A benzo[1,2-d:4,5-d′]bisthiazole-based wide-bandgap copolymer semiconductor for efficient fullerene-free organic solar cells with a small energy loss of 0.50 eV

2019 ◽  
Vol 7 (10) ◽  
pp. 5234-5238 ◽  
Author(s):  
Nai-Yu Chen ◽  
Qihui Yue ◽  
Wenrui Liu ◽  
Hao-Li Zhang ◽  
Xiaozhang Zhu

A wide-bandgap polymer donor based on benzo[1,2-d:4,5-d′]bisthiazole is designed and synthesized delivering a PCE of 11.08% with a low energy loss of 0.50 eV.

2020 ◽  
Vol 4 (12) ◽  
pp. 6203-6211
Author(s):  
Yu Chen ◽  
Rui Cao ◽  
Hui Liu ◽  
M. L. Keshtov ◽  
Emmanuel N. Koukaras ◽  
...  

In order to increase the power conversion efficiency (PCE) of organic solar cells, developing high-performance non-fullerene small molecule acceptors is important for efficient charge generation and small energy loss.


2017 ◽  
Vol 5 (47) ◽  
pp. 12591-12596 ◽  
Author(s):  
Pan Ye ◽  
Yusheng Chen ◽  
Jianfei Wu ◽  
Xiaoxi Wu ◽  
Simiao Yu ◽  
...  

Upon replacing thiophene moieties with thiazole ones, introducing S⋯N noncovalent conformational locks resulted in a significant enhancement of photovoltaic performances.


2019 ◽  
Vol 7 (32) ◽  
pp. 10039-10048 ◽  
Author(s):  
Zhiyong Liu ◽  
Ning Wang

Fullerene-free organic solar cells (OSCs) were fabricated using a blend of wide bandgap donor PBDB-T and ultranarrow bandgap acceptor IEICO-4F as binary photoactive layers.


2021 ◽  
pp. 129768
Author(s):  
Dou Luo ◽  
Xue Lai ◽  
Nan Zheng ◽  
Chenghao Duan ◽  
Zhaojin Wang ◽  
...  

2018 ◽  
Vol 6 (16) ◽  
pp. 4457-4463 ◽  
Author(s):  
Jingyang Xiao ◽  
Ziming Chen ◽  
Guichuan Zhang ◽  
Qing-Ya Li ◽  
Qingwu Yin ◽  
...  

We have systematically investigated the synergistic effect of thermal annealing and interlayer modification on improving the performance of inverted non-fullerene organic solar cells.


ChemPhysChem ◽  
2019 ◽  
Vol 20 (20) ◽  
pp. 2668-2673 ◽  
Author(s):  
Ruihao Xie ◽  
Lei Ying ◽  
Kang An ◽  
Wenkai Zhong ◽  
Qingwu Yin ◽  
...  

2019 ◽  
Vol 01 (01) ◽  
pp. 030-037 ◽  
Author(s):  
Jianyun Zhang ◽  
Wenrui Liu ◽  
Shengjie Xu ◽  
Xiaozhang Zhu

Recently, by elaborately designing nonfullerene acceptors and selecting suitable polymer donors great progresses have been made towards binary organic solar cells (OSCs) with power conversion efficiencies (PCEs) over 15%. Ternary organic photovoltaics by introducing a third component into the host binary system is recognized to be highly effective to elevate the performance through extending the light absorption, manipulating the recombination behavior of the carriers, and improving the morphology of the active layer. In this work, we synthesized a new electron-acceptor ZITI-4F matching it with the wide-bandgap polymer donor PBDB-T The PBDB-T:ZITI-4F-based OSC showed a high PCE of 12.33%. After introducing 40% of PC71BM as the third component, the ternary device achieved an improved PCE of 13.40% with simultaneously improved photovoltaic parameters. The higher performance of the ternary device can be attributed to the improved and more balanced charge mobility, reduced bimolecular recombination, and more favorable morphology. These results indicate that the cooperation of a fullerene-based acceptor and a nonfullerene acceptor to fabricate ternary OSCs is an effective approach to optimizing morphology and therefore to increase the performance of OSCs.


Polymer ◽  
2020 ◽  
Vol 188 ◽  
pp. 122131 ◽  
Author(s):  
Chang Eun Song ◽  
Hyobin Ham ◽  
Jiwoong Noh ◽  
Sang Kyu Lee ◽  
In-Nam Kang

2017 ◽  
Vol 10 (8) ◽  
pp. 1739-1745 ◽  
Author(s):  
Jiahui Wan ◽  
Xiaopeng Xu ◽  
Guangjun Zhang ◽  
Ying Li ◽  
Kui Feng ◽  
...  

Naphtho[1,2-c:5,6-c']bis[1,2,5]thiadiazole-based small molecules have been synthesized for organic solar cells. The optimized devices processed by a halogen-free solvent of CS2 exhibited a PCE of 11.53% with a small energy loss of 0.57 eV.


2020 ◽  
Vol 13 (5) ◽  
pp. 1309-1317 ◽  
Author(s):  
Yulong Wang ◽  
Yang Wang ◽  
Lei Zhu ◽  
Haiqin Liu ◽  
Jin Fang ◽  
...  

A novel small molecule donor based on thiazolo[5,4-d]thiazole (TTz) unit is developed for OSCs application with 13.9% power conversion efficiency and a small non-radiative energy loss of 0.18 eV.


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