Polyphenyl polysulfide: a new polymer cathode material for Li–S batteries

2019 ◽  
Vol 55 (33) ◽  
pp. 4857-4860 ◽  
Author(s):  
Pengfei Sang ◽  
Yubing Si ◽  
Yongzhu Fu
Keyword(s):  
Cathode Material ◽  
Carbon Disulfide ◽  
Room Temperature ◽  
Molar Ratios ◽  
New Class ◽  
Condensation Reactions

We report a new class of polyphenyl polysulfides synthesized by condensation reactions between 4,4′-thiobisbenzenethiol (TBBT) and sulfur with four different molar ratios in a toluene/carbon disulfide mixture at room temperature.

Green synthesis of mixed metallic nanoparticles using room temperature self-assembly

2017 ◽  
Vol 13 (2) ◽  
pp. 4671-4677 ◽  
Author(s):  
A. M. Abdelghany ◽  
A.H. Oraby ◽  
Awatif A Hindi ◽  
Doaa M El-Nagar ◽  
Fathia S Alhakami
Keyword(s):  
Self Assembly ◽  
Metallic Nanoparticles ◽  
Room Temperature ◽  
Bimetallic Nanoparticles ◽  
Reduction Process ◽  
Nano Particles ◽  
Nano Structure ◽  
Small Shift ◽  
Molar Ratios ◽  
Vis Spectroscopy

Bimetallic nanoparticles of silver (Ag) and gold (Au) were synthesized at room temperature using Curcumin. Reduction process of silver and gold ions with different molar ratios leads to production of different nanostructures including alloys and core-shells. Produced nanoparticles were characterized simultaneously with FTIR, UV/vis. spectroscopy, transmission electron microscopy (TEM), and Energy-dispersive X-ray (EDAX). UV/vis. optical absorption spectra of as synthesized nanoparticles reveals presence of surface palsmon resonance (SPR) of both silver at (425 nm) and gold at (540 nm) with small shift and broadness of gold band after mixing with resucing and capping agent in natural extract which suggest presence of bimetallic nano structure (Au/Ag). FTIR and EDAX data approve the presence of bimetallic nano structure combined with curcumin extract. TEM micrographs shows that silver and gold can be synthesized separately in the form of nano particles using curcumin extract. Synthesis of gold nano particles in presence of silver effectively enhance and control formation of bi-metallic structure.

Layered High-Entropy Oxide Structures for Reversible Energy Storage

2020 ◽  
Author(s):  
Junbo Wang ◽  
Yanyan Cui ◽  
Qingsong Wang ◽  
Kai Wang ◽  
Xiaohui Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Cathode Material ◽  
Spray Pyrolysis ◽  
Lattice Structure ◽  
Oxide Materials ◽  
High Entropy ◽  
New Class ◽  
Nebulized Spray Pyrolysis

<p>Layered Li<i><sub>x</sub></i>MO<sub>2</sub> materials, a new class of high-entropy oxides, have been synthesized by nebulized spray pyrolysis. Specifically, the lattice structure of Li(Ni<sub>1/3</sub>Mn<sub>1/3</sub>Co<sub>1/3</sub>)O<sub>2</sub> (NCM111) cathode material has been replicated successfully while increasing the number of cations in equimolar proportions, thereby allowing transition to high-entropy oxide materials.</p>

scholarly journals Green Solvents as an Alternative to DMF in ZIF-90 Synthesis

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1573
Author(s):  
Aljaž Škrjanc ◽  
Ciara Byrne ◽  
Nataša Zabukovec Logar
Keyword(s):  
Room Temperature ◽  
Product Yield ◽  
Solvent Exchange ◽  
Green Solvents ◽  
Zeolitic Imidazolate Framework ◽  
Short Treatment ◽  
Molar Ratios ◽  
Primary Particles ◽  
High Product Yield

The use of green solvents as an alternative to dimethylformamide (DMF) in the synthesis of zeolitic imidazolate framework-90 (ZIF-90) was investigated. Two biobased aprotic dipolar solvents CyreneTM and γ-valerolactone (GVL) proved to successfully replace DMF in the synthesis at room temperature with a high product yield. While the CyreneTM—based product shows reduced porosity after activation, the use of GVL resulted in materials with preserved crystallinity and porosity after activation, without prior solvent exchange and a short treatment at 200 °C. The primary particles of 30 nm to 60 nm in all products further form agglomerates of different size and interparticle mesoporosity, depending on the type and molar ratios of solvents used.

scholarly journals Liquid-Liquid Extraction in Systems Containing Butanol and Ionic Liquids – A Review

