NanoMOFs: little crystallites for substantial applications

2018 ◽  
Vol 6 (17) ◽  
pp. 7338-7350 ◽  
Author(s):  
M. B. Majewski ◽  
H. Noh ◽  
T. Islamoglu ◽  
O. K. Farha
Keyword(s):  
Metal Organic Framework ◽  
Synthetic Methods ◽  
Size Regime ◽  
Potential Applications ◽  
Metal Organic ◽  
Nano Size ◽  
Organic Framework

Synthetic methods for the preparation of metal–organic framework crystallites in the nano-size regime and their potential applications are reviewed.

Photochromism and photoswitchable luminescence in a Zn7 cluster-based metal-organic framework with organic guest

2021 ◽  
Author(s):  
Jian-Jun Liu ◽  
Jia-Jia Fu ◽  
Teng Liu ◽  
Chixian He ◽  
Feixiang Cheng
Keyword(s):  
Metal Organic Framework ◽  
Optical Memory ◽  
Memory Devices ◽  
Potential Applications ◽  
Metal Organic ◽  
Photochromic Materials ◽  
Organic Framework

Photochromic materials coupled with the photoswitchable luminescence functionalities are of particular interest due to their potential applications in switches and optical memory devices. However, construct such materials, especially those with...

scholarly journals Recent Developments in the Synthesis and Applications of Metal Organic Framework: A Concise Review

2021 ◽  
Vol 33 (5) ◽  
pp. 956-962
Author(s):  
Chandan Adhikari ◽  
Rehana Farooq
Keyword(s):  
Drug Delivery ◽  
Porous Materials ◽  
Electrochemical Sensors ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Inorganic Materials ◽  
Synthetic Methods ◽  
Concise Review ◽  
Metal Organic ◽  
Organic Framework

Metal organic frameworks (MOFs) are one of those compounds which have drawn attention in various applications due to their several interesting properties like tunable shape, size, pore size, easy functionalization, high surface area, pore volume, etc. Metal organic frameworks due to their uniform structures, tunable porosity, wide variety and stability on various topology, geometry, dimension and chemical functions of the molecular network give a remarkable structural diversity in comparison to other porous materials. This enables scientists to handle numerous framework structures, porosity and functionality effectively. The unique structural architecture and tunable properties of MOF’s makes them an interesting hybrid material consisting of organic and inorganic materials. MOF can be randomly constructed like Lego bricks and superior in terms of versatility in comparisson to other porous materials. A number of MOFs containing a wide variety of metal e.g. zinc, copper, iron, aluminium, magnesium, chromium, zirconium, gadolinium, manganese are gaining rapid growth in commercial markets for gas storage, adsorption, separation and catalytic applications. This concise review emphasizes various synthetic methods e.g. solvothermal process, hydrothermal synthesis, electrochemical synthesis, microwave synthesis, sonochemical synthesis, mechanochemical synthesis, of metal organic framework developed in the last few decades. It also addresses various applications of metal organic framework e.g. hydrogen storage, gas adsorption, drug delivery systems and bioimaging agents, biocatalysts, biosensors, electrochemical sensors, etc. It also comments on various challenges and futuristic applications of metal organic frameworks in various field e.g. liquid wate management, gaseous waste management, sunlight assisted catalysis, water purification, building materials, electronic devices, battery technologies, targeted drug delivery, solar cells, etc. of science and technology in coming decades.

scholarly journals Metal-Organic Framework and Inorganic Glass Composites

2020 ◽  
Author(s):  
Louis Longley ◽  
Courtney Calahoo ◽  
Rene Limbach ◽  
Joshua M. Tuffnell ◽  
Adam Sapnik ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Inorganic Glass ◽  
Glass Composites ◽  
New Family ◽  
Optically Transparent ◽  
Potential Applications ◽  
Metal Organic ◽  
Quenched Glass ◽  
Inorganic Glasses ◽  
Organic Framework

<p>Metal-organic framework (MOF) glasses have become a subject of study due to their novelty as an entirely new category of melt quenched glass and their potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses, in order to fabricate a new family of optically transparent materials, composed of both MOF and inorganic glass domains. Here, we present the design rules for this family of materials, use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.</p>

Fabrication of a freestanding metal organic framework predominant hollow fiber mat and its potential applications in gas separation and catalysis

