Molecular engineering of enamine-based small organic compounds as hole-transporting materials for perovskite solar cells

2019 ◽  
Vol 7 (9) ◽  
pp. 2717-2724 ◽  
Author(s):  
Maryte Daskeviciene ◽  
Sanghyun Paek ◽  
Artiom Magomedov ◽  
Kyoung Taek Cho ◽  
Michael Saliba ◽  
...  
Keyword(s):  
Solar Cells ◽  
Organic Compounds ◽  
Perovskite Solar Cells ◽  
Molecular Engineering ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

Optimization of the structure of hole transporting material leads to over 19% efficiency.

Molecular Engineering of Thienyl Functionalized Ullazines as Hole Transporting Materials for Perovskite Solar Cells

Solar RRL ◽  
2021 ◽  
Author(s):  
Jianxing Xia ◽  
Marco Cavazzini ◽  
Cansu Igci ◽  
Maria Cristina Momblona Rincón ◽  
Simonetta Orlandi ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Molecular Engineering ◽  
Hole Transporting ◽  
Hole Transporting Materials

scholarly journals Low cost triazatruxene hole transporting material for >20% efficiency perovskite solar cells

2019 ◽  
Vol 7 (18) ◽  
pp. 5235-5243 ◽  
Author(s):  
Arthur Connell ◽  
Zhiping Wang ◽  
Yen-Hung Lin ◽  
Peter C. Greenwood ◽  
Alan A. Wiles ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

Organic hole-transporting materials (HTM) have shown excellent ability in achieving high efficiency perovskite solar cells.

Hole transporting materials based on benzodithiophene and dithienopyrrole cores for efficient perovskite solar cells

2018 ◽  
Vol 6 (14) ◽  
pp. 5944-5951 ◽  
Author(s):  
R. Sandoval-Torrientes ◽  
I. Zimmermann ◽  
J. Calbo ◽  
J. Aragó ◽  
J. Santos ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Reorganization Energy ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

High efficiency (18.1%) perovskite solar cells are demonstrated by using a hole transporting material with very low reorganization energy (λ).

scholarly journals Novel Anthracene HTM Containing TIPs for Perovskite Solar Cells

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2249
Author(s):  
Sanghyun Paek
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Long Term Stability ◽  
Photovoltaic Conversion Efficiency ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

Recently, perovskite solar cells have been in the spotlight due to several of their advantages. Among the components of PSCs, hole transporting materials (HTMs) re the most important factors for achieving high performance and a stable device. Here, we introduce a new D–π–D type hole transporting material incorporating Tips-anthracene as a π–conjugation part and dimethoxy-triphenylamine as a donor part (which can be easily synthesized using commercially available materials). Through the measurement of various optical properties, the new HTM not only has an appropriate energy level but also has excellent hole transport capability. The device with PEH-16 has a photovoltaic conversion efficiency of 17.1% under standard one sun illumination with negligible hysteresis, which can be compared to a device using Spiro_OMeTAD under the same conditions. Ambient stability for 1200 h shown that 98% of PEH-16 device from the initial PCE was retained, indicating that the devices had good long-term stability.

Imidazole core to construct dopant-free asymmetric hole-transporting material for efficient inverted perovskite solar cells

2021 ◽  
Author(s):  
Yang Cheng ◽  
Quanping Wu ◽  
Ming Luo ◽  
Haolin Wang ◽  
Song Xue ◽  
...  
Keyword(s):  
Solar Cells ◽  
Direct Contact ◽  
Bottom Electrode ◽  
Perovskite Solar Cells ◽  
Perovskite Layer ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

As the sandwiched hole transporting materials (HTMs) layers are in direct contact with up-coated perovskite layer and bottom electrode in p-i-n structured perovskite (i-PSCs), the film quality of HTMs determines...

scholarly journals Development of simple hole-transporting materials for perovskite solar cells

2016 ◽  
Vol 94 (4) ◽  
pp. 352-359 ◽  
Author(s):  
Andrew M. Namespetra ◽  
Arthur D. Hendsbee ◽  
Gregory C. Welch ◽  
Ian G. Hill
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Insulating Polymers ◽  
Hole Transporting Material ◽  
Surface Morphologies ◽  
Highest Occupied Molecular Orbitals ◽  
Hole Transporting Materials

Three low-cost propeller-shaped small molecules based on a triphenylamine core and the high-performance donor molecule 7,7′-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′]dithiophene-2,6-diyl]bis[6-fluoro-4-(5′-hexyl-[2,2′-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole] (DTS(FBTTh2)2) were investigated as hole-transporting materials in perovskite solar cells. Each hole-transporting material was designed with highly modular side arms, allowing for different bandgaps and thin-film properties while maintaining a consistent binding energy of the highest occupied molecular orbitals to facilitate hole extraction from the perovskite active layer. Perovskite solar cell devices were fabricated with each of the three triphenylamine-based hole-transporting materials and DTS(FBTTh2)2 and were compared to devices with 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) hole-transporting layers. Each of our triphenylamine hole-transporting materials and DTS(FBTTh2)2 displayed surface morphologies that were considerably rougher than that of spiro-OMeTAD; a factor that may contribute to lower device performance. It was found that using inert, insulating polymers as additives with DTS(FBTTh2)2 reduced the surface roughness, resulting in devices with higher photocurrents.

scholarly journals Molecularly engineered thienyl-triphenylamine substituted zinc phthalocyanine as dopant free hole transporting materials in perovskite solar cells

2020 ◽  
Vol 4 (12) ◽  
pp. 6188-6195
Author(s):  
Peng Huang ◽  
Adrián Hernández ◽  
Samrana Kazim ◽  
Javier Ortiz ◽  
Ángela Sastre-Santos ◽  
...  
Keyword(s):  
Solar Cells ◽  
Chemical Stability ◽  
Perovskite Solar Cells ◽  
Zinc Phthalocyanine ◽  
Free Hole ◽  
Semiconducting Properties ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials ◽  
Excellent Chemical

The synthesis and semiconducting properties of thienyl-triphenylamine tetrasubstituted zinc(ii) phthalocyanine and its integration as a dopant-free hole transporting material in perovskite solar cells. Competitive performance and excellent chemical stability were obtained.

Naphtho[1,2-b:4,3-b′]dithiophene-based hole transporting materials for high-performance perovskite solar cells: molecular engineering and opto-electronic properties

2018 ◽  
Vol 6 (21) ◽  
pp. 10057-10063 ◽  
Author(s):  
Bin-Bin Cui ◽  
Ning Yang ◽  
Congbo Shi ◽  
Shuangshuang Yang ◽  
Jiang-Yang Shao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electronic Properties ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Molecular Engineering ◽  
Hole Transporting ◽  
Charge Extraction ◽  
Hole Transporting Materials

Better planarity and conjugation of hole-transporting materials resulting in good charge extraction and transport efficiently improve the performance of perovskite solar cells.

A review on triphenylamine (TPA) based organic hole transport materials (HTMs) for dye sensitized solar cells (DSSCs) and perovskite solar cells (PSCs): evolution and molecular engineering

2017 ◽  
Vol 5 (4) ◽  
pp. 1348-1373 ◽  
Author(s):  
Pooja Agarwala ◽  
Dinesh Kabra
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Hole Transport ◽  
Molecular Engineering ◽  
Morphological Stability ◽  
Dye Sensitized ◽  
Hole Transporting ◽  
Sensitized Solar Cells ◽  
Hole Transporting Materials

Development of triphenylamine (TPA) based hole-transporting-materials (HTMs) leading to highTg, higher morphological stability and longevity of dye-sensitized and perovskite solar cells.

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