2017 ◽  
Vol 38 (1) ◽  
pp. 97-110 ◽  
Author(s):  
Artur Kubiczek ◽  
Władysław Kamiński
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Liquid Extraction ◽  
Butanol Production ◽  
Model Liquid ◽  
New Class ◽  
Liquid Liquid Extraction ◽  
Liquid Systems ◽  
Nrtl Equation ◽  
Equilibrium Data

AbstractRoom-temperature ionic liquids (RTILs) are a moderately new class of liquid substances that are characterized by a great variety of possible anion-cation combinations giving each of them different properties. For this reason, they have been termed as designer solvents and, as such, they are particularly promising for liquid-liquid extraction, which has been quite intensely studied over the last decade. This paper concentrates on the recent liquid-liquid extraction studies involving ionic liquids, yet focusing strictly on the separation of n-butanol from model aqueous solutions. Such research is undertaken mainly with the intention of facilitating biological butanol production, which is usually carried out through the ABE fermentation process. So far, various sorts of RTILs have been tested for this purpose while mostly ternary liquid-liquid systems have been investigated. The industrial design of liquid-liquid extraction requires prior knowledge of the state of thermodynamic equilibrium and its relation to the process parameters. Such knowledge can be obtained by performing a series of extraction experiments and employing a certain mathematical model to approximate the equilibrium. There are at least a few models available but this paper concentrates primarily on the NRTL equation, which has proven to be one of the most accurate tools for correlating experimental equilibrium data. Thus, all the presented studies have been selected based on the accepted modeling method. The reader is also shown how the NRTL equation can be used to model liquid-liquid systems containing more than three components as it has been the authors’ recent area of expertise.

Room temperature long-term creep/relaxation behaviour of carbon cathode material

2008 ◽  
Vol 496 (1-2) ◽  
pp. 366-375 ◽  
Author(s):  
D. Picard ◽  
M. Fafard ◽  
G. Soucy ◽  
J.-F. Bilodeau
Keyword(s):  
Cathode Material ◽  
Room Temperature ◽  
Relaxation Behaviour ◽  
Carbon Cathode ◽  
Term Creep

scholarly journals Stereoselective synthesis of glycosides using (salen)Co catalysts as promoters

2015 ◽  
Vol 51 (43) ◽  
pp. 8939-8941 ◽  
Author(s):  
Sandra Medina ◽  
Alexander S. Henderson ◽  
John F. Bower ◽  
M. Carmen Galan
Keyword(s):  
Room Temperature ◽  
Stereoselective Synthesis ◽  
Co Catalysts ◽  
New Class ◽  
Stereoselective Glycosylation ◽  
Glycosyl Donors

The use of (salen)Co catalysts as a new class of bench-stable stereoselective glycosylation promoters of trichloroacetimidate glycosyl donors at room temperature is described.

scholarly journals A green approach to the synthesis of a nano catalyst and the role of basicity, calcination, catalytic activity and aging in the green synthesis of 2-aryl bezimidazoles, benzothiazoles and benzoxazoles

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42000-42012 ◽  
Author(s):  
Pramod K. Sahu
Keyword(s):  
Catalytic Activity ◽  
Green Synthesis ◽  
Room Temperature ◽  
Molar Ratios ◽  
Green Approach ◽  
Grinding Method ◽  
Nano Catalyst ◽  
Layered Catalyst

A green synthesis of hydrotalcite (a double layered catalyst) by a grinding method using Al/Mg molar ratios of 1.0–3.0 at room temperature is described.

Defect thiospinels: a new class of reversible cathode material

1989 ◽  
Vol 26 (3-4) ◽  
pp. 277-283 ◽  
Author(s):  
A.C.W.P. James ◽  
J.B. Goodenough
Keyword(s):  
Cathode Material ◽  
New Class

scholarly journals Low-temperature transport properties of n-type layered homologous compounds Bi8−xSbxSe7

2020 ◽  
Vol 8 (40) ◽  
pp. 14037-14048
Author(s):  
Pavan Kumar-Ventrapati ◽  
Shantanu Misra ◽  
Gaëlle Delaizir ◽  
Anne Dauscher ◽  
Bertrand Lenoir ◽  
...  
Keyword(s):  
Low Temperature ◽  
Transport Properties ◽  
Thermoelectric Materials ◽  
Room Temperature ◽  
Parent Compound ◽  
New Class ◽  
Highly Efficient ◽  
Homologous Compounds

The n-type chalcogenide Bi8Se7 is the parent compound of a new class of highly-efficient thermoelectric materials for near-room-temperature thermoelectric applications.

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