2020 ◽  
Vol 8 (7) ◽  
pp. 3803-3813 ◽  
Author(s):  
Zijian Dai ◽  
Dennis T. Lee ◽  
Kaihang Shi ◽  
Siyao Wang ◽  
Heather F. Barton ◽  
...  
Keyword(s):  
Gas Separation ◽  
Hollow Fiber ◽  
Metal Organic Framework ◽  
Fiber Mats ◽  
Potential Applications ◽  
Metal Organic ◽  
Voc Abatement ◽  
Organic Framework

Freestanding MOF predominant hollow fiber mats are fabricated via an oxide-to-MOF conversion approach. The unique hollow fiber mats show promising potential in CO2 adsorption, CO2/N2 separation, and VOC abatement applications.

Toxicity of metal–organic framework nanoparticles: from essential analyses to potential applications

2022 ◽  
Author(s):  
Romy Ettlinger ◽  
Ulrich Lächelt ◽  
Ruxandra Gref ◽  
Patricia Horcajada ◽  
Twan Lammers ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Systematic Assessment ◽  
Potential Applications ◽  
Metal Organic ◽  
Key Aspects ◽  
Organic Framework ◽  
The Way

This tutorial review highlights the key aspects of nanotoxicity and the importance of its systematic assessment for metal–organic framework (MOF) nanoparticles to pave the way towards their potential applications in a safe and sustainable manner.

A new luminescent anionic metal–organic framework based on heterometallic zinc(II)–barium(II) for selective detection of Fe3+ and Cu2+ ions in aqueous solution

2019 ◽  
Vol 75 (10) ◽  
pp. 1372-1380 ◽  
Author(s):  
Natthakorn Phadungsak ◽  
Filip Kielar ◽  
Winya Dungkaew ◽  
Mongkol Sukwattanasinitt ◽  
Yan Zhou ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Crystal Engineering ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Functional Materials ◽  
Ionic Species ◽  
Hydrothermal Conditions ◽  
Potential Applications ◽  
Metal Organic ◽  
Organic Framework

Over the past two decades, the development of novel inorganic–organic hybrid porous crystalline materials or metal–organic frameworks (MOFs) using crystal engineering has provoked significant interest due to their potential applications as functional materials. In this context, luminescent MOFs as fluorescence sensors have recently received significant attention for the sensing of ionic species and small molecules. In this work, a new luminescent heterometallic zinc(II)–barium(II)-based anionic metal–organic framework, namely poly[imidazolium [triaqua(μ6-benzene-1,3,5-tricarboxylato)bariumtrizinc] tetrahydrate], {(C3H4N2)[BaZn3(C9H3O6)3(H2O)3]·4H2O} n (1), was synthesized under hydrothermal conditions and characterized. Compound 1 presents a three-dimensional framework with an unprecedented (3,5)-connected topology of the point symbol (3.92).(33.42.5.93.10), and exhibits `turn-off' luminescence responses for the Cu2+ and Fe3+ ions in aqueous solution based on significantly different quenching mechanisms.

scholarly journals Metal-organic framework and inorganic glass composites

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Louis Longley ◽  
Courtney Calahoo ◽  
René Limbach ◽  
Yang Xia ◽  
Joshua M. Tuffnell ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Inorganic Glass ◽  
Glass Composites ◽  
New Family ◽  
Distinct Category ◽  
Potential Applications ◽  
Metal Organic ◽  
Quenched Glass ◽  
Inorganic Glasses ◽  
Organic Framework

AbstractMetal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.

Regulating the size and spatial distribution of Pd nanoparticles supported by the defect engineered metal–organic framework HKUST-1 and applied in the aerobic oxidation of cinnamyl alcohol

2019 ◽  
Vol 9 (14) ◽  
pp. 3703-3710 ◽  
Author(s):  
Penghu Guo ◽  
Qi Fu ◽  
Ceylan Yildiz ◽  
Yen-Ting Chen ◽  
Kevin Ollegott ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Pd Nanoparticles ◽  
Cinnamyl Alcohol ◽  
Pd Catalysts ◽  
Size Regime ◽  
Metal Organic ◽  
Organic Framework

A series of novel Pd@DE-HKUST-1(Cu/Pd) catalysts with different pydc feeding ratios were successfully synthesized. The size regime and the spatial distribution of the Pd NPs can be controlled by the amount of framework incorporated pydc.

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