scholarly journals Fabrication of planar heterojunction CsPbBr2I perovskite solar cells using ZnO as an electron transport layer and improved solar energy conversion efficiency

2018 ◽  
Vol 42 (17) ◽  
pp. 14104-14110 ◽  
Author(s):  
Muhammad Aamir ◽  
Tham Adhikari ◽  
Muhammad Sher ◽  
Neerish Revaprasadu ◽  
Waqas Khalid ◽  
...  

Inorganic cesium lead bromoiodide based planar perovskite solar cells with ZnO electron transport layers are deposited using one step spin coating.

2018 ◽  
Vol 6 (17) ◽  
pp. 7409-7419 ◽  
Author(s):  
Zhiyong Liu ◽  
Bo Sun ◽  
Xingyue Liu ◽  
Jinghui Han ◽  
Haibo Ye ◽  
...  

Low-temperature printable carbon based planar-heterojunction perovskite solar cells with efficiencies exceeding 15% were demonstrated by using a TiO2/SnO2bilayer as ETL together with CuPc as HTL.


2019 ◽  
Vol 29 (46) ◽  
pp. 1905694 ◽  
Author(s):  
Lin Yang ◽  
Chunxiang Dall'Agnese ◽  
Yohan Dall'Agnese ◽  
Gang Chen ◽  
Yu Gao ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2272
Author(s):  
Junqi Wang ◽  
Xiaoping Zou ◽  
Jialin Zhu ◽  
Jin Cheng ◽  
Dan Chen ◽  
...  

The film quality of the electron transport layer (ETL) plays an important role in improving the performance of perovskite solar cells (PSCs). In order to reduce the effect of rough fluorine-doped SnO2 (FTO)substrate on the film quality of the TiO2 ETL, multiple cycles of spin-coating were employed to realize optimized TiO2 film and improve the performance of PSCs with rough FTO. The results show that TiO2 ETL was optimized most effectively using two spin-coating cycles, obtaining the best performance of PSCs with rough FTO. The carbon electrode-based PSCs were then demonstrated. Our work discusses the feasibility of low-quality rough FTO for the fabrication of PSCs and photodetectors to reduce costs.


Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3090
Author(s):  
Jun Choi ◽  
Young Ki Park ◽  
Hee Dong Lee ◽  
Seok Il Hong ◽  
Woosung Lee ◽  
...  

A robust electron transport layer (ETL) is an essential component in planar-heterojunction perovskite solar cells (PSCs). Herein, a sol-gel-driven ZrSnO4 thin film is synthesized and its optoelectronic properties are systematically investigated. The optimized processing conditions for sol-gel synthesis produce a ZrSnO4 thin film that exhibits high optical transmittance in the UV-Vis-NIR range, a suitable conduction band maximum, and good electrical conductivity, revealing its potential for application in the ETL of planar-heterojunction PSCs. Consequently, the ZrSnO4 ETL-based devices deliver promising power conversion efficiency (PCE) up to 19.05% from CH3NH3PbI3-based planar-heterojunction devices. Furthermore, the optimal ZrSnO4 ETL also contributes to decent long-term stability of the non-encapsulated device for 360 h in an ambient atmosphere (T~25 °C, RH~55%,), suggesting great potential of the sol-gel-driven ZrSnO4 thin film for a robust solution-processed ETL material in high-performance PSCs.


2016 ◽  
Vol 4 (22) ◽  
pp. 8724-8733 ◽  
Author(s):  
Hua Zhang ◽  
Lingwei Xue ◽  
Junbo Han ◽  
Yong Qing Fu ◽  
Yan Shen ◽  
...  

In this study, for the first time, we introduced amino-substituted perylene diimide derivative (N-PDI) as an alternative electron transport layer (ETL) to replace the commonly used TiO2 in planar heterojunction perovskite solar cells.


Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 933
Author(s):  
Helong Wang ◽  
Guanchen Liu ◽  
Chongyang Xu ◽  
Fanming Zeng ◽  
Xiaoyin Xie ◽  
...  

Surface passivation, which has been intensively studied recently, is essential for the perovskite solar cells (PSCs), due to the intrinsic defects in perovskite crystal. A series of chemical or physical methods have been published for passivating the defects of perovskites, which effectively suppressed the charge recombination and enhanced the photovoltaic performance. In this study, the n-type semiconductor of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is dissolved in chlorobenzene (CB) for the surface passivation during the spin-coating process for depositing the two-dimensional (2D) perovskite film. This approach simplifies the fabrication process of 2D PSCs and benefits the film quality. As a result, the defects of perovskite film are effectively passivated by this method. A better perovskite/PCBM heterojunction is generated, exhibiting an increased film coverage and improved film morphology of PCBM. It is found that this technology results in an improved electron transporting performance as well as suppressed charge recombination for electron transport layer. As a result, PSCs based on the one-step formed perovskite/PCBM heterojunctions exhibit the optimized power conversion efficiency of 15.69% which is about 37% higher than that of regular perovskite devices. The device environmental stability is also enhanced due to the quality improved electron transport layer.


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