Regulating the size and spatial distribution of Pd nanoparticles supported by the defect engineered metal–organic framework HKUST-1 and applied in the aerobic oxidation of cinnamyl alcohol

2019 ◽  
Vol 9 (14) ◽  
pp. 3703-3710 ◽  
Author(s):  
Penghu Guo ◽  
Qi Fu ◽  
Ceylan Yildiz ◽  
Yen-Ting Chen ◽  
Kevin Ollegott ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Pd Nanoparticles ◽  
Cinnamyl Alcohol ◽  
Pd Catalysts ◽  
Size Regime ◽  
Metal Organic ◽  
Organic Framework

A series of novel Pd@DE-HKUST-1(Cu/Pd) catalysts with different pydc feeding ratios were successfully synthesized. The size regime and the spatial distribution of the Pd NPs can be controlled by the amount of framework incorporated pydc.

Amine-functionalized metal–organic framework-based Pd nanoparticles: highly efficient multifunctional catalysts for base-free aerobic oxidation of different alcohols

2020 ◽  
Vol 44 (44) ◽  
pp. 19113-19121
Author(s):  
Abu Taher ◽  
Md. Abu Bin Hasan Susan ◽  
Noorjahan Begum ◽  
Ik-Mo Lee
Keyword(s):  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Pd Nanoparticles ◽  
Highly Efficient ◽  
Amine Functionalized ◽  
Multifunctional Catalysts ◽  
Aromatic Alcohols ◽  
Metal Organic ◽  
Organic Framework

Metal–organic framework-based palladium nanoparticles are found to be highly efficient multifunctional catalysts for the base-free aerobic oxidation of different aliphatic, aromatic and hetero-aromatic alcohols.

A novel copper(ii)–lanthanum(iii) metal organic framework as a selective catalyst for the aerobic oxidation of benzylic hydrocarbons and cycloalkenes

2016 ◽  
Vol 6 (11) ◽  
pp. 3727-3736 ◽  
Author(s):  
P. Cancino ◽  
A. Vega ◽  
Andrea Santiago-Portillo ◽  
Sergio Navalon ◽  
Mercedes Alvaro ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Selective Catalyst ◽  
Pyridinedicarboxylic Acid ◽  
Metal Organic ◽  
Organic Framework

The synthesis and catalytic activity of a novel heteronuclear CuII and LaIII metal organic framework (MOF) having pyridinedicarboxylic acid (CuLa-MOF) is reported.

A cerium-based metal–organic framework having inherent oxidase-like activity applicable for colorimetric sensing of biothiols and aerobic oxidation of thiols

CrystEngComm ◽  
2017 ◽  
Vol 19 (39) ◽  
pp. 5915-5925 ◽  
Author(s):  
Rana Dalapati ◽  
Balasubramanian Sakthivel ◽  
Manoj K. Ghosalya ◽  
Amarajothi Dhakshinamoorthy ◽  
Shyam Biswas
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Colorimetric Sensing ◽  
Metal Organic ◽  
Organic Framework

A cerium-based MOF exhibits oxidase-like activity for colorimetric sensing of biothiols and aerobic oxidation of thiols.

scholarly journals Frontispiz: Palladium Catalysis for Aerobic Oxidation Systems Using Robust Metal–Organic Framework

2019 ◽  
Vol 131 (48) ◽  
Author(s):  
Jiawei Li ◽  
Jianhua Liao ◽  
Yanwei Ren ◽  
Chi Liu ◽  
Chenglong Yue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aerobic Oxidation ◽  
Palladium Catalysis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Micro-spectroscopy of HKUST-1 metal–organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host–guest chemistry and electrical conductivity

2019 ◽  
Vol 21 (46) ◽  
pp. 25678-25689 ◽  
Author(s):  
Miguel Rivera-Torrente ◽  
Matthias Filez ◽  
Christian Schneider ◽  
Ewout C. van der Feltz ◽  
Konrad Wolkersdörfer ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Spatial Distribution ◽  
Water Vapor ◽  
Metal Organic Framework ◽  
Next Generation ◽  
Metal Organic ◽  
Spectroscopy Studies ◽  
Organic Framework ◽  
Guest Chemistry

Guest@MOF materials have potential in next-generation materials for electroconductive devices. Micro-spectroscopy studies of TCNQ@HKUST-1 electroconductive composites revealed the effects of spatial distribution and water vapor on this material.

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