Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

2019 ◽  
Vol 55 (98) ◽  
pp. 14725-14728 ◽  
Author(s):  
Natalie Dehnhardt ◽  
Jan-Niclas Luy ◽  
Marvin Szabo ◽  
Mirco Wende ◽  
Ralf Tonner ◽  
...  

A new layered organic–inorganic iodido bismuthate is prepared from an in situ condensation reaction of acetone and dimethylammonium iodide.

2022 ◽  
Author(s):  
Yoshihiro Kikkawa ◽  
Mayumi Nagasaki ◽  
Seiji Tsuzuki ◽  
Thierry Fouquet ◽  
Sayaka Nakamura ◽  
...  

The two-dimensional self-assembly of rufigallol derivatives and their metal coordination were studied by scanning tunnelling microscopy. Ex-situ Cu(II)-coordinated rufigallol derivatives exhibited columnar structures with some defects, whereas regular and linear...


2019 ◽  
Vol 491 (4) ◽  
pp. 5595-5620 ◽  
Author(s):  
Sanson T S Poon ◽  
Richard P Nelson ◽  
Seth A Jacobson ◽  
Alessandro Morbidelli

ABSTRACT The NASA’s Kepler mission discovered ∼700 planets in multiplanet systems containing three or more transiting bodies, many of which are super-Earths and mini-Neptunes in compact configurations. Using N-body simulations, we examine the in situ, final stage assembly of multiplanet systems via the collisional accretion of protoplanets. Our initial conditions are constructed using a subset of the Kepler five-planet systems as templates. Two different prescriptions for treating planetary collisions are adopted. The simulations address numerous questions: Do the results depend on the accretion prescription?; do the resulting systems resemble the Kepler systems, and do they reproduce the observed distribution of planetary multiplicities when synthetically observed?; do collisions lead to significant modification of protoplanet compositions, or to stripping of gaseous envelopes?; do the eccentricity distributions agree with those inferred for the Kepler planets? We find that the accretion prescription is unimportant in determining the outcomes. The final planetary systems look broadly similar to the Kepler templates adopted, but the observed distributions of planetary multiplicities or eccentricities are not reproduced, because scattering does not excite the systems sufficiently. In addition, we find that ∼1 per cent of our final systems contain a co-orbital planet pair in horseshoe or tadpole orbits. Post-processing the collision outcomes suggests that they would not significantly change the ice fractions of initially ice-rich protoplanets, but significant stripping of gaseous envelopes appears likely. Hence, it may be difficult to reconcile the observation that many low-mass Kepler planets have H/He envelopes with an in situ formation scenario that involves giant impacts after dispersal of the gas disc.


2021 ◽  
Author(s):  
Yijuan Wang ◽  
Jianzhi Wang ◽  
Jie Liu ◽  
Zhuangwei Xiao ◽  
Yanan Xue ◽  
...  

A rigid segment-containing polysulfide was used as a sulfur source and in situ intercalator to induce the formation of few-layer and 1T-rich MoS2.


AIP Advances ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 065015
Author(s):  
Fu Yi ◽  
Xupeng Qi ◽  
Xuexin Zheng ◽  
Huize Yu ◽  
Wenming Bai ◽  
...  

Micromachines ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 929
Author(s):  
Xudong Yang ◽  
Zexiao Li ◽  
Linlin Zhu ◽  
Yuchu Dong ◽  
Lei Liu ◽  
...  

Taper-cutting experiments are important means of exploring the nano-cutting mechanisms of hard and brittle materials. Under current cutting conditions, the brittle-ductile transition depth (BDTD) of a material can be obtained through a taper-cutting experiment. However, taper-cutting experiments mostly rely on ultra-precision machining tools, which have a low efficiency and high cost, and it is thus difficult to realize in situ measurements. For taper-cut surfaces, three-dimensional microscopy and two-dimensional image calculation methods are generally used to obtain the BDTDs of materials, which have a great degree of subjectivity, leading to low accuracy. In this paper, an integrated system-processing platform is designed and established in order to realize the processing, measurement, and evaluation of taper-cutting experiments on hard and brittle materials. A spectral confocal sensor is introduced to assist in the assembly and adjustment of the workpiece. This system can directly perform taper-cutting experiments rather than using ultra-precision machining tools, and a small white light interference sensor is integrated for in situ measurement of the three-dimensional topography of the cutting surface. A method for the calculation of BDTD is proposed in order to accurately obtain the BDTDs of materials based on three-dimensional data that are supplemented by two-dimensional images. The results show that the cutting effects of the integrated platform on taper cutting have a strong agreement with the effects of ultra-precision machining tools, thus proving the stability and reliability of the integrated platform. The two-dimensional image measurement results show that the proposed measurement method is accurate and feasible. Finally, microstructure arrays were fabricated on the integrated platform as a typical case of a high-precision application.


2021 ◽  
Vol 202 ◽  
pp. 109535
Author(s):  
Yadong Wu ◽  
Xiuyan Cheng ◽  
Shaoyun Chen ◽  
Bo Qu ◽  
Rui Wang ◽  
...  

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