Two new MOFs based on 5-((4-carboxypyridin-2-yl)oxy) isophthalic acid displaying unique selective CO2 gas adsorption and magnetic properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (46) ◽  
pp. 7078-7084 ◽  
Author(s):  
Jian-Guo Cheng ◽  
Jiao Liu ◽  
Wen-Quan Tong ◽  
Dan Wu ◽  
Fan Yang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Gas Adsorption ◽  
Selective Adsorption ◽  
Isophthalic Acid ◽  
Carboxylate Ligand ◽  
Co2 Gas

The reaction of Cu(ii)/Co(ii) with a N-heterocyclic carboxylate ligand produced two new MOFs with different topologies. The Cu-MOF showed selective adsorption for CO2 over CH4, and the antiferromagnetic properties existed in the two MOFs.

Five transition metal coordination polymers driven by a semirigid trifunctional nicotinic acid ligand: selective adsorption and magnetic properties

CrystEngComm ◽  
2018 ◽  
Vol 20 (38) ◽  
pp. 5726-5734 ◽  
Author(s):  
Nannan Bai ◽  
Ruicheng Gao ◽  
Haihua Wang ◽  
Yunlong Wu ◽  
Lei Hou ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Transition Metal ◽  
Nicotinic Acid ◽  
Functional Groups ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Selective Adsorption ◽  
Acid Ligand ◽  
Metal Coordination Polymers ◽  
Organic Linker

Five coordination polymers have been synthesized by a new organic linker containing three distinct types of functional groups together with the mixed 2,2′-bipy or 4,4′-bipy co-ligand, revealing various framework structures and selective gas adsorption and magnetic properties.

Probing the performance of imide linked micro-porous polymers for enhanced CO2 gas adsorption applications

2021 ◽  
Author(s):  
Narendran Rajendran ◽  
Ali A. Husain ◽  
Saad Makhseed
Keyword(s):  
Surface Area ◽  
Gas Adsorption ◽  
Oxidative Polymerization ◽  
Porous Polymers ◽  
Bet Surface Area ◽  
Co2 Gas

Three new carbazole containing cross-linked polymers namely AH-Poly, TM-PDA-Poly and TMB-PDA-Poly were designed and successfully synthesized by an oxidative polymerization protocol. The prepared AH-Poly showed a specific BET surface area...

Structural diversity, gas adsorption and magnetic properties of three coordination polymers based on a rigid multicarboxylate ligand

CrystEngComm ◽  
2020 ◽  
Vol 22 (42) ◽  
pp. 7046-7053
Author(s):  
Lingling Gao ◽  
Yongjun Bian ◽  
Yuan Tian ◽  
Yongqiang Chen ◽  
Tuoping Hu
Keyword(s):  
Magnetic Properties ◽  
Benzoic Acid ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Structural Diversity ◽  
Acid Ligand

A pictogram: the gas adsorption and magnetic properties of three Co(ii) coordination polymers constructed from 3,5-di(2′,5′-dicarboxylphenyl)benzoic acid ligand have been explored.

Fabrication of a functional microgel-based hybrid nanofluid and its application in CO2 gas adsorption

2019 ◽  
Vol 136 ◽  
pp. 131-137 ◽  
Author(s):  
Dongdong Yao ◽  
Ting Li ◽  
Yaping Zheng ◽  
Zhilin Zhang
Keyword(s):  
Gas Adsorption ◽  
Hybrid Nanofluid ◽  
Co2 Gas

Functionalized polyoxometalate-based metal–organic cuboctahedra for selective adsorption toward cationic dyes in aqueous solution

2018 ◽  
Vol 47 (37) ◽  
pp. 12979-12983 ◽  
Author(s):  
Ya-Ru Gong ◽  
Wei-Chao Chen ◽  
Liang Zhao ◽  
Kui-Zhan Shao ◽  
Xin-Long Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Selective Adsorption ◽  
Cationic Dyes ◽  
Carboxylate Ligand ◽  
Metal Organic

Two new VMOPs with cuboctahedral geometries were synthesized based on [V6O6(OCH3)9X] (X = VO4 or SO4) and the rigid tridentate carboxylate ligand H3TATB, which present selective adsorption toward cationic dyes in aqueous solution.

Modulation of Gas Adsorption and Magnetic Properties of Monolayer-MoS2 by Antisite Defect and Strain

2016 ◽  
Vol 120 (26) ◽  
pp. 14113-14121 ◽  
Author(s):  
MPK Sahoo ◽  
Jie Wang ◽  
Yajun Zhang ◽  
Takahiro Shimada ◽  
Takayuki Kitamura
Keyword(s):  
Magnetic Properties ◽  
Gas Adsorption ◽  
Antisite Defect ◽  
Monolayer Mos2

CO2 gas-adsorption calorimetry applied to the study of chemically activated carbons

2018 ◽  
Vol 136 ◽  
pp. 753-760 ◽  
Author(s):  
Débora Aline Soares Maia ◽  
José Carlos Alexandre de Oliveira ◽  
Marcelo Sandro Nazzarro ◽  
Karim Manuel Sapag ◽  
Raul Horácio López ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Activated Carbons ◽  
Adsorption Calorimetry ◽  
Co2 Gas

Tuning the electronic and magnetic properties of Mn-doped graphene by gas adsorption and effect of external electric field: First-principles study

2019 ◽  
Vol 33 (16) ◽  
pp. 1950166
Author(s):  
Huan Ma ◽  
Ling Ma ◽  
Liang-Cai Ma
Keyword(s):  
Magnetic Properties ◽  
Electric Field ◽  
External Electric Field ◽  
Spin Polarization ◽  
First Principles ◽  
Density Functional ◽  
Gas Adsorption ◽  
Electronic And Magnetic Properties ◽  
Doped Graphene ◽  
Mn Doped

The effect of gas molecule (H2CO, NO, NO2, O2 and SO2) adsorption on the electronic and magnetic properties of Mn-doped graphene (MnG) is investigated by first-principles calculations in the framework of density functional theory (DFT). Our study reveals that after H2CO, NO, NO2 and SO2 adsorption, MnG transforms from half-metal to semiconductor, and this transformation indicates that MnG’s conductivity is changed significantly. Meanwhile, O2 adsorption has no influence on MnG’s original electronic property. Therefore, the substrate of MnG is highly sensitive to H2CO, NO, NO2 and SO2. The reconfiguration of electron distribution caused by gas adsorption dramatically alters the spin polarization distribution of the combined system, that is, NO2 and H2CO adsorption leads to local spin polarization, whereas O2, NO and SO2 adsorption result in complete spin polarization. In addition, the external electric field (E-field) is varied from −0.50 V/Å to +0.50 V/Å then applied to the adsorption system. A strong interaction is observed between gas and MnG with a positive E-field as reflected in the enhancement of adsorption energy. The interaction is obviously weakened by introducing the E-field in the negative direction. Hence, the adsorption strength and sensitivity of gas on MnG can be effectively tuned by the E-field. The results can serve as useful references for the design of graphene-based gas sensor.

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