Perovskite solar cells with an MoS2 electron transport layer

2019 ◽  
Vol 7 (12) ◽  
pp. 7151-7158 ◽  
Author(s):  
Ranbir Singh ◽  
Anupam Giri ◽  
Monalisa Pal ◽  
Kaliannan Thiyagarajan ◽  
Junghyeok Kwak ◽  
...  

MoS2 thin films are directly synthesized over FTO/glass substrate in a one-step process and used as an efficient electron transport layer (ETL) for perovskite solar cells (PSCs).

2019 ◽  
Vol 7 (44) ◽  
pp. 25347-25354 ◽  
Author(s):  
Huiyun Wei ◽  
Jionghua Wu ◽  
Peng Qiu ◽  
Sanjie Liu ◽  
Yingfeng He ◽  
...  

Plasma-enhanced atomic-layer-deposited GaN thin-films have been introduced into planar perovskite solar cells as electron transport layers.


2019 ◽  
Vol 09 (05) ◽  
pp. 1950042 ◽  
Author(s):  
Shanming Ke ◽  
Bukui Du ◽  
Zhenggang Rao ◽  
Chun Huang ◽  
Peng Lin ◽  
...  

Hybrid perovskite solar cells (PSCs) have been intensively studied in recent years because of their high efficiency and low costs. For PSCs, the electron transport layer (ETL) is a key for its photoelectric conversion efficiency. Here we demonstrate the application of amorphous InGaZnO4 thin films as ETL for efficient PSCs by pulsed laser deposition (PLD). The PSC device using such InGaZnO4 amorphous film as ETL has achieved an efficiency of 15.1%. The outstanding performance is attributed to the excellent properties of amorphous InGaZnO4 oxide thin films, including high electron mobility and high transparency, what is more, the electronic properties of the films can be controlled by changing the partial pressure of oxygen in the deposition chamber and post-deposition annealing process. Our result will be helpful for preparation of large area PSCs and other opto-electric devices at low temperature by physical vapor deposition method.


Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 933
Author(s):  
Helong Wang ◽  
Guanchen Liu ◽  
Chongyang Xu ◽  
Fanming Zeng ◽  
Xiaoyin Xie ◽  
...  

Surface passivation, which has been intensively studied recently, is essential for the perovskite solar cells (PSCs), due to the intrinsic defects in perovskite crystal. A series of chemical or physical methods have been published for passivating the defects of perovskites, which effectively suppressed the charge recombination and enhanced the photovoltaic performance. In this study, the n-type semiconductor of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is dissolved in chlorobenzene (CB) for the surface passivation during the spin-coating process for depositing the two-dimensional (2D) perovskite film. This approach simplifies the fabrication process of 2D PSCs and benefits the film quality. As a result, the defects of perovskite film are effectively passivated by this method. A better perovskite/PCBM heterojunction is generated, exhibiting an increased film coverage and improved film morphology of PCBM. It is found that this technology results in an improved electron transporting performance as well as suppressed charge recombination for electron transport layer. As a result, PSCs based on the one-step formed perovskite/PCBM heterojunctions exhibit the optimized power conversion efficiency of 15.69% which is about 37% higher than that of regular perovskite devices. The device environmental stability is also enhanced due to the quality improved electron transport layer.


2018 ◽  
Vol 6 (31) ◽  
pp. 15348-15358 ◽  
Author(s):  
Ziqiu Ren ◽  
Jinde Wu ◽  
Na Wang ◽  
Xin Li

Herein, for the first time, we report the Er-doped nano-crystalline mixed-phase TiO2 synthesized through one-step hydrothermal method as electron transport layer for PSCs.


2018 ◽  
Vol 54 (21) ◽  
pp. 2623-2626 ◽  
Author(s):  
Zhelu Hu ◽  
Hengyang Xiang ◽  
Mathilde Schoenauer Sebag ◽  
Laurent Billot ◽  
Lionel Aigouy ◽  
...  

Thickness-tunable and compact FA0.83Cs0.17Pb(I0.6Br0.4)3 perovskite thin films are achieved with a large grain size up to 12 microns. They are then employed to fabricate planar electron-transport-layer-free solar cells.


2017 ◽  
Vol 5 (38) ◽  
pp. 10023-10028 ◽  
Author(s):  
Jia Dong ◽  
Jihuai Wu ◽  
Jinbiao Jia ◽  
Leqing Fan ◽  
Yu Lin ◽  
...  

In this report, redispersable CdS nanoparticles are synthesized via a specific one-step solvothermal reaction and are employed as electron-selective materials for organometal halide perovskite solar cells.


2018 ◽  
Vol 42 (17) ◽  
pp. 14104-14110 ◽  
Author(s):  
Muhammad Aamir ◽  
Tham Adhikari ◽  
Muhammad Sher ◽  
Neerish Revaprasadu ◽  
Waqas Khalid ◽  
...  

Inorganic cesium lead bromoiodide based planar perovskite solar cells with ZnO electron transport layers are deposited using one step spin coating.


Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 32 ◽  
Author(s):  
Seungtae Baek ◽  
Jeong Woo Han ◽  
Devthade Vidyasagar ◽  
Hanbyeol Cho ◽  
Hwi-Heon HA ◽  
...  

We report amorphous tin-indium-oxide (TIO, Sn fraction: >50 atomic percentage (at%)) thin films as a new electron transport layer (ETL) of perovskite solar cells (PSCs). TIO thin films with Sn fraction of 52, 77, 83, 92, and 100 at% were grown on crystalline indium-tin-oxide (ITO, Sn fraction: ~10 at%) thin films, a common transparent conducting oxide, by co-sputtering In2O3 and SnO2 at room temperature. The energy band structures of the amorphous TIO thin films were determined from the optical absorbance and the ultraviolet photoelectron spectra. All the examined compositions are characterized by a conduction band edge lying between that of ITO and that of perovskite (here, methylammonium lead triiodide), indicating that TIO is a potentially viable ETL of PSCs. The photovoltaic characteristics of the TIO-based PSCs were evaluated. Owing mainly to the highest fill factor and open circuit voltage, the optimal power conversion efficiency was obtained for the 77 at%-Sn TIO ETL with TiCl4 treatment. The fill factor and the open circuit voltage changes with varying the Sn fraction, despite similar conduction band edges. We attribute these differences to the considerable changes in the electrical resistivity of the TIO ETL. This would have a significant effect on the shunt and/or the series resistances. The TIO ETL can be continuously grown on an ITO TCO in a chamber, as ITO and TIO are composed of identical elements, which would help to reduce production time and costs.


2021 ◽  
Author(s):  
Song Fang ◽  
Bo Chen ◽  
Bangkai Gu ◽  
Linxing Meng ◽  
Hao Lu ◽  
...  

UV induced decomposition of perovskite material is one of main factors to severely destroy perovskite solar cells for instability. Here we report a UV stable perovskite solar cell with a...


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