A NIR facile, cell-compatible fluorescent sensor for glutathione based on Michael addition induced cascade spirolactam opening and its application in hepatocellular carcinoma

2018 ◽  
Vol 6 (45) ◽  
pp. 7486-7494 ◽  
Author(s):  
Xin Yang ◽  
Ying Qian

A NIR fluorescence probe with NIR emission wavelength at 746 nm and high quantum yield of 0.36 was designed and synthesized to selectively detect GSH over Hcy and Cys in living systems.

2019 ◽  
Vol 43 (24) ◽  
pp. 9614-9622
Author(s):  
Ming Qian ◽  
Liuwei Zhang ◽  
Jingyun Wang

Probe N-Bio exhibited rapid response, high sensitivity and strong NIR fluorescence in the detection of biothiols in living cells.


2020 ◽  
Vol 11 (31) ◽  
pp. 8095-8104
Author(s):  
Erin J. Viere ◽  
Wei Qi ◽  
Ian N. Stanton ◽  
Peng Zhang ◽  
Michael J. Therien

Incorporation of proquinoidal BTD building blocks into conjugated porphyrin oligomers minimizes the extent of excited-state structural relaxation relative to the ground-state conformation, elucidating new classes of impressive NIR fluorophores.


2020 ◽  
Vol 110 ◽  
pp. 110461
Author(s):  
Xiaoshuo Zhang ◽  
Chunhua Li ◽  
Sheliang Zhao ◽  
Huiyun Pang ◽  
Yong Han ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 107717-107722 ◽  
Author(s):  
Saihua Wang ◽  
Hongyun Niu ◽  
Sijing He ◽  
Yaqi Cai

Easily synthesized high quantum yield sulfur- and nitrogen-doped carbon dots can serve as a very efficient fluorescent sensor for the detection of Cr(vi).


2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>


Author(s):  
Jinmeng Xiang ◽  
Xiaoqi Zhao ◽  
Hao Suo ◽  
Minkun Jin ◽  
Xue Zhou ◽  
...  

Controlling the light environment of plant growth using phosphor-converted light-emitting diodes (pc-LEDs) is an important means to regulate the growth rhythm and enhance the yield, in which bluish violet light...


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