
...  

2011 ◽  
Vol 399-401 ◽  
pp. 982-986
Author(s):  
Jin Liu ◽  
Dong Mei Shi ◽  
Ying Gang Zhao ◽  
Xiao Feng Wang

The visible and near infrared emission spectra of Er3+/Tm3+-doped Ga2O3-Bi2O3-PbO-GeO2(GBPG) glasses excited at 808 nm are experimentally investigated. The results reveal that 1.53 µm emission were enhanced with an increase of Er3+concentration. Furthermore, the incorporation of Er3+into Tm3+-doped systems has also resulted in intense 522, 545 and 693nm upconversion emission intensity and an weak 660 nm red emission. The possible mechanism and related discussions on this phenomenon have been presented. The results show that Er3+/Tm3+-codoped GBPG glass may be a promising materials for developing laser and fiber optical devices.


Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12573-12581 ◽  
Author(s):  
Qingyun Liu ◽  
Xianmei Zou ◽  
Yibing Shi ◽  
Bin Shen ◽  
Cong Cao ◽  
...  

Through combining Cy7 and NaYbF4@NaYF4:60%Nd together to form a dye-sensitized system, the near-infrared emission intensity of Yb was significantly enhanced.


2007 ◽  
Vol 336-338 ◽  
pp. 655-657 ◽  
Author(s):  
Ying He ◽  
K. Ma ◽  
L. Bi ◽  
Jia You Feng ◽  
Q.L. Wu

In this paper, we have investigated the near-infrared luminescence emitting from NiSi2 passivated silicon nanocrystals (NCs) embedded in SiOx films. For comparison, we also prepared the regular specimen without NiSi2 passivation. In the both systems, the intensity of photoluminescence emission from NC-Si increased with the increase of annealing temperature, which was explained by the crystallization of amorphous silicon in SiOx films. The maximum intensity of near-infrared emission from NiSi2-passivated NC-Si was stronger by factor 5 than that of regular specimen without NiSi2 passivation. The model of NiSi2 passivation was employed to explain this phenomenon.


2018 ◽  
Vol 54 (67) ◽  
pp. 9364-9367 ◽  
Author(s):  
Hannah R. Shanks ◽  
Mingning Zhu ◽  
Amir H. Milani ◽  
James Turton ◽  
Sarah Haigh ◽  
...  

Core–shell–shell particles with incorporated near-infrared polymer dots give high brightness, increased colloidal stability, and non-radiative resonance energy transfer.


2007 ◽  
Vol 336-338 ◽  
pp. 647-650
Author(s):  
Zhi Yong Yang ◽  
Lan Luo ◽  
Wei Chen

Near-infrared emission properties of Dy3+-Tm3+ co-doped Ge-Ga-Sb-Se glasses were investigated. Possible energy transfer routes and the regime of donor decay were discussed. Tm3+ is found to be an efficient sensitizer on the Dy3+:1.34μm luminescence. Probable energy transfer schemes include Tm3+:3H4 → Dy3+: 6F5/2 and Tm3+:3H5 → Dy3+:6F11/2· 6H9/2. The donor (Tm3+) excitation is transferred to an acceptor (Dy3+) by direct interaction or migrates among donors by diffusion-limited regime until it comes into the vicinity of an energy acceptor where direct interaction and transfer occur.